Cathode for metal-air battery including spaces for accommodating metal oxides formed during discharge of metal-air battery and metal-air battery including the same

Patent metadata

Field	Value
Publication number	US-11670752-B2
Application number	US-202017120633-A
Country	US
Kind code	B2
Filing date	Dec 14, 2020
Priority date	Nov 1, 2016
Publication date	Jun 6, 2023
Grant date	Jun 6, 2023

Abstract

Provided is a metal-air battery including a cathode having a space which may be filled with a metal oxide formed during a discharge of the metal-air battery and thus having improved energy density and lifespan. The cathode for the metal-air battery includes a plurality of cathode materials, a plurality of electrolyte films disposed on surfaces of the plurality of cathode materials, and a plurality of spaces which are not occupied by the plurality of cathode materials and the plurality of electrolyte films. A volume of the plurality of spaces may be greater than or equal to a maximum space of a metal oxide formed during a discharge of the metal-air battery.

First claim

What is claimed is:

1. A cathode for a metal-air battery, the cathode comprising:
a plurality of cathode materials, each of the plurality of cathode materials having a cylindrical or cone shape and using oxygen as an active material; and
a plurality of electrolyte films, each of the plurality of electrolyte films being disposed on an outer circumferential surface of a corresponding one of the plurality of cathode materials;
wherein a space, which is not occupied by the plurality of cathode materials and the plurality of electrolyte films, is defined between the plurality of electrolyte films,
wherein the plurality of cathode materials is spaced apart from each other by a predetermined distance,
wherein each of the plurality of cathode materials has a diameter of 150 nm or less, and
wherein each of the plurality of electrolyte films has a thickness of 10 nm or less.

2. The cathode of claim 1 , wherein the plurality of electrolyte films are formed of an organic material.

3. The cathode of claim 1 , wherein a volume of the space is equal to or less than 120% of a predetermined volume.

4. The cathode of claim 1 , wherein a distance between adjacent electrolyte films, among the plurality of electrolyte films, facing each other in a direction connecting centers of two adjacent cathode materials, among the plurality of cathode materials, is greater than 20 nm.

5. The cathode of claim 1 , wherein the plurality of cathode materials are regularly arranged.

6. The cathode of claim 1 , wherein each of the plurality of cathode materials comprises carbon nanotubes.

7. The cathode of claim 1 , wherein the plurality of cathode materials are arranged at a density greater than about 10 9 /cm 2 .

8. A metal-air battery comprising:
a cathode comprising a plurality of cathode materials and a plurality of electrolyte films, each of the plurality of cathode materials having a cylindrical or cone shape and using oxygen as an active material, and each of the plurality of electrolyte films being disposed on an outer circumferential surface of a corresponding one of the plurality of cathode materials;
an anode metal layer configured to supply metal ions to the plurality of cathode materials; and
a gas diffusion layer configured to supply oxygen to the plurality of cathode materials,
wherein a space, which is not occupied by the plurality of cathode materials and the plurality of electrolyte films, is defined between the plurality of electrolyte films,
wherein the plurality of cathode materials is spaced apart from each other by a predetermined distance,
wherein a volume of the space is greater than or equal to a maximum volume of a product formed between each of the plurality of cathode materials and a corresponding one of the plurality of electrolyte films during a discharge of the metal-air battery,
wherein each of the anode metal layer and the gas diffusion layer has a flat panel form and the anode metal layer and the gas diffusion layer are disposed in parallel to each other,
wherein the plurality of cathode materials are arranged between the anode metal layer and the gas diffusion layer to be perpendicular to a surface of the anode metal layer
wherein each of the plurality of cathode materials has a diameter of 150 nm or less, and
wherein each of the plurality of electrolyte films ahs a thickness of 10 nm or less.

9. The metal-air battery of claim 8 , wherein the volume of the space is equal to or less than 120% of the maximum volume of the product.

10. The metal-air battery of claim 8 , wherein a distance between adjacent electrolyte films facing each other in a direction connecting centers of two adjacent cathode materials is greater than 20 nm.

11. The metal-air battery of claim 8 , wherein each of a plurality of electrolyte films of the cathode comprises:
a first electrolyte portion disposed on a top surface of the anode metal layer; and
a second electrolyte portion extending from the first electrolyte portion to the outer circumferential surface of one of the plurality of cathode materials.

12. The metal-air battery of claim 11 , further comprising a third electrolyte portion which transmits metal ions and blocks moisture and oxygen,
wherein the third electrolyte portion is disposed between the first electrolyte portion and the anode metal layer.

13. The metal-air battery of claim 8 , wherein the plurality of electrolyte films are formed of an organic material.

14. The metal-air battery of claim 11 , wherein the plurality of cathode materials are arranged in a way such that each of first end portions thereof is in contact with a corresponding one of the first electrolyte portions and second end portions thereof are in contact with the gas diffusion layer.

15. The metal-air battery of claim 8 , wherein the plurality of cathode materials are regularly arranged.

16. The metal-air battery of claim 8 , wherein each of the plurality of cathode materials comprises carbon nanotubes.

17. The metal-air battery of claim 8 , wherein the plurality of cathode materials are arranged at a density greater than about 10 9 /cm 2 .

Assignees

• Samsung Electronics Co Ltd

Inventors

• Lee Heungchan
• Im Dongmin
• Lee Hyunpyo

Classifications

• H01M4/8626 Primary

  characterised by the form · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M12/08 Primary

  composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type · CPC title

• H01M2004/8689

  Positive electrodes · CPC title

• H01M4/96 Primary

  Carbon-based electrodes · CPC title