Systems, devices and methods for amplification of signals based on a cycling excitation process in disordered materials

Patent metadata

Field	Value
Publication number	US-11670731-B2
Application number	US-201816486482-A
Country	US
Kind code	B2
Filing date	Feb 13, 2018
Priority date	Feb 16, 2017
Publication date	Jun 6, 2023
Grant date	Jun 6, 2023

Abstract

Methods, systems, and devices are disclosed for low noise and high efficiency photoelectric amplification based on cycling excitation process (CEP). In some aspects, a device for amplifying signals of light-induced photocurrent includes an anode connected to a positive terminal of a voltage source; a disordered material layer coupled to the anode, wherein the disordered material layer is structured to have a thickness of 100 nm or less; and a cathode coupled to the disordered material layer and connected to a negative terminal of the voltage source, in which the device is operable to amplify photoexcited carriers based on photon absorption to produce an external quantum efficiency of the device that is at least 100%.

First claim

What is claimed is:

1. A device for amplifying signals of light-induced photocurrent, comprising:
an anode in electrical contact with a positive terminal of a voltage source;
a cathode in electrical contact with a negative terminal of the voltage source;
a disordered material layer coupled to the cathode, wherein the disordered material layer is structured to have a thickness of 100 nm or less;
and a light absorption layer coupled to the disordered material layer and coupled to the anode, wherein a first electron affinity of the light absorption layer is lower than a second electron affinity of the disordered material layer, and a first sum of the first electron affinity and a first bandgap of the light absorption layer is lower than a second sum of the second electron affinity and a second bandgap of the disordered material layer, the light absorption layer absorbs light incident on the device and causes amplification via a cycling excitation process (CEP) amplification mechanism, wherein the light absorption layer and the disordered material layer are coupled to have a bandgap alignment between the light absorption layer and the disordered material layer that causes an external quantum efficiency of a charge carrier transport between the light absorption layer and the disordered material layer of at least 100%.

2. The device of claim 1 , wherein the disordered material layer is structured to have a density of localized energy states between the second bandgap or at bandtails of a conduction band and a valence band of at least 1×10 18 cm −3 .

3. The device of claim 1 , wherein the CEP amplification mechanism amplifies an electrical signal converted from photons absorbed by the device with a gain of at least 10.

4. The device of claim 1 , wherein the device is operable to convert photons absorbed by the device to an electrical signal amplified across the disordered material layer by the CEP amplification mechanism to produce the external quantum efficiency of charge carriers between the light absorption layer and the disordered material layer of at least 100%.

5. The device of claim 1 , wherein the voltage source is configured to supply a bias potential of 10 V or less between the anode and the cathode.

6. The device of claim 1 , wherein the disordered material includes an amorphous semiconductor material.

7. The device of claim 6 , wherein the amorphous semiconductor material includes an intrinsically disordered material or material that has been modified to introduce disorder.

8. The device of claim 7 , wherein the amorphous semiconductor material includes a hydrogenated amorphous Silicon (a-Si:H).

9. The device of claim 6 , wherein the amorphous semiconductor material includes amorphous Si (a-Si), amorphous SiGe (a-SiGe), amorphous GaAs (a-GaAs), amorphous InP (a-InP), amorphous GaN (a-GaN), amorphous MN (a-AlN), amorphous BN (a-BN), or amorphous SiC (a-SiC).

10. The device of claim 6 , wherein the amorphous semiconductor material is further doped with nitrogen (N).

11. The device of claim 1 , wherein the disordered material includes a polymer material.

12. The device of claim 11 , wherein the polymer material includes P3HT Poly(3-hexylthiophene-2,5-diyl), PDBT, polyphenylene vinylene (PPV), PCE, PDPP-DTT, PTAA, Alq3, phenyl-C61-butyric acid methyl ester (PCBM), pentacene, triphenyl diamin (TPD) derivatives of carbazole, or phthalocyanine.

13. The device of claim 1 , wherein the disordered material layer has a thickness in a range of 30 nm to 60 nm.

14. The device of claim 1 , wherein the device is operable to detect a single photon and produce a corresponding electrical signal.

15. The device of claim 1 , wherein the device is operable to reduce noise associated with dark current to 30 nA or less at a 3 V reverse bias.

16. The device of claim 1 , wherein the disordered material layer includes a carbon-doped semiconductor layer, and the carbon-doped semiconductor layer includes a Carbon dopant having a percentage of the Carbon dopant in the disordered material layer that is more than 0% and less than 5%.

17. The device of claim 1 , wherein the disordered material layer comprises Germanium.

18. The device of claim 1 , wherein the disordered material comprises Silicon.

19. The device of claim 1 , comprising a layer including Copper (I) Oxide (Cu 2 O) or Nickel (II) Oxide (NiO).

20. The device of claim 1 , wherein the disordered material layer is formed on a mesa structure.

21. The device of claim 1 , wherein the voltage source is configured to supply a voltage bias potential of at least 4 V between the anode and the cathode to obtain a CEP gain.

22. A device, comprising:
an anode contact layer;
a cathode contact layer;
a disordered material layer coupled to the cathode contact layer; and
a light absorption layer coupled to the disordered material layer and coupled to the anode contact layer, wherein a first electron affinity of the light absorption layer is lower than a second electron affinity of the disordered material layer, and a first sum of the first electron affinity and a first bandgap of the light absorption layer is lower than a second sum of the second electron affinity and a second bandgap of the disordered material layer, the light absorption layer absorbs a light incident on the device and causes photoelectric signal amplification via a carrier multiplication process, wherein the first bandgap of the coupled light absorption layer is aligned with the second bandgap of the disordered material layer, wherein no additional intervening layers lie between any two of the anode contact layer, the cathode contact layer, the disordered material layer, and the light absorption layer.

23. The device of claim 22 , wherein the bandgap aligned between the light absorption layer and the disordered material layer causes a transport of carriers between the light absorption layer and the disordered material layer.

24. The device of claim 23 , wherein the carrier multiplication process includes a cycling excitation amplification (CEP) mechanism.

25. The device of claim 23 , wherein the transport of carriers between the light absorption layer and the disordered material layer has an external quantum efficiency of at least 100%.

26. The device of claim 22 , wherein the device amplifies a photocurrent induced by the light incident on the device.

27. The device of claim 22 , wherein the disordered material layer includes a carbon-doped semiconductor layer, and wherein the carbon doped semiconductor enables a phonon-assisted excitation of localized carriers into a mobile band of the disordered material layer.

28. The device of claim 22 , wherein the disordered material layer includes a carbon doped semiconductor layer, and wherein the carbon-doped semiconductor layer includes a Carbon dopant having a percentage of the Carbon dopant in the disordered material layer that is more than 0% and less than 5%.

29. The device of claim 22 , wherein the disordered material layer comprises one or both of Germanium and Silicon.

Assignees

• Univ California
• The Regents Of The Unversity Of California

Inventors

• Lo Yu-Hwa
• Hall David
• Liu Yu-Hsin
• Xu Zihan
• Yan Lujiang

Classifications

• Y02E10/549

  Organic PV cells · CPC title

• H10K30/10

  comprising heterojunctions between organic semiconductors and inorganic semiconductors · CPC title

• H10F30/2255

  in which the active layers form heterostructures, e.g. SAM structures · CPC title

• H10F77/206 Primary

  for devices having potential barriers · CPC title

• H10F77/1665

  including Group IV-IV materials, e.g. SiGe or SiC · CPC title