Synthetic layered magnesium silicates and their derivatives for high performance oil-based drilling fluids

Patent metadata

Field	Value
Publication number	US-11674069-B2
Application number	US-202117395129-A
Country	US
Kind code	B2
Filing date	Aug 5, 2021
Priority date	Sep 4, 2018
Publication date	Jun 13, 2023
Grant date	Jun 13, 2023

Abstract

A method of producing a synthetic functionalized additive including the steps of mixing an amount of a magnesium salt with a fluid medium to produce a magnesium-containing fluid, adding an amount of a silane to the magnesium-containing fluid to produce a reactant mix, adding an amount of an aqueous hydroxide to the reactant mix to produce a reaction mixture, mixing the reaction mixture for a mix period, refluxing the reaction mixture for a reflux period to produce a product mix, treating the product mix to separate the synthetic functionalized additive.

First claim

That which is claimed is:

1. A composition of a synthetic functionalized additive, the composition comprising:
a synthetic layered magnesium silicate, the synthetic layered magnesium silicate comprising:
a first functionalized silicate layer, the first functionalized silicate layer comprising a tetrahedral silicate layer and a functional group,
an octahedral brucite layer, the octahedral brucite layer comprising magnesium oxide/hydroxide, and
a second functionalized silicate layer, the second functionalized silicate layer comprising the tetrahedral silicate layer and the functional group,
where the octahedral brucite layer is positioned between the first functionalized silicate layer and the second functionalized silicate layer; and

the functional group, the functional group covalently bonded to the tetrahedral silicate layer of the first functionalized silicate layer and separately covalently bonded to the tetrahedral silicate layer of the second functionalized silicate layer, where the functional group extends from both the first functionalized silicate layer and the second functionalized silicate layer away from the octahedral brucite layer, where the functional group is selected from the group consisting of saturated alkyl groups having the formula (—CH 2 (CH 2 ) x CH 3 ), where x is an integer between 0 and 18, phenyl groups, amine groups, diamine groups, carboxylate groups, amide groups, acrylate groups, thiol groups, methacrylate groups, isocyanate groups, and combinations of the same.

2. The composition of claim 1 , where a thickness of the synthetic layered magnesium silicate is 1 nanometer, where a lateral dimension of the synthetic layered magnesium silicate is between 2 nm and 5 microns.

3. A method of using a synthetic functionalized additive in a well fluid, the method comprising the steps of:
preparing a well fluid, where the well fluid is selected from aqueous-based fluids, oil-based fluids, and combinations of the same;
adding an amount of the synthetic functionalized additive to the well fluid to produce a rheologically-modified well fluid, where the synthetic functionalized additive comprises:
a synthetic layered magnesium silicate comprising:
a first functionalized silicate layer, the first functionalized silicate layer comprising a tetrahedral silicate layer and a functional group,
an octahedral brucite layer, the octahedral brucite layer comprising magnesium oxide/hydroxide, and
a second functionalized silicate layer, the second functionalized silicate layer comprising the tetrahedral silicate layer and the functional group,
where the octahedral brucite layer is positioned between the first functionalized silicate layer and the second functionalized silicate layer, and

a functional group, where the functional group is covalently bonded to the synthetic layered magnesium silicate, where the functional group is selected from the group consisting of saturated alkyl groups having the formula (—CH 2 (CH 2 ) x CH 3 ), where x is an integer between 0 and 18, phenyl groups, amine groups, diamine groups, and combinations of the same;

subjecting the rheologically-modified well fluid to a shear stress; and
injecting the rheologically-modified well fluid into a well.

4. The method of claim 3 , where the amount of the synthetic functionalized additive in the rheologically-modified well fluid is between 0.1% w/v to 20% w/v.

5. The method of claim 3 , where the rheologically-modified well fluid is operable to exhibit rheologically-independent behavior.

Assignees

• Saudi Arabian Oil Co

Inventors

• Patel Hasmukh
• Santra Ashok
• Thaemlitz Carl

Classifications

• C01B33/325

  After-treatment, e.g. purification or stabilisation of solutions, granulation; Dissolution; Obtaining solid silicate, e.g. from a solution by spray-drying, flashing off water or adding a coagulant · CPC title

• C09K8/22

  Synthetic organic compounds · CPC title

• C07F7/087

  Compounds of unknown structure containing a Si-O-Si sequence · CPC title

• B01J37/036

  to form a gel or a cogel · CPC title

• B01J21/16

  Clays or other mineral silicates · CPC title