Polyvinyl alcohol and ethylene vinyl alcohol copolymer barrier coatings
US-10392527-B2 · Aug 27, 2019 · US
US11655390B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11655390-B2 |
| Application number | US-201816754219-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 5, 2018 |
| Priority date | Nov 7, 2017 |
| Publication date | May 23, 2023 |
| Grant date | May 23, 2023 |
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The present invention provides a coating fluid including: a hydroxy group-containing resin; an inorganic layered compound; and a liquid medium, in which a ratio (outflow time (B)/outflow time (A)) of outflow time (B) of a coating fluid at 5° C. measured by a Zahn cup to outflow time (A) of a coating fluid at 24° C. measured by a Zahn cup is 1.40 or less.
Opening claim text (preview).
The invention claimed is: 1. A coating fluid, comprising: a hydroxy group-containing resin that comprises a hydroxy group and an amino group; an inorganic layered compound; and a liquid medium, wherein a ratio (outflow time (B)/outflow time (A)) of outflow time (B) of a coating fluid at 5° C. measured by a Zahn cup to outflow time (A) of a coating fluid at 24° C. measured by a Zahn cup is 1.40 or less, wherein a number average molecular weight of the hydroxy group-containing resin is 10,000 to 50,000. 2. The coating fluid according to claim 1 , wherein the outflow time (B)/outflow time (A) is 1.30 or less. 3. The coating fluid according to claim 1 , wherein an amount of a hydroxy group per 100 g of the hydroxy group-containing resin is 1.50 to 2.27 mol. 4. The coating fluid according to claim 1 , wherein an amount of the amino group per 100 g of the hydroxy group-containing resin is 0.046 to 0.682 mol. 5. The coating fluid according to claim 1 , wherein the hydroxy group-containing resin is a vinylamine-vinylalcohol copolymer. 6. The coating fluid according to claim 1 , wherein a content of the hydroxy group-containing resin is 0.2 to 9.05% by mass per 100% by mass of the coating fluid. 7. The coating fluid according to claim 1 , wherein the liquid medium contains water and ethanol. 8. The coating fluid according to claim 7 , wherein a content of ethanol is 1 to 70% by mass per 100% by mass of the total of water and ethanol. 9. The coating fluid according to claim 1 , wherein a content of the liquid medium is 90 to 99.5% by mass per 100% by mass of the coating fluid. 10. The coating fluid according to claim 1 , wherein an average particle size of the inorganic layered compound in the coating fluid is 0.02 to 3 μm. 11. The coating fluid according to claim 1 , wherein a ratio (L/a) of an average particle size L of the inorganic layered compound in the coating fluid to a thickness a of a unit crystal layer of an inorganic layered compound measured by powder X-ray diffraction method is 20 to 3,000. 12. The coating fluid according to claim 1 , wherein the inorganic layered compound is montmorillonite. 13. The coating fluid according to claim 1 , wherein a content of the inorganic layered compound is 0.047 to 6.0% by mass per 100% by mass of the coating fluid. 14. The coating fluid according to claim 1 , wherein a content of the inorganic layered compound is 0.047 to 5.0% by mass per 100% by mass of the coating fluid. 15. The coating fluid according to claim 4 , wherein the liquid medium contains water and ethanol. 16. The coating fluid according to claim 15 , wherein a content of the ethanol is 10 to 50% by mass per 100% by mass of the total of water and ethanol. 17. The coating fluid according to claim 5 , wherein the liquid medium contains water and ethanol. 18. The coating fluid according to claim 17 , wherein a content of the ethanol is 10 to 50% by mass per 100% by mass of the total of water and ethanol. 19. The coating fluid according to claim 7 , wherein a content of the ethanol is 10 to 50% by mass per 100% by mass of the total of water and ethanol.
containing nitrogen atoms · CPC title
Homopolymers or copolymers of vinylamine · CPC title
containing oxygen atoms {(C09D201/025 takes precedence)} · CPC title
Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced {(electrically insulating plastics, resins or waxes H01B3/30)}; Filling pastes · CPC title
Clay · CPC title
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