Polar solvent solution and production method thereof

Patent metadata

Field	Value
Publication number	US-11668024-B2
Application number	US-202016740106-A
Country	US
Kind code	B2
Filing date	Jan 10, 2020
Priority date	Apr 9, 2015
Publication date	Jun 6, 2023
Grant date	Jun 6, 2023

Abstract

A polar solvent solution of the present invention is a polar solvent solution in which a solute containing a polyamine acid is dissolved in a polar solvent. The solution has a moisture content of less than 5 mass % based on 100 mass % of the solution. A method for producing a polar solvent solution of the present invention includes changing a moisture content of the solution to adjust the viscosity of the solution. Further, another method for producing a polar solvent solution includes reducing a moisture content of the solution to increase the viscosity of the solution. Thus, the present invention provides a polar solvent solution that enables stable spinning and casting without lowering its viscosity when used as dopes for spinning, film, etc., and methods for producing the same.

First claim

The invention claimed is:

1. A method for producing a polar solvent solution in which a solute containing a polyamino acid is dissolved in a polar solvent, comprising:
changing a water content of the solution to adjust the viscosity of the solution,
wherein the solution has a water content of less than 5% by mass based on 100% by mass of the solution, and
the polar solvent comprises at least one selected from the group consisting of dimethylsulfoxide (DMSO), N,N-dimethylformamide (DMF), N,N-dimethylacetamide (DMA), and N-methyl-2-pyrrolidone (NMP).

2. A method for producing a polar solvent solution in which a solute containing a polyamino acid is dissolved in a polar solvent, comprising:
reducing a water content of the solution to increase the viscosity of the solution,
wherein the solution has a water content of less than 5% by mass based on 100% by mass of the solution, and
the polar solvent comprises at least one selected from the group consisting of dimethylsulfoxide (DMSO), N,N-dimethylformamide (DMF), N,N-dimethylacetamide (DMA), and N-methyl-2-pyrrolidone (NMP).

3. The method for producing a polar solvent solution according to claim 1 , wherein the polyamino acid is a polypeptide.

4. The method for producing a polar solvent solution according to claim 1 , wherein the solute containing the polyamino acid is dried to reduce a water content of the solute, prior to dissolving the solute in the polar solvent.

5. The method for producing a polar solvent solution according to claim 1 , wherein the water content of the solution is changed by adjusting a relative humidity of an atmosphere in the production and/or storage of the solution.

6. The method for producing a polar solvent solution according to claim 5 , wherein the relative humidity of the atmosphere in the production and/or storage of the solution is adjusted to 1.3% RH or less.

7. The method for producing a polar solvent solution according to claim 2 , wherein the polyamino acid is a polypeptide.

8. The method for producing a polar solvent solution according to claim 2 , wherein the solute containing the polyamino acid is dried to reduce a water content of the solute, prior to dissolving the solute in the polar solvent.

9. The method for producing a polar solvent solution according to claim 2 , wherein the water content of the solution is changed by adjusting a relative humidity of an atmosphere in the production and/or storage of the solution.

10. The method for producing a polar solvent solution according to claim 9 , wherein the relative humidity of the atmosphere in the production and/or storage of the solution is adjusted to 1.3% RH or less.

11. The method for producing a polar solvent solution according to claim 1 , wherein the solution exhibits at least one of the following viscosity properties (a) to (f):
(a) a viscosity in a range from 100 to 434 mPa·s at 25° C.;
(b) a viscosity in a range from 100 to 333 mPa·s at 30° C.;
(c) a viscosity in a range from 100 to 221 mPa·s at 40° C.;
(d) a viscosity in a range from 89 to 153 mPa·s at 50° C.;
(e) a viscosity in a range from 63 to 110 mPa·s at 60° C.; and
(f) a viscosity in a range from 49 to 82 mPa·s at 70° C.

12. The method for producing a polar solvent solution according to claim 2 , wherein the solution exhibits at least one of the following viscosity properties (a) to (f):
(a) a viscosity in a range from 100 to 434 mPa·s at 25° C.;
(b) a viscosity in a range from 100 to 333 mPa·s at 30° C.;
(c) a viscosity in a range from 100 to 221 mPa·s at 40° C.;
(d) a viscosity in a range from 89 to 153 mPa·s at 50° C.;
(e) a viscosity in a range from 63 to 110 mPa·s at 60° C.; and
(f) a viscosity in a range from 49 to 82 mPa·s at 70° C.

Assignees

• Spiber Inc

Inventors

• ISHIDA Kana
• Yamamoto Hironori
• SUZUMURA Hiroaki
• Sekiyama Kazuhide

Classifications

• C07K14/43518 Primary

  from spiders · CPC title

• C08J3/091

  characterised by the chemical constitution of the organic liquid · CPC title

• D01F6/68

  from polyaminoacids or polypeptides · CPC title

• D01D1/02

  Preparation of spinning solutions · CPC title

• D01C3/00

  Treatment of animal material, e.g. chemical scouring of wool · CPC title