Engine system with catalytic reactor

Patent metadata

Field	Value
Publication number	US-11674419-B1
Application number	US-202117456497-A
Country	US
Kind code	B1
Filing date	Nov 24, 2021
Priority date	Nov 24, 2021
Publication date	Jun 13, 2023
Grant date	Jun 13, 2023

Abstract

An engine system includes an engine configured to combust liquid natural gas and generate an exhaust gas comprising methane; a catalytic reactor coupled downstream of the engine and configured to convert methane into a product through one or more of oxidative coupling of methane (OCM) reaction and steam methane reforming (SMR) reaction; and a recirculation loop configured to recirculate at least a part of the product back to the engine.

First claim

What is claimed:

1. An engine system comprising:
an engine configured to combust liquid natural gas and generate an exhaust gas comprising methane;
a catalytic reactor coupled downstream of the engine and configured to convert methane into a product through one or more of oxidative coupling of methane (OCM) reaction and steam methane reforming (SMR) reaction; and
a recirculation loop configured to recirculate at least a part of the product back to the engine, wherein the catalytic reactor is configured to convert methane into ethylene through the OCM reaction;
the catalytic reactor further comprises an oxygen permeable membrane to supply oxygen to the catalytic reactor; and
the recirculation loop is configured to recirculate the ethylene in the product to the engine to increase combustion efficiency.

2. The engine system of claim 1 , further comprising a treatment device coupled to the recirculation loop configured to remove carbon dioxide, water, or both, from the product; and
wherein the recirculation loop is configured to recirculate the product to the engine after removal of carbon dioxide, water, or both.

3. The engine system of claim 1 , wherein:
the catalytic reactor is configured to convert methane through the SMR reaction;
the catalytic reactor further comprises a hydrogen permeable membrane; and
the recirculation loop is configured to recirculate hydrogen that permeates through the hydrogen permeable membrane to the engine.

4. The engine system of claim 1 , further comprising a treatment device coupled to the recirculation loop configured to remove carbon dioxide, water, or both from the product;
wherein the catalytic reactor is configured to convert methane through the SMR reaction; and
wherein the recirculation loop is configured to recirculate the product to the engine after removal of carbon dioxide, water, or both.

5. The engine system of claim 1 , wherein:
the catalytic reactor is configured to convert methane through the OCM reaction and the SMR reaction;
the catalytic reactor further comprises a hydrogen permeable membrane; and
the recirculation loop is configured to recirculate hydrogen that permeates through the hydrogen permeable membrane to the engine.

6. The engine system of claim 1 , further comprising a treatment device coupled to the recirculation loop configured to remove carbon dioxide, water, or both, from the product;
wherein the catalytic reactor is configured to convert methane through the OCM reaction and the SMR reaction; and
wherein the recirculation loop is configured to recirculate the product to the engine after removal of carbon dioxide, water, or both.

7. The engine system of claim 1 , wherein the engine type is selected from the group consisting of a dual fuel compression ignition engine and a spark ignited engine.

8. The engine system of claim 1 , further comprising a temperature control device that is configured to control a temperature of the catalytic reactor.

9. The engine system of claim 1 , wherein the catalytic reactor is configured to utilize exhaust energy carried by the exhaust gas for at least one of the OCM reaction and SMR reactions.

10. The engine system of claim 1 , further comprising a water injector that is configured to introduce water into the engine.

11. A vessel comprising the engine system of claim 1 .

12. A method comprising:
operating an engine system such that:
a fuel comprising liquid natural gas is introduced into an engine,
an exhaust gas comprising methane is directed from the engine to a catalytic reactor,
methane is converted to a product through one or more of oxidative coupling of methane (OCM) reaction and steam methane reforming (SMR) reactions, and
at least a part of the product is recirculated to the engine,
wherein oxygen is supplied to the catalytic reactor through an oxygen permeable membrane;
methane is converted to ethylene through the OCM reaction in the catalytic reactor, and
the ethylene in the product is recirculated to the engine to increase combustion efficiency.

13. The method of claim 12 , further comprising operating the engine system such that carbon dioxide, water, or both, are removed from the product;
wherein the product is recirculated to the engine after removing carbon dioxide, water, or both.

14. The method of claim 12 , further comprising operating the engine system such that hydrogen is obtained from the product using a hydrogen permeable membrane;
wherein methane is converted to the product through the SMR reaction, and
wherein hydrogen that permeates the hydrogen permeable membrane is recirculated to the engine.

15. The method of claim 12 , further comprising operating the engine system such that carbon dioxide, water, or both, is removed from the product;
wherein methane is converted to the product through the SMR reaction; and
wherein the product is recirculated to the engine after the removing carbon dioxide, water, or both.

16. The method of claim 12 , further comprising operating the engine system such that hydrogen is obtained from the product using a hydrogen permeable membrane;
wherein methane is converted to the product through the OCM and the SMR reactions, and
wherein hydrogen that permeates the hydrogen permeable membrane is recirculated to the engine.

17. The method of claim 12 , further comprising operating the engine system such that carbon dioxide, water, or both, is removed from the product;
wherein methane is converted to the product through the OCM and the SMR reactions;
wherein the product is recirculated to the engine after the removing carbon dioxide, water, or both.

18. The method of claim 12 , further comprising operating the engine system such that a temperature of a catalytic reactor is controlled utilizing a temperature control system.

19. The method of claim 12 , further comprising operating the engine system such that water is introduced into the engine utilizing a water injector.

Assignees

• Saudi Arabian Oil Co

Inventors

• Raman Vallinayagam
• Choi Seung-Hak
• Chang Junseok

Classifications

• F01N3/10

  by thermal or catalytic conversion of noxious components of exhaust · CPC title

• F01N2570/12

  Hydrocarbons · CPC title

• F01N2610/04

  the substance being hydrogen · CPC title

• F02M26/35

  with means for cleaning or treating the recirculated gases, e.g. catalysts, condensate traps, particle filters or heaters · CPC title

• F01N3/20

  specially adapted for catalytic conversion (F01N3/22 takes precedence) · CPC title