Metal support for electrochemical element, electrochemical element, electrochemical module, electrochemical device, energy system, solid oxide fuel cell, solid oxide electrolytic cell, and method for manufacturing metal support

Patent metadata

Field	Value
Publication number	US-11670779-B2
Application number	US-201917044094-A
Country	US
Kind code	B2
Filing date	Mar 29, 2019
Priority date	Mar 30, 2018
Publication date	Jun 6, 2023
Grant date	Jun 6, 2023

Abstract

A metal support for an electrochemical element has a plate shape as a whole, and is provided with a plurality of penetration spaces that pass through the metal support from a front face to a back face. The front face is a face to be provided with an electrode layer. Each of front-side openings that are openings of the penetration spaces formed in the front face has an area of 3.0×10−4 mm2 or more and 3.0×10−3 mm2 or less.

First claim

The invention claimed is:

1. A solid oxide fuel cell comprising:
an electrochemical element including a metal support, an electrode layer, an electrolyte layer, and a counter electrode layer,
wherein the metal support has a plate shape,
the electrode layer, the electrolyte layer, and the counter electrode layer are provided on/over a front face of the metal support,
the metal support is provided with a plurality of penetration spaces that pass through the metal support from the front face to a back face,
each front-side opening that is an opening of the penetration spaces formed in the front face has an area of 3.0×10 −4 mm 2 or more and 3.0×10 −3 mm 2 or less,
intervals between the front-side openings are 0.05 mm or more and 0.3 mm or less, and
a power generation reaction is caused in the electrochemical element.

2. A solid oxide electrolytic cell comprising:
an electrochemical element including a metal support, an electrode layer, an electrolyte layer, and a counter electrode layer,
wherein the metal support has a plate shape,
the electrode layer, the electrolyte layer, and the counter electrode layer are provided on/over a front face of the metal support,
the metal support is provided with a plurality of penetration spaces that pass through the metal support from the front face to a back face,
each front-side opening that is an opening of the penetration spaces formed in the front face has an area of 3.0×10 −4 mm 2 or more and 3.0×10 −3 mm 2 or less,
intervals between the front-side openings are 0.05 mm or more and 0.3 mm or less, and
an electrolytic reaction is caused in the electrochemical element.

3. The solid oxide fuel cell according to claim 1 , wherein each of the front-side openings has a circular shape or a substantially circular shape having a diameter of 20 μm or more and 60 μm or less.

4. The solid oxide fuel cell according to claim 1 , wherein each of back-side openings that are openings of the penetration spaces formed in the back face has an area or a diameter larger than those of the front-side openings.

5. The solid oxide fuel cell according to claim 1 , wherein the metal support has a thickness of 0.1 mm or more and 1.0 mm or less.

6. The solid oxide fuel cell according to claim 1 , wherein the metal support is formed by stacking a plurality of metal plates.

7. The solid oxide fuel cell according to claim 1 , wherein the metal support is formed by stacking a plurality of metal plates having the same thickness or substantially the same thickness.

8. The solid oxide fuel cell according to claim 1 , wherein the metal support is formed by stacking a plurality of metal plates including a first metal plate that is a plate made of metal, and a second metal plate that is a plate made of metal and is thicker than the first metal plate, the first metal plate being arranged closer to the front face than the second metal plate is.

9. The solid oxide fuel cell according to claim 1 , wherein the metal support is made of a Fe—Cr based alloy.

10. The solid oxide fuel cell according to claim 1 , wherein at least a portion of the front face is covered by a metal oxide film.

11. The solid oxide electrolytic cell according to claim 2 , wherein each of the front-side openings has a circular shape or a substantially circular shape having a diameter of 20 μm or more and 60 μm or less.

12. The solid oxide electrolytic cell according to claim 2 , wherein each of back-side openings that are openings of the penetration spaces formed in the back face has an area or a diameter larger than those of the front-side openings.

13. The solid oxide electrolytic cell according to claim 2 , wherein the metal support has a thickness of 0.1 mm or more and 1.0 mm or less.

14. The solid oxide electrolytic cell according to claim 2 , wherein the metal support is formed by stacking a plurality of metal plates.

15. The solid oxide electrolytic cell according to claim 2 , wherein the metal support is formed by stacking a plurality of metal plates having the same thickness or substantially the same thickness.

16. The solid oxide electrolytic cell according to claim 2 , wherein the metal support is formed by stacking a plurality of metal plates including a first metal plate that is a plate made of metal, and a second metal plate that is a plate made of metal and is thicker than the first metal plate, the first metal plate being arranged closer to the front face than the second metal plate is.

17. The solid oxide electrolytic cell according to claim 2 , wherein the metal support is made of a Fe—Cr based alloy.

18. The solid oxide electrolytic cell according to claim 2 , wherein at least a portion of the front face is covered by a metal oxide film.

Assignees

• Osaka Gas Co Ltd

Inventors

• Echigo Mitsuaki
• Ohnishi Hisao
• Minami Kazuyuki
• Tsuda Yuji
• Manabe Kyohei
• Yamazaki Osamu

Classifications

• H01M8/0258

  characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant · CPC title

• H01M8/04014

  Heat exchange using gaseous fluids; Heat exchange by combustion of reactants · CPC title

• H01M8/1226

  characterised by the supporting layer · CPC title

• H01M8/0245

  in the form of layered or coated products · CPC title

• C25B13/04

  characterised by the material · CPC title