Thermoplastic elastomer composition and thermoplastic elastomer manufactured by using the same

Patent metadata

Field	Value
Publication number	US-11680126-B2
Application number	US-202117532473-A
Country	US
Kind code	B2
Filing date	Nov 22, 2021
Priority date	Mar 2, 2021
Publication date	Jun 20, 2023
Grant date	Jun 20, 2023

Abstract

A thermoplastic elastomer composition includes about 80 parts by weight of an ethylene propylene diene monomer (EPDM) including 5-ethylidene-2-norbornene (ENB) and polyethylene, about 30 parts by weight to about 70 parts by weight of polypropylene, about 20 parts by weight to about 40 parts by weight of a filler, and about 60 parts by weight to about 90 parts by weight of a plasticizer.

First claim

What is claimed is:

1. A thermoplastic elastomer composition, comprising
about 80 parts by weight of an ethylene propylene diene monomer (EPDM) including 5-ethylidene-2-norbornene (ENB) and polyethylene,
about 31 parts by weight to about 35 parts by weight of polypropylene,
about 20 parts by weight to about 40 parts by weight of a filler, and
about 60 parts by weight to about 90 parts by weight of a plasticizer,
wherein the ethylene propylene diene monomer has a crystallinity of about 0% to about 15.8%, a crosslinking density of about 2.26×10 −4 mol/ml to about 2.68×10 −4 mol/ml, and a molecular weight distribution of about 3.4 to about 4.3, and
wherein the polypropylene has a crystallinity of about 52% to about 60%.

2. The thermoplastic elastomer composition of claim 1 , wherein the ethylene propylene diene monomer comprises about 5 wt % to about 10 wt % of 5-ethylidene-2-norbornene and about 50 wt % to about 70 wt % of polyethylene, based on the total weight of the ethylene propylene diene monomer.

3. The thermoplastic elastomer composition of claim 2 , wherein the ethylene propylene diene monomer comprises about 8.9 wt % to about 10 wt % of 5-ethylidene-2-norbornene and about 50 wt % to about 58 wt % of polyethylene, based on the total weight of the ethylene propylene diene monomer.

4. The thermoplastic elastomer composition of claim 1 , wherein the thermoplastic elastomer composition comprises about 85 parts by weight to about 90 parts by weight of the plasticizer.

5. The thermoplastic elastomer composition of claim 1 , wherein the thermoplastic elastomer composition further comprises about 0.1 parts by weight to about 1.25 parts by weight of a crosslink agent.

6. The thermoplastic elastomer composition of claim 1 , wherein the thermoplastic elastomer composition comprises about 0.1 parts by weight to about 0.5 parts by weight of a crosslink aid, about 0.1 parts by weight to about 0.5 parts by weight of an antioxidant, about 1 part by weight to about 3 parts by weight of a surface modifier, about 1 part by weight to about 3 parts by weight of a lubricant, about 1 part by weight to about 3 parts by weight of a crosslink accelerator, about 1 part by weight to about 5 parts by weight of a UV stabilizer, or a mixture thereof.

7. A thermoplastic elastomer manufactured of the thermoplastic elastomer composition of claim 1 ,
having a loss factor (Tan δ) of greater than or equal to about 0.139, and
having a compression set of less than or equal to about 45.44%,
wherein the loss factor (Tan δ) is an average Tan δ obtained at a low temperature (−4° C. to 4° C.) after performing a temperature sweep at 0.2% of dynamic strain and 10 Hz by using a Q850 equipment (dynamic mechanical analysis, DMA) made by TA Instruments, and
wherein the compression set is obtained in an oven at 70° C. for 22 hours after applying 25% of strain according to the ISO815 standard.

8. The thermoplastic elastomer of claim 7 , wherein the thermoplastic elastomer has
the loss factor (Tan δ) of about 0.144 to about 0.158, and
the compression set of about 29.53% to about 35.35%.

9. The thermoplastic elastomer of claim 7 , wherein
the thermoplastic elastomer has a static friction coefficient of less than or equal to about 0.9,
a kinetic friction coefficient of less than or equal to about 0.69, and
a maximum acceleration of less than or equal to about 2.44 g during stick slip.

10. A method for manufacturing the thermoplastic elastomer of claim 7 , comprising
mixing powders including fillers,
introducing ethylene propylene diene monomer (EPDM), polypropylene (PP), and the mixed powders into an extruder,
mixing the ethylene propylene diene monomer and polypropylene in the extruder, and
dynamically crosslinking the ethylene propylene diene monomer.

11. A weather strip for a vehicle including the thermoplastic elastomer of claim 7 .

12. The thermoplastic elastomer composition of claim 1 , wherein the thermoplastic elastomer composition comprises:
80 parts by weight of the ethylene propylene diene monomer (EPDM) including 5-ethylidene-2-norbornene (ENB) and polyethylene,
31 parts by weight to 35 parts by weight of polypropylene,
20 parts by weight to 40 parts by weight of the filler, and
60 parts by weight to 90 parts by weight of the plasticizer.

13. The thermoplastic elastomer composition of claim 12 , wherein the ethylene propylene diene monomer has a crystallinity of 0% to 15.8%, a crosslinking density of 2.26×10 −4 mol/ml to 2.68×10 −4 mol/ml, and a molecular weight distribution of 3.4 to 4.3, and
wherein the polypropylene has a crystallinity of 52% to 60%.

Assignees

• Hyundai Motor Co Ltd
• Kia Corp
• Hwaseung Mat Co Ltd
• Research & Business Found Sungkyunkwan Univ
• Hawseung Mat Co Ltd

Inventors

• Lee Sang Hyun
• Seong Jeehoon
• Kim Ho Dong
• Suhr Jonghwan
• Yoon Bumyong
• Cho Seunghyun
• Hong Kyoung-Min
• Lee Sang Hyun

Classifications

• C08J3/24

  Crosslinking, e.g. vulcanising, of macromolecules (mechanical aspects B29C35/00; crosslinking agents C08K) · CPC title

• C08J3/005 Primary

  Processes for mixing polymers · CPC title

• C08F255/02 Primary

  on to polymers of olefins having two or three carbon atoms · CPC title

• C08L2312/02

  with dienes · CPC title

• C08K5/0016

  Plasticisers · CPC title