Multimodal polyethylene film

Patent metadata

Field	Value
Publication number	US-11674022-B2
Application number	US-201716332046-A
Country	US
Kind code	B2
Filing date	Sep 8, 2017
Priority date	Sep 12, 2016
Publication date	Jun 13, 2023
Grant date	Jun 13, 2023

Abstract

The present invention relates to a multimodal polyethylene composition comprising: (A) 40 to 65 parts by weight, preferably 43 to 52 parts by weight, most preferred 44 to 50 parts by′ weight, of the low molecular weight polyethylene having a weight average molecular weight (Mw) of 20,000 to 90,000 g/mol, wherein the low molecular weight polyethylene has a MI2 of 500 to 1,000 g/10 min according to ASTM D 1238; (B) 5 to 17 parts by weight, preferably 10 to 17 parts by weight, most preferred 10 to 15 parts by weight, of the first high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 150,000 to 1,000,000 g/mol or the first ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 1,000,000 to 5,000,000 g/mol; and (C) 30 to 50 parts by weight, preferably 37 to 47 party by weight, most preferably 39 to 45 parts by weight, of the second high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 150,000 to 1,000,000 g/mol or the second ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 1,000,000 to 5,000,000 g/mol, wherein the density of the first high molecular weight polyethylene or the first ultra high molecular weight polyethylene and the second high molecular weight polyethylene or the second ultra high molecular weight polyethylene is in the same range and both densities are in the range from 0.910 to 0.940 g/cm3; and the molecular weight distribution of the multimodal polyethylene composition is from 18 to 30, preferably 20 to 28, measured by gel permeation chromatography, film comprising the multimodal polyethylene composition and the use thereof.

First claim

The invention claimed is:

1. A multimodal polyethylene composition comprising:
(A) 44 to 50 parts by weight of a low molecular weight polyethylene homopolymer having a weight average molecular weight (Mw) of 49,542 to 53,771 g/mol, wherein the low molecular weight polyethylene has a M2 of 500 to 1,000 g/10 min according to ASTM D 1238;
(B) 10 to 15 parts by weight of a first high molecular weight polyethylene having a weight average molecular weight (Mw) of 998,032 to 999,438 g/mol wherein the first high molecular weight polyethylene is a copolymer of ethylene and 1-butene; and
(C) 39 to 45 parts by weight of a second high molecular weight polyethylene having a weight average molecular weight (Mw) of 199,713 to 212,888 g/mol, wherein the second high molecular weight polyethylene is a copolymer of ethylene and 1-butene,
wherein the density of the first high molecular weight polyethylene and the second high molecular weight polyethylene is in the same range and both densities are in the range from 0.910 to 0.940 g/cm 3 ; and
the polydispersity index (PDI) of the multimodal polyethylene composition is from 22 to 24, measured by gel permeation chromatography.

2. The multimodal polyethylene composition according to claim 1 , wherein the multimodal polyethylene composition has a weight average molecular weight from 150,000 to 400,000 g/mol, measured by Gel Permeation Chromatography.

3. The multimodal polyethylene composition according to claim 1 , wherein the multimodal polyethylene composition has a number average molecular weight from 5,000 to 15,000 g/mol, measured by Gel Permeation Chromatography.

4. The multimodal polyethylene composition according to claim 1 , wherein the multimodal polyethylene composition has a Z average molecular weight from 1,000,000 to 3,000,000 g/mol, measured by Gel Permeation Chromatography.

5. The multimodal polyethylene composition according to claim 1 , wherein the multimodal polyethylene composition has a density of at least 0.940 g/cm 3 , according to ASTM D 1505 and/or MI 2 from 0.03 to 0.10 g/10 min.

6. The multimodal polyethylene composition according to claim 5 , wherein the MI 2 is from 0.03 to 0.08 g/10 min.

7. A film comprising the multimodal polyethylene composition according to claim 1 , wherein the film has a thickness from 40 to 120 μm.

8. An industrial bag or a geomembrane comprising the film according to claim 7 .

9. The multimodal polyethylene composition of claim 1 , wherein the polydispersity index is from 22 to 23.

10. The multimodal polyethylene composition of claim 2 , wherein the weight average molecular weight is from 200,000 to 300,000 g/mol, measured by Gel Permeation Chromatography.

11. The multimodal polyethylene composition of claim 3 , wherein the number average molecular weight is from 7,000 to 13,000 g/mol, measured by Gel Permeation Chromatography.

12. The multimodal polyethylene composition of claim 4 , wherein the Z average molecular weight is from 1,000,000 to 2,500,000 g/mol, measured by Gel Permeation Chromatography.

13. The multimodal polyethylene composition of claim 5 , wherein the density is from 0.940 to 0.948 g/cm 3 , according to ASTM D 1505.

14. The film of claim 7 , having a thickness from 45 to 80 μm.

Assignees

• Thai Polyethylene Co Ltd
• Scg Chemicals Co Ltd

Inventors

• Mattayan Arunsri
• Cheevasrirungruang Watcharee
• Traisilanun Saranya
• Klomkamol Warachad

Classifications

• C08J5/18 Primary

  Manufacture of films or sheets · CPC title

• C08L2203/16

  used for films · CPC title

• C08L23/06 Primary

  Polyethylene · CPC title

• E02D31/004

  Sealing liners · CPC title

• C08L23/0815

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title