Microporous battery separators including polyolefin layer and non-woven layer with alkylbenzene sulfonic acid lithium salt surfactant, lithium batteries utilizing the same, and methods of manufacture of the same

Patent metadata

Field	Value
Publication number	US-11658333-B2
Application number	US-202016921952-A
Country	US
Kind code	B2
Filing date	Jul 7, 2020
Priority date	May 8, 2015
Publication date	May 23, 2023
Grant date	May 23, 2023

Abstract

In accordance with at least certain embodiments, the present invention is directed to novel, improved, coated, or treated separator membranes, separators or membrane based separators for lithium batteries. The membranes or separators may include non-woven layers, improved surfactant treatments, or combinations thereof. The separators or membranes are useful for solvent electrolyte lithium batteries, especially rechargeable lithium ion batteries, and provide improved performance, wettability, cycling ability, and/or recharging efficiency.

First claim

What is claimed is:

1. A microporous battery separator for a lithium battery, comprising:
a) a polyolefin layer which comprises at least one membrane of polypropylene; and
b) at least one non-woven layer on at least one side of the polyolefin layer, wherein the non-woven layer comprises polypropylene, and wherein the separator has a surfactant coating thereon and wherein the surfactant coating consists of a combination of lithium salts of a linear and branched alkylbenzene sulfonic acid depicted in the following chemical structures (1) and (2) in a combined weight add-on amount of from about 1.37% to about 10.0 wt. %:

where R is an alkyl functionality having the following formula C n H 2n+1 with n >6 and X m+ is Li + or

where R1 and R2 are independently an alkyl functionality which can be C n H 2n+1 , with n>6 and X m+ is Li + .

2. The separator according to claim 1 , wherein n is greater than 8 for either the lithium salt of a linear or branched alkylbenzene sulfonic acid depicted in chemical structure (1) or the lithium salt of a linear or branched alkylbenzene sulfonic acid depicted in chemical structure (2).

3. The separator according to claim 1 , wherein n is between 12 and 20 for either the lithium salt of a linear or branched alkylbenzene sulfonic acid depicted in chemical structure (1) or the lithium salt of a linear or branched alkylbenzene sulfonic acid depicted in chemical structure (2).

4. The separator according to claim 1 , wherein the one of or a combination of the lithium salts of a linear or branched alkylbenzene sulfonic acid are present in the weight add-on amount from about 2.58% to about 10%.

5. The separator according to claim 1 , wherein the one of or a combination of the lithium salts of a linear or branched alkylbenzene sulfonic acid are present in a weight add-on amount from about 2.58% to about 4.84%.

6. The separator according to claim 1 , wherein the non-woven layer comprises a non-woven layer having a melting point less than about 200° C.

7. The separator according to claim 1 , wherein the non-woven layer further comprises polyethylene, low density polyethylene, polycarbonate, polyethylene terephthalate, polybutylene terephthalate, polymethylpentene, polystyrene, polyamide, polyimide, nylon, or a combination, blend or mixture thereof.

8. The separator of claim 1 , wherein the separator wets by an organic or inorganic electrolyte in less than 5 seconds.

9. The separator of claim 1 , wherein the separator wets by an organic or inorganic electrolyte in less than 1 second.

10. The separator according to claim 1 , wherein the polyolefin layer further comprises at least one membrane or layer of polyethylene.

11. The separator according to claim 1 , wherein the polyolefin layer further comprises at least one membrane of polyethylene, polypropylene, or a combination, blend or mixture thereof.

12. The separator according to claim 1 , wherein the polyolefin layer which comprises at least one membrane of polypropylene comprises multiple layers of polypropylene, or multiple layers of polyethylene and polypropylene.

13. The separator according to claim 12 , wherein the polyolefin layer is selected from one of the following multilayer arrangements: PP/PP, PE/PP, PP/PE/PP, PE/PP/PE, PP/PP/PP, PP/PP/PP/PP, PE/PP/PP/PE, PP/PE/PE/PP, PP/PP/PP/PP/PP, PP/PP/PE/PP/PP, PP/PE/PP/PE/PP, PE/PP/PE/PP/PE, PP/PP/PP/PP/PP/PP, PE/PE/PP/PP/PE/PE, PP/PP/PE/PE/PP/PP, PP/PE/PP/PP/PE/PP, PE/PP/PE/PE/PP/PE, PP/PE/PE/PE/PE/PP, and PE/PP/PP/PP/PP/PE.

Assignees

• Celgard Llc

Inventors

• Adams Changqing Wang
• Wensley C Glen
• Reinartz Stefan

Classifications

• H01M50/489 Primary

  Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties · CPC title

• H01M50/403

  Manufacturing processes of separators, membranes or diaphragms · CPC title

• H01M10/0525 Primary

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/5825

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title

• H01M10/052

  Li-accumulators · CPC title