CO2 solidified fiber cement board and its preparation method

Patent metadata

Field	Value
Publication number	US-11680015-B2
Application number	US-202217888536-A
Country	US
Kind code	B2
Filing date	Aug 16, 2022
Priority date	Sep 29, 2021
Publication date	Jun 20, 2023
Grant date	Jun 20, 2023

Abstract

Disclosed is a CO2 solidified fiber cement board and its preparation method. The matrix composition of the fiber cement board prepared in this disclosure is calcium carbonate, which has high compactness, and the crystal form of calcium carbonate is adjusted by adding shell powder to improve the toughness of the matrix, so that the fiber cement board has excellent mechanics and durability performance. In addition, the preparation process does not require high temperature maintenance, and has the characteristics of normal temperature preparation, which creates conditions for the introduction of organic synthetic fibers, so that the organic synthetic fibers can further improve the brittleness of cement fiberboard. While reducing energy consumption, the preparation process can also effectively solve the problem that excessive pressure is easily generated in the fiberboard under high temperature conditions in the existing high-temperature and high-pressure curing process.

First claim

What is claimed is:

1. A preparation method for CO 2 solidified fiber cement board, comprising the following steps;
dispersing cellulose fibers and organic synthetic fibers in water to obtain a fiber suspension;
mixing a gelling component and an additive to obtain a mixed material; the gelling component comprises one or more of calcium silicate mineral powder, calcium silicate mineral phase-rich steel slag powder, and calcium silicate mineral phase-rich magnesium slag powder; the additive comprises silica fume, limestone powder, shell powder and pigment;
mixing the fiber suspension, the mixed material, and water to obtain a slurry, and the slurry is sequentially dewatered, grouted, and statically maintained to obtain a slab, and the slab is cured in a CO 2 atmosphere to obtain the fiber cement board.

2. The preparation method for CO 2 solidified fiber cement board according to claim 1 , wherein the calcium silicate mineral powder includes one or more of γ-type dicalcium silicate, tricalcium disilicate, and monocalcium silicate; the average particle size of the gelling component is less than 50 μm.

3. The preparation method for CO 2 solidified fiber cement board according to claim 1 , wherein the additive also comprises expanded perlite; the particle size of the expanded perlite is 50-300 the particle size of the silica fume is 0.2-5 and the SiO 2 mass content in the silica fume is more than 90%;
the particle size of the limestone powder is 10-20 and the particle size of the shell powder is 10-100 μm.

4. The preparation method for CO 2 solidified fiber cement board according to claim 1 , wherein the pigment comprises cadmium red, titanium nickel yellow, titanium chromium brown, cobalt blue or cobalt green, and the particle size of the pigment is 10-20 μm.

5. The preparation method for CO 2 solidified fiber cement board according to claim 1 , wherein the length of the cellulose fiber is 1-5 mm, and the organic synthetic fiber comprises PVA fiber.

6. The preparation method for CO 2 solidified fiber cement board according to claim 1 , wherein the additive also comprises expanded perlite, and wherein the mass ratio of the gelling component, expanded perlite, the silica fume, the limestone powder, the shell powder, the cellulose fibers, the organic synthetic fibers, and the pigments is (55˜75):(0˜10):(4˜8):(10˜20):(5˜10):(2˜4):(2˜4):(0.1˜0.2).

7. The preparation method for CO 2 solidified fiber cement board according to claim 1 , wherein a pressure of the grouting is 300-850 kN with a pressure holding time of 45˜60 s.

8. The preparation method for CO 2 solidified fiber cement board according to claim 1 , wherein a temperature of the static maintenance is 40-50° C. with a relative humidity of less than 50% and a maintenance time of 1-4 h.

9. The preparation method for CO 2 solidified fiber cement board according to claim 1 , wherein curing conditions in the CO 2 atmosphere are: curing temperature of 5 to 90° C., relative humidity of 30% to 80%, air pressure of 0.05 to 0.3 MPa, and time of 2 to 48 hours.

10. A CO 2 solidified fiber cement board prepared by the preparation method for CO 2 solidified fiber cement board according to claim 1 .

Assignees

• Univ Wuhan Tech

Inventors

• Wang Fazhou
• Liu Zhichao
• Hu Shuguang
• Yang Lu

Classifications

• C04B16/0641

  Polyvinylalcohols; Polyvinylacetates · CPC title

• C04B2103/445

  Gelling agents · CPC title

• C04B12/007 Primary

  Non-hydraulic cements containing low lime calcium silicate phases, e.g. wollastonite, pseudowollastonite, rankinite or cements curable in the presence of CO2 · CPC title

• C04B14/185

  expanded · CPC title

• C04B14/42

  Glass · CPC title