Catalyst for oxidative coupling reaction of methane, method for preparing the same, and method for oxidative coupling reaction of methane using the same

Patent metadata

Field	Value
Publication number	US-11673121-B2
Application number	US-202117553795-A
Country	US
Kind code	B2
Filing date	Dec 17, 2021
Priority date	Dec 28, 2020
Publication date	Jun 13, 2023
Grant date	Jun 13, 2023

Abstract

Disclosed are a catalyst for oxidative coupling reaction of methane, a method for preparing the same, and a method for oxidative coupling reaction of methane using the same. The catalyst includes a mixed metal oxide, which is a mixed oxide of metals including sodium (Na), tungsten (W), manganese (Mn), barium (Ba) and titanium (Ti). It is possible to obtain paraffins, such as ethane and propane, and olefins, such as ethylene and propylene, with high efficiency through the method for oxidative coupling reaction of methane using the catalyst.

First claim

The invention claimed is:

1. A catalyst for oxidative coupling reaction of methane, comprising a mixed metal oxide, which is a mixed oxide of metals comprising sodium (Na), tungsten (W), manganese (Mn), barium (Ba) and titanium (Ti); wherein the elemental ratio of Mn/Na is 1.0 or more.

2. The catalyst for oxidative coupling reaction of methane according to claim 1 , wherein the elemental ratio of W/Ti is 0.04 to 0.44.

3. The catalyst for oxidative coupling reaction of methane according to claim 1 , wherein the elemental ratio of Mn/Ti is 0.30 to 2.85.

4. The catalyst for oxidative coupling reaction of methane according to claim 1 , wherein the elemental ratio of Ba/Ti is 0.8 to 1.5.

5. The catalyst for oxidative coupling reaction of methane according to claim 1 , wherein the elemental ratio of Mn/Na is 1.5 or more.

6. A catalyst for oxidative coupling reaction of methane, comprising a mixed metal oxide, which is a mixed oxide of metals comprising sodium (Na), tungsten (W), manganese (Mn), barium (Ba) and titanium (Ti);
wherein the elemental ratio of Mn/Na is 1.0 or more;
wherein the elemental ratio of Mn/Ti is 0.32 to 0.65; and
wherein the elemental ratio of W/Ti is 0.1 to 0.49.

7. A method for preparing the catalyst for oxidative coupling reaction of methane according to claim 1 , comprising the steps of:
mixing and heating an aqueous precursor solution of sodium (Na), tungsten (W), manganese (Mn), barium (Ba) and titanium (Ti) metals with an organic acid to prepare a gel;
drying and pulverizing the gel-like mixture to obtain a pulverized product; and
baking the pulverized product to obtain the catalyst.

8. The method for preparing the catalyst for oxidative coupling reaction of methane according to claim 7 , wherein the organic acid comprises citric acid.

9. The method for preparing the catalyst for oxidative coupling reaction of methane according to claim 7 , wherein the drying is carried out at 50-150° C.

10. The method for preparing the catalyst for oxidative coupling reaction of methane according to claim 7 , wherein the baking is carried out at 800-900° C.

11. The method for preparing the catalyst for oxidative coupling reaction of methane according to claim 7 , wherein the elemental ratio of Mn/Ti is 0.32 to 0.65, and the elemental ratio of W/Ti is 0.1 to 0.49.

12. A method for oxidative coupling reaction of methane, comprising contacting methane with the catalyst for oxidative coupling reaction of methane according to claim 1 to obtain hydrocarbon compounds containing two or more carbon atoms from methane.

13. The method for oxidative coupling reaction of methane according to claim 12 , which comprises the steps of:
introducing a reaction mixture comprising methane, oxygen and inert gas and the catalyst for oxidative coupling reaction of methane into a reactor; and
carrying out oxidative coupling reaction of methane.

14. The method for oxidative coupling reaction of methane according to claim 13 , wherein the oxidative coupling reaction of methane is carried out at 600 to 850° C.

Assignees

• Korea Inst Sci & Tech

Inventors

• Ha Jeong-Myeong
• Do Lien Thi
• Choi Jae Wook
• Suh Dong Jin
• Yoon Young Hyun
• Yang Gi Seok
• Lee Hyun Joo

Classifications

• B01J37/04

  Mixing {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• C07C2523/02

  of the alkali- or alkaline earth metals or beryllium · CPC title

• C07C2/84

  catalytic · CPC title

• C07C2523/30

  Tungsten · CPC title

• B01J37/036

  to form a gel or a cogel · CPC title