Nickel-carbon and nickel-cobalt-carbon brazes and brazing processes for joining ceramics and metals and semiconductor processing and industrial equipment using same

Patent metadata

Field	Value
Publication number	US-11666993-B2
Application number	US-201916423626-A
Country	US
Kind code	B2
Filing date	May 28, 2019
Priority date	Jun 13, 2018
Publication date	Jun 6, 2023
Grant date	Jun 6, 2023

Abstract

A brazing process using Nickel(Ni)-Carbon as graphite(Cg) alloys, Ni-Cg-Molybdenum(Mo) alloys, and Ni-Cobalt(Co)-Cg-Mo alloys for brazing together ceramics, ceramics to metals, metals to metals. Semiconductor processing equipment made with the use of Ni-Cg alloys, such as heaters and chucks. Semiconductor processing equipment components and industrial equipment components using a highly wear resistant surface layer, such as sapphire, joined to a substrate such as a ceramic, with a Ni-Cg alloy braze.

First claim

What is claimed is:

1. A joining method, said method comprising the steps of:
placing a brazing element between an interface area of a first ceramic piece and an interface area of a second ceramic piece to create a joining pre-assembly, wherein said brazing element consists of 3.5 to 25 atomic percent of Carbon, 63.5 to 87.5 atomic percent of one or more elements from the group consisting of Iron, Cobalt, and Nickel, and greater than 0 and up to 35 atomic percent of one or more elements from the group consisting of Ti, Zr, Hf, Nb, CR, Mo, W, and Si;
placing the components of said joining pre-assembly into a process chamber; removing oxygen from said process chamber; and heating at least said brazing element of said joining pre-assembly, thereby joining said first ceramic piece to said second ceramic piece.

2. The method of claim 1 wherein said first ceramic piece comprises a ceramic from the group of aluminum nitride, alumina, beryllium oxide, and zirconia, and said second ceramic piece comprises a ceramic from the group of aluminum nitride, alumina, beryllium oxide, and zirconia.

3. The method of claim 2 wherein the step of removing oxygen from said process chamber comprises applying a pressure of lower than 1×10E −4 Torr to said process chamber.

4. The method of claim 1 wherein said step of heating at least said brazing element comprises:
heating at least said brazing element to a first temperature below the eutectic temperature of said brazing element; and
heating at least said brazing element to second temperature above said eutectic temperature of said brazing element.

5. The method of claim 2 wherein said step of heating at least said brazing element comprises:
heating at least said brazing element to a first temperature below the eutectic temperature of said brazing element; and
heating at least said brazing element to second temperature above said eutectic temperature of said brazing element.

6. The method of claim 3 wherein said step of heating at least said brazing element comprises:
heating at least said brazing element to a first temperature below the eutectic temperature of said brazing element; and
heating at least said brazing element to second temperature above said eutectic temperature of said brazing element.

7. The method of claim 1 wherein said first ceramic piece comprises a ceramic from the group of aluminum nitride, alumina, beryllium oxide, and zirconia.

8. The method of claim 7 wherein the step of removing oxygen from said process chamber comprises applying a pressure of lower than 1×10E −4 Torr to said process chamber.

9. The method of claim 8 wherein said step of heating at least said brazing element comprises: heating at least said brazing element to a first temperature below the eutectic temperature of said brazing element; and heating at least said brazing element to second temperature above said eutectic temperature of said brazing element.

10. The method of claim 1 wherein the step of removing oxygen from said process chamber comprises applying a pressure of lower than 1×10E −4 Torr to said process chamber.

11. The method of claim 10 wherein said step of heating at least said brazing element comprises:
heating at least said brazing element to a first temperature below the eutectic temperature of said brazing element; and
heating at least said brazing element to second temperature above said eutectic temperature of said brazing element.

12. The method of claim 1 wherein said brazing element consists of:
Carbon in the range of 8-13 atomic percent;
Nickel in the range of 70-85 atomic percent; and
Molybdenum in the range of 7-20 atomic percent.

13. The method of claim 1 wherein said brazing element consists of:
Carbon in the range of 5.7-17.3 atomic percent;
Nickel in the range of 63-94 atomic percent; and
Molybdenum in the range of 4-23 atomic percent.

14. The method of claim 1 wherein said second ceramic piece comprises a ceramic from the group of aluminum nitride, alumina, beryllium oxide, and zirconia.

Assignees

• Watlow Electric Mfg

Inventors

• Elliot Alfred Grant
• Elliot Brent

Classifications

• C04B2237/348

  Zirconia, hafnia, zirconates or hafnates · CPC title

• C04B2237/083

  Carbide interlayers, e.g. silicon carbide interlayers · CPC title

• B23K35/306

  with C as next major constituent, e.g. cast iron · CPC title

• C04B37/005

  consisting of glass or ceramic material · CPC title

• C04B2237/343

  Alumina or aluminates · CPC title