Copolyester including cyclic aliphatic unit, method of preparing the same, and optical film with low water absorption and low birefringence including the same

Patent metadata

Field	Value
Publication number	US-11667752-B2
Application number	US-202016992319-A
Country	US
Kind code	B2
Filing date	Aug 13, 2020
Priority date	Oct 11, 2019
Publication date	Jun 6, 2023
Grant date	Jun 6, 2023

Abstract

The present disclosure relates to a copolyester including a polymer formed by polymerization of monomers represented by the following Structural Formula 1 to Structural Formula 4:(in the above Structural Formula 1 to Structural Formula 4, R1 to R18 are identical to or different from each other and are each independently selected from the group consisting of H, substituted or unsubstituted linear or branched C1-C20 alkyl and substituted or unsubstituted C6-C20 aryl).

First claim

We claim:

1. A copolyester represented by one of the following Structural Formula 10 to 21:

wherein, R 1 to R 18 are identical to or different from each other and are each independently selected from the group consisting of H, substituted or unsubstituted linear or branched C 1 -C 20 alkyl and substituted or unsubstituted C 6 -C 20 aryl; k, l, m and n are each independently greater than 0 and less than 10; a sum of k, l, m and n is 10; and p is from 1 to 1,000,000.

2. A method of preparing the copolyester of claim 1 , comprising:
preparing a prepolymer by esterification of monomers represented by the following Structural Formula 1 to Structural Formula 4; and
preparing the copolyester by condensation of the prepolymer and a catalyst:

3. The method of claim 2 ,
wherein the esterification is performed at 200° C. to 300° C.

4. The method of claim 2 ,
wherein the catalyst comprises a member selected from the group consisting of titanium butoxide, titanium methoxide, titanium ethoxide, titanium propoxide, titanium isopropoxide, titanium 2-ethylhexoxide, tantalum pentoxide, zirconium butoxide and combinations thereof.

5. The method of claim 2 ,
wherein in the condensation, a thermal stabilizer is added.

6. The method of claim 5 ,
wherein the thermal stabilizer comprises an inorganic phosphoric acid selected from the group consisting of phosphorous acid, phosphoric acid and combinations thereof or an organic phosphoric acid ester selected from the group consisting of dibutyl phosphoric acid, tributyl phosphoric acid, trioctyl phosphoric acid, triphenyl phosphoric acid, triphenyl phosphorous acid and combinations thereof.

7. The method of claim 2 ,
wherein the condensation is performed under a pressure of 0.1 torr to 1 torr.

8. The method of claim 2 ,
wherein the condensation is performed at a temperature of 200° C. to 400° C.

9. The method of claim 2 ,
wherein in the esterification, the monomers represented by the Structural Formula 1 and Structural Formula 2 and the monomers represented by the Structural Formula 3 and Structural Formula 4 are added at a molar ratio in the range of 1:1 to 2:1.

10. The method of claim 2 ,
wherein, after the condensation is completed, solid state polymerization is further performed.

11. An optical film comprising the copolyester of claim 1 .

Assignees

• Research & Business Found Sungkyunkwan Univ

Inventors

• Kim Jinhwan
• Kang Soo-Jung
• Park Sangwon
• Jeong Jae Min

Classifications

• C08G63/199

  Acids or hydroxy compounds containing cycloaliphatic rings · CPC title

• C08G63/80

  Solid-state polycondensation · CPC title

• C08G63/85 Primary

  Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof {(C08G63/823 takes precedence)} · CPC title

• C08K3/32

  Phosphorus-containing compounds · CPC title

• C08G63/672 Primary

  Dicarboxylic acids and dihydroxy compounds · CPC title