Composition for use in additive manufacturing processes

Patent metadata

Field	Value
Publication number	US-11674013-B2
Application number	US-201816756273-A
Country	US
Kind code	B2
Filing date	Oct 12, 2018
Priority date	Oct 16, 2017
Publication date	Jun 13, 2023
Grant date	Jun 13, 2023

Abstract

The present invention relates to a composition comprising at least one polymer system and at least one anti-agglomeration agent, the polymer system being selected from at least one thermoplastic polymer, the bulk density of the composition being more than 300 g/l. Furthermore, the present invention relates to a method for producing the composition according to the invention and its use.

First claim

The invention claimed is:

1. A composition comprising:
at least one polymer system; and
at least two anti-agglomeration agents,
wherein the polymer system is selected from at least one member from the group consisting of at least one thermoplastic polymer, the thermoplastic polymer being selected from polyetherimide, polycarbonate, polyphenylene sulfone, polyphenylene oxide, polyether sulfone, acrylonitrile-butadiene-styrene copolymer (ABS), acrylonitrile-styrene-acrylate copolymer (ASA), polyvinyl chloride, polyacrylate, polyester, polyamide, polyaryl ether ketone, polyether, polyurethane, polyimide, polyamide imide and polyolefin;
wherein the bulk density of the composition being at least 300 g/l, and/or the bulk density is up to about 550 g/l;
wherein a first anti-agglomeration agent comprises silicon dioxide, and wherein particles of the first anti-agglomeration agent are modified with at least one hydrophobizing agent based on at least one organosilane;
wherein a second anti-agglomeration agent comprises silicon dioxide, and wherein particles of the second anti-agglomeration agent are modified with at least one hydrophobizing agent based on at least one organosilane, and
the proportion by weight of the at least two anti-agglomeration agents is in total at most about 1%, and the first and second anti-agglomeration agents are further functionalized with amino, amide, and/or quaternary ammonium end groups.

2. The composition according to claim 1 , wherein the particles of the first anti-agglomeration agent are modified with a first hydrophobizing agent which is selected from at least one member from the group consisting of alkoxysilane, silazane and siloxane.

3. The composition according to claim 1 , wherein the particles of the second anti-agglomeration agent are modified with a second hydrophobizing agent which is selected from at least one member from the group consisting of alkoxysilane, silazane and siloxane.

4. The composition according to claim 1 , wherein the first and the second anti-agglomeration agents have a weight ratio of at least about 1:1.

5. The composition according to claim 1 , wherein the at least two anti-agglomeration agents have a BET surface area of at least about 200 m 2 /g, and/or wherein the BET surface area of the at least two anti-agglomeration agents is at most about 350 m 2 /g.

6. The composition according to claim 1 , wherein the at least two anti-agglomeration agents have an average diameter of agglomerate particles d50 of at least about 100 nm, and/or wherein the average diameter of the agglomerate particles d50 is at most about 500 nm.

7. The composition according to claim 1 , wherein an average diameter of the particles d50 of the at least one polymer system to the average diameter of the agglomerate particles d50 of the at least two anti-agglomeration agents has a ratio of at least about 100:1, and/or wherein the ratio of the average diameter of the particles d50 of the at least one polymer system to the average diameter of the agglomerate particles d50 of the at least two anti-agglomeration agents is at most about 5000:1.

8. The composition according to claim 1 , wherein the polymer system is a thermoplastic polyurethane.

9. The composition according to claim 1 , wherein a melting point of the composition is at least about 100° C. and/or at most about 200° C.

10. The composition according to claim 1 , wherein the composition has a tensile strength of at least about 5 MPa, and/or at most about 150 MPa, and an elongation at break of at least about 1%.

11. The composition according to claim 1 , further comprising at least one additive.

12. A method of producing the composition according to claim 1 , the method comprising the following steps:
providing at least one polymer system, the at least one polymer system being selected from at least one member from the group consisting of at least one thermoplastic polymer, the thermoplastic polymer being selected from polyetherimide, polycarbonate, polyphenylene sulfone, polyphenylene oxide, polyether sulfone, acrylonitrile-butadiene-styrene copolymer (ABS), acrylonitrile-styrene-acrylate copolymer (ASA), polyvinyl chloride, polyacrylate, polyester, polyamide, polyaryl ether ketone, polyether, polyurethane, polyimide, polyamide imide and polyolefin;
adding first and second anti-agglomeration agents; and
mixing the at least one polymer system with the first and second anti-agglomeration agents.

13. A method for producing a three-dimensional object by applying layers and selectively solidifying a construction material, the method comprising the following steps:
providing the construction material as the composition produced by the method according to claim 12 ;
applying a layer of the construction material to a construction field;
selectively solidifying the applied layer of the construction material at locations corresponding to a cross section of the three-dimensional object to be produced; and
lowering a carrier of an additive manufacturing machine and repeating the steps of applying and solidifying until the three-dimensional object is completed.

14. A three-dimensional object obtained by the method according to claim 13 .

15. The composition according to claim 1 ,
wherein the composition is implemented in additive manufacturing processes.

Assignees

• Eos Gmbh Electro Optical Systems

Inventors

• Gessler Monika
• Paternoster Stefan
• Froehlich Daniel

Classifications

• B29K2101/12

  Thermoplastic materials · CPC title

• B33Y70/00

  Materials specially adapted for additive manufacturing · CPC title

• B29K2075/00

  Use of {PU, i.e.} polyureas or polyurethanes {or derivatives thereof}, as moulding material · CPC title

• C08K5/56

  Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title