Pyrometallurgical method for obtaining compounds of lithium and intermediates from alpha-spodumene and lepidolite

Patent metadata

Field	Value
Publication number	US-11674199-B2
Application number	US-201816766247-A
Country	US
Kind code	B2
Filing date	Nov 23, 2018
Priority date	Nov 24, 2017
Publication date	Jun 13, 2023
Grant date	Jun 13, 2023

Abstract

Pyrometallurgic process for obtaining lithium compounds and intermediates, the process being characterized by comprising the steps of a) contacting lithium aluminosilicate particles with at least a fluorine solid compound, b) heating until a temperature of 25 to 900° C. obtaining a solid mixture and c) carrying out at least a leaching process of the mixture in step b).

First claim

The invention claimed is:

1. Pyrometallurgic process to obtain lithium compounds and intermediaries, comprising the steps of
a) contacting particles of at least a lithium aluminosilicate with at least a solid fluorine solid compound, selected from the group consisting of NaF, KF or NH 4 HF 2;
b) heating until a temperature of 120° C. to 900° C. obtaining as a product of the reaction a solid mixture comprising at least a compound of the group consisting in lithium fluoride (LiF), albite (NaAlSi 3 O 8 ), nepheline (NaAlSiO 4 ), leucite (KAlSi 2 O 6 ), aluminum fluoride (AlF 3 ) and ammonium hexafluorosilicate ((NH 4 ) 3 SiF 6 );
c) carrying out a leaching process with distilled water of the mixture of step b) to eliminate excess fluorinating agent, NaF, KF or NH 4 HF 2 , and subsequently filter and dry; and
d) carrying out at least the leaching process of the solid mixture obtained in step c) using as leaching agents compounds selected from the group consisting of sodium hydroxide (NaOH), calcium chloride (CaCl 2 ), sulfuric acid (H 2 SO 4 ) and subsequently filter and dry.

2. Process according to claim 1 , wherein at least a lithium aluminosilicate is α-spodumene, lepidolite or a combination thereof.

3. Process according to claim 1 , wherein in step a) the aluminosilicate particles comprise a size between 29 and 200 μm.

4. Process according to claim 1 , wherein the heating of step b) is carried out for a time of 30 to 300 min.

5. Process according to claim 1 , wherein the fluorine solid compound is NaF, and the molar ratio aluminosilicate:NaF is between 1:1 and 1:2.5.

6. Process according to claim 1 , wherein the fluorine solid compound is KF, and the molar ratio aluminosilicate:KF is between 1:1 and 1:2.5.

7. Process according to claim 1 , wherein the fluorine solid compound is NH 4 HF 2 , and the molar ratio aluminosilicate:NH 4 HF 2 is between 1:3.0 and 1:19.

Assignees

• Consejo Nacional De Investigaciones Cientificas Y Tecn Conicet
• Univ Nacional De Cuyo
• Consejo Nacional De Investigaciones Cientificas Y Tecn Conicte

Inventors

• Rodriguez Mario Humberto
• Resentera Beiza Alexander Cristian
• Rosales Gustavo Daniel

Classifications

• C01P2002/72

  by d-values or two theta-values, e.g. as X-ray diagram · CPC title

• C01P2002/88

  by thermal analysis data, e.g. TGA, DTA, DSC · CPC title

• C22B3/08

  Sulfuric acid {, other sulfurated acids or salts thereof} · CPC title

• Y02P10/20

  Recycling · CPC title

• C22B1/02

  Roasting processes (C22B1/16 takes precedence) · CPC title