Structured catalyst for CO shift or reverse shift and method for producing same, CO shift or reverse shift reactor, method for producing carbon dioxide and hydrogen, and method for producing carbon monoxide and water

Patent metadata

Field	Value
Publication number	US-11666894-B2
Application number	US-201916698579-A
Country	US
Kind code	B2
Filing date	Nov 27, 2019
Priority date	May 31, 2017
Publication date	Jun 6, 2023
Grant date	Jun 6, 2023

Abstract

Provided are a structured catalyst for CO shift or reverse shift that can realize a long life time by suppressing the decline in function, a method for producing the same, a CO shift or reverse shift reactor, a method for producing carbon dioxide and hydrogen, and a method for producing carbon monoxide and water. The structured catalyst for CO shift or reverse shift (1) includes a support (10) of a porous structure composed of a zeolite-type compound, and at least one CO shift or reverse shift catalytic substance (20) present in the support (10), the support (10) has channels (11) connecting with each other, and the CO shift or reverse shift catalytic substance (20) is present at least in the channels (11) of the support (10).

First claim

What is claimed is:

1. A structured catalyst for CO shift or reverse shift, comprising:
a support of a porous structure composed of a zeolite-type compound; and
at least one CO shift or reverse shift catalytic substance present in the support, wherein
the support has channels connecting with each other, and
the CO shift or reverse shift catalytic substance is present at least in the channels of the support,
wherein
the channels have any one of a one-dimensional pore, a two-dimensional pore, and a three-dimensional pore defined by a framework of the zeolite-type compound and an enlarged pore portion different from any of the one-dimensional pore, the two-dimensional pore, and the three-dimensional pore,
the CO shift or reverse shift catalytic substance is present at least in the enlarged pore portion,
a diameter of CO shift or reverse shift catalytic substance is greater than a pore diameter of the zeolite-type compound, and
the enlarged pore portion is a new skeletal structure providing support for the structured catalyst for CO shift or reverse shift.

2. The structured catalyst for CO shift or reverse shift according to claim 1 , wherein the enlarged pore portion causes a plurality of pores constituting any one of the one-dimensional pore, the two-dimensional pore, and the three-dimensional pore to connect with each other.

3. The structured catalyst for CO shift or reverse shift according to claim 1 , wherein the CO shift or reverse shift catalytic substance is made of metal nanoparticles.

4. The structured catalyst for CO shift or reverse shift according to claim 3 , wherein the metal nanoparticles are nanoparticles composed of at least one type of metal or metal oxide selected from the group consisting of cobalt, nickel, iron, and copper.

5. The structured catalyst for CO shift or reverse shift according to claim 3 , wherein the average particle size of the metal nanoparticles is greater than an average inner diameter of the channels and is less than or equal to the inner diameter of the enlarged pore portion.

6. The structured catalyst for CO shift or reverse shift according to claim 3 , wherein a metal element (M) of the metal nanoparticles is contained in an amount from 0.5 mass % to 2.5 mass % based on the structured catalyst for CO shift or reverse shift.

7. The structured catalyst for CO shift or reverse shift according to claim 3 , wherein the average particle size of the metal nanoparticles is from 0.08 nm to 30 nm.

8. The structured catalyst for CO shift or reverse shift according to claim 3 , wherein the ratio of the average particle size of the metal nanoparticles to the average inner diameter of the channels is from 0.05 to 300.

9. The structured catalyst for CO shift or reverse shift according to claim 1 , further comprising at least one another CO shift or reverse shift catalytic substance held on an outer surface of the support.

10. The structured catalyst for CO shift or reverse shift according to claim 9 , wherein the content of the at least one CO shift or reverse shift catalytic substance present in the support is greater than that of the at least other one CO shift or reverse shift catalytic substance held on an outer surface of the support.

11. A method for producing carbon dioxide and hydrogen, the method comprising:
reacting carbon monoxide and water in the presence of the structured catalyst for CO shift according to claim 1 to generate carbon dioxide and hydrogen.

12. A method for producing carbon monoxide and water, the method comprising:
reacting carbon dioxide and hydrogen in the presence of the structured catalyst for reverse shift described in claim 1 to generate carbon monoxide and water.

13. A method for producing carbon dioxide and hydrogen, the method comprising:
reacting carbon monoxide and water using a catalyst to produce carbon dioxide and hydrogen using a CO shift reaction,
wherein
the catalyst comprises:
a support of a porous structure composed of a zeolite-type compound; and
at least one type of metal nanoparticles present in the support, wherein
the support has channels connecting with each other,
the metal nanoparticles include a structured catalyst for CO shift present in at least an enlarged pore portion of the channels, and a diameter of the metal nanoparticles are greater than a pore diameter of the zeolite-type compound, and
the enlarged pore portion is a new skeletal structure providing support for the structured catalyst for CO shift or reverse shift.

14. The method according to claim 13 , further comprising:
controlling a reaction temperature to be 150 to 300° C. and a reaction pressure to be 1 to 100 atmospheres.

15. A method of producing carbon monoxide and water, the method comprising:
reacting carbon dioxide and hydrogen using a catalyst to generate carbon monoxide and water using a reverse shift reaction,
wherein
the catalyst comprising:
a support of a porous structure composed of a zeolite-type compound; and
at least one type of metal nanoparticles present in the support, wherein
the support has channels connecting with each other,
the metal nanoparticles include a structured catalyst for reverse shift present in at least an enlarged pore portion of the channels, a diameter of the metal nanoparticles are greater than a pore diameter of the zeolite-type compound, wherein the enlarged pore portion is a new skeletal structure providing support for the structured catalyst for CO shift or reverse shift.

16. The method according to claim 15 , wherein a reaction temperature of the reverse shift reaction is 300° C. or higher and 900° C. or lower.

17. The method according to claim 15 , further comprising:
removing unreacted carbon dioxide and generated water.

Assignees

• Furukawa Electric Co Ltd

Inventors

• Masuda Takao
• Nakasaka Yuta
• Yoshikawa Takuya
• Kato Sadahiro
• Fukushima Masayuki
• Takahashi Hiroko
• BANBA Yuichiro
• Sekine Kaori

Classifications

• B01J37/0205

  in several steps · CPC title

• C01B5/00

  Water · CPC title

• B01J29/7669

  MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3 · CPC title

• C01B2203/1058

  Nickel catalysts · CPC title

• B01J29/14 Primary

  Iron group metals or copper · CPC title