Low-power sensor memory

Patent metadata

Field	Value
Publication number	US-11674829-B2
Application number	US-201916726192-A
Country	US
Kind code	B2
Filing date	Dec 23, 2019
Priority date	Dec 23, 2019
Publication date	Jun 13, 2023
Grant date	Jun 13, 2023

Abstract

A sensor system includes a sensor configured to measure a parameter. The sensor system also includes a memory configured to record one or more occurrences when the parameter is outside of a predetermined range. The memory includes a wire, a counter-electrode, and an electrolyte.

First claim

What is claimed is:

1. A sensor system, comprising:
a sensor configured to measure a parameter; and
a memory configured to record one or more occurrences when the parameter is outside of a predetermined range, wherein the memory comprises:
a wire;
a counter-electrode; and
an electrolyte,
wherein the wire and the counter-electrode are configured to receive the voltage from the sensor,
wherein the voltage generates an electrical current between the wire and the counter-electrode,
wherein the electrical current causes an electrochemical reaction in the wire, the counter-electrode, or both when the parameter is outside of the predetermined range, and
wherein the electrochemical reaction causes corrosion of the wire, which causes a conductance of the wire to decrease.

2. The sensor system of claim 1 , wherein the memory does not record a value of the parameter.

3. The sensor system of claim 1 , wherein:
the wire comprises a conductor that is configured to undergo the electrochemical reaction which changes a property of the wire when the parameter is outside of the predetermined range;
the counter-electrode comprises a redox-active material that is configured to be oxidized, reduced, or both when the parameter is outside of the predetermined range; and
the electrolyte comprises water with dissolved salt, an organic solvent with dissolved salt, a polymer with dissolved salt, an ionically conductive inorganic solid, or an ionic liquid.

4. The sensor system of claim 1 , further comprising a membrane positioned at least partially between the wire and the counter-electrode, wherein the membrane allows a flow of ions between two regions of the electrolyte, and wherein the membrane comprises an ion-selective membrane, an ion-conductive glass, or a polymer membrane.

5. The sensor system of claim 1 , further comprising a dielectric layer that is configured to isolate a portion of the wire from the electrolyte, a portion of the counter-electrode from the electrolyte, or both, wherein the dielectric layer comprises tape, a polymer coating, or a plastic laminate.

6. The sensor system of claim 1 , wherein the sensor outputs the voltage which is based at least partially upon the parameter, and wherein the electrochemical reaction causes a property of the wire to change.

7. The sensor system of claim 6 , wherein the electrochemical reaction comprises a half-reaction in the wire that comprises oxidation of the wire.

8. The sensor system of claim 6 , wherein the electrochemical reaction comprises a half-reaction in the wire that comprises oxidation or reduction that results in an irreversible change in a carrier mobility within the wire.

9. The sensor system of claim 6 , wherein the electrochemical reaction comprises a half-reaction in the wire that generates gas bubbles that mechanically damage the wire and decrease the property of the wire, and wherein the property comprises conductivity.

10. The sensor system of claim 6 , wherein the electrochemical reaction comprises a half-reaction in the wire that comprises an electroplating reaction or an electrodeposition reaction that changes the property of the wire.

11. The sensor system of claim 6 , wherein the electrochemical reaction comprises a half-reaction in the counter-electrode that comprises a reduction reaction.

12. The sensor system of claim 6 , wherein the electrochemical reaction comprises a reduction of poly(3,4-ethylenedioxythiophene) (PEDOT) followed by a substantially irreversible reaction of reduced PEDOT with oxygen.

13. The sensor system of claim 6 , wherein the change in the property is substantially irreversible.

14. The sensor system of claim 6 , wherein the change in the property is at least partially reversible.

15. The sensor system of claim 14 , wherein the property comprises the conductance, wherein the conductance decreases from a first value to a second value in response to a first occurrence of the parameter being outside of the predetermined range, wherein the conductance is configured to subsequently be increased to a third value that is between than the first value and the second value in response to application of a voltage to the memory.

16. The sensor system of claim 1 , wherein a value of the conductance corresponds to a number of the occurrences when the parameter was outside of the predetermined range.

17. The sensor system of claim 1 , wherein the counter-electrode comprises a material that is configured to be oxidized or reduced.

18. The sensor system of claim 1 , wherein the counter-electrode serves as a current-collector that allows the electrolyte or a species dissolved in the electrolyte to be oxidized or reduced.

19. The sensor system of claim 1 , wherein the counter-electrode comprises a redox-active material.

20. The sensor system of claim 19 , wherein the redox-active material comprises ferricyanide, ferrocyanide, iodide, triiodide, viologen and its derivatives, viologen and its derivatives, or a combination thereof.

21. The sensor system of claim 19 , wherein the redox-active material comprises metals and their salts, and wherein the metals comprise silver, aluminum, copper, nickel, or a combination thereof.

22. The sensor system of claim 19 , wherein the redox-active material comprises redox-active inorganic solids, and wherein the redox-active inorganic solids comprise Prussian blue, intercalation materials, metal oxides, metal phosphates, or a combination thereof.

23. The sensor system of claim 1 , wherein the counter-electrode comprises printed PEDOT:PSS.

24. A sensor system, comprising:
a sensor configured to measure a parameter and to output a voltage that is a function of the parameter, wherein the parameter is selected from the group consisting of temperature, pressure, humidity, moisture, vibration, shock, light, oxygen, concentration, pH, and salinity; and
a memory connected to the sensor, wherein the memory comprises:
a wire comprising a metal or a semiconductor;
a counter-electrode comprising a redox-active material; and
an electrolyte in contact with the wire and the counter-electrode,

wherein the wire and the counter-electrode are configured to receive the voltage from the sensor,
wherein the voltage generates an electrical current between the wire and the counter-electrode,
wherein the electrical current causes an electrochemical reaction in the wire, the counter-electrode, or both when the parameter is outside of a predetermined range,
wherein the electrochemical reaction causes corrosion of the wire, which causes a property of the wire to change, and
wherein the property is selected from the group consisting of resistance, conductance, impedance, capacitance, inductance, and color.

25. The sensor system of claim 24 , wherein the changed conductance indicates one or more current or past occurrences when the parameter was outside of the predetermined range.

26. The sensor system of claim 25 , wherein a value of the conductance corresponds to a number of the occurrences when the parameter was outside of the predetermined range.

27. A sensor system, comprising:
a sensor configured to measure a parameter and to output a voltage that is a function of the parameter; and
a memory connected to the sensor, wherein the memory comprises an electrochemical cell, wherein the memory is configured to record one or more past occurrences when the par

Assignees

• Palo Alto Res Ct Inc

Inventors

• Doris Sean E
• Evans Kent

Classifications

• G01N27/403 Primary

  Cells and electrode assemblies · CPC title

• H01B1/02

  mainly consisting of metals or alloys · CPC title

• H01B1/06

  mainly consisting of other non-metallic substances · CPC title

• H10K85/113

  Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene · CPC title

• G11C13/0009

  RRAM elements whose operation depends upon chemical change · CPC title