System and method for optical fiber preform preparation via high-surface-area coating

Patent metadata

Field	Value
Publication number	US-11655183-B2
Application number	US-202016899069-A
Country	US
Kind code	B2
Filing date	Jun 11, 2020
Priority date	Jun 11, 2020
Publication date	May 23, 2023
Grant date	May 23, 2023

Abstract

The present disclosure relates to a method for forming a glass, ceramic or composite material. The method may involve initially forming a plurality of tubes and then performing a coating operation to coat the plurality of tubes with materials containing metal or metalloid elements, including inorganic compounds, organometallic compounds, or coordination complexes to form coated tubes. The method may further include performing at least one of a thermal operation or a thermochemical operation on the coated tubes to form a solid glass, ceramic, or composite structure with dimensions representing at least one of a rod or fiber.

First claim

What is claimed is:

1. A method for forming a glass, ceramic or composite preform material comprising:
forming a matrix of glass including at least one of individual tubes or rods, the at least one of individual tubes or rods having surfaces individually coated with materials containing metal or metalloid elements to form a coated matrix of glass, wherein a surface area of the matrix of glass exceeds, by more than a factor of two, an area of an interior surface of an imaginary cylinder or parallelepiped of a minimum size to enclose the matrix; and
performing at least one of a thermal operation or a thermochemical operation on the coated matrix of glass to increase a density of the at least one of individual tubes or rods by reducing said matrix of glass to a solid volume of material, representing a single structure having interstitial spaces therewithin removed, with dimensions representing at least one of a solid rod or a fiber.

2. The method of claim 1 , wherein the matrix of glass comprises a solid rod of ceramic or glass that has been etched to increase a surface area thereof and internal surfaces of the etched ceramic or glass is coated during the coating operation.

3. The method of claim 1 , wherein the matrix of glass comprises a fused assembly of glass beads or particles and the surfaces of the assembly of beads or particles are coated during the coating operation.

4. The method of claim 1 , wherein performing at least one of a thermal operation or a thermochemical operation comprises performing at least one of a sintering operation, a melt operation, a thermochemical reaction operation, or a collapse operation on an assembled collection of the coated matrix.

5. The method of claim 1 , further comprising:
performing a cutting operation to cut the rod/fiber into individual rod/fiber segments;
performing an assembly operation to form an assembly of the individual rod/fiber segments;
performing a collapsing operation to collapse the assembly of the individual rod/fiber segments again to another rod/fiber shaped glass; and
repeating the cutting, assembly and the collapsing operations as needed to homogenize the composition of the glass.

6. The method of claim 5 , wherein the repeated collapsing operation comprises repeatedly using a glass lathe and a hydrogen-oxygen flame.

7. The method of claim 5 , wherein the repeated collapsing operation comprises repeatedly using a furnace.

8. The method of claim 1 , further comprising forming a matrix of glass; and
wherein the coating operation comprises coating the matrix of glass using a liquid solution coating operation.

9. The method of claim 8 , wherein the matrix of glass is coated with SiO 2 particles or a porous SiO 2 structure.

10. The method of claim 8 , wherein coating the matrix of glass using a liquid solution coating operation comprises submerging and soaking the matrix of glass in a solution containing precursors of desired dopant species.

11. The method of claim 10 , wherein the desired dopant species comprise at least one of:
dissolved salts;
metalorganics; or
a suspension of oxide particles including at least one of Nd, Yb, Er, Ho, P, Tm, Sm, Eu, Pm, U, Ge, Ga, B, Ba, Al, La, Te, or Ce.

12. The method of claim 1 , further comprising forming a matrix of glass; and
wherein the coating operation comprises coating the matrix of glass using a vapor-phase deposition process.

13. The method of claim 1 , further comprising:
after performing the coating operation to coat the matrix of glass, bundling the at least one of the tubes rods into a bundled collection of tubes or rods prior to performing the thermochemical operation, and wherein the thermochemical operation comprises a thermochemical heat treatment operation to heat bundled collection of tubes or rods.

14. The method of claim 13 , wherein the thermochemical heat treatment operation on the matrix of glass is performed using a furnace.

15. The method of claim 13 , wherein the thermochemical treatment operation on the matrix of glass is performed using a torch.

16. The method of claim 1 , wherein the at least one of a thermal operation or a thermochemical operation to collapse the matrix of glass into a solid volume of material is performed using a glass lathe/hydrogen-oxygen torch.

17. The method of claim 1 , wherein the solid volume of material forms a preform from which optical fiber is drawn.

18. A method for forming a glass preform with a tailored composition, comprising:
forming a plurality of high purity SiO 2 glass tubes;
coating the plurality of tubes with a porous SiO 2 network to form coated SiO 2 tubes;
submerging the coated SiO 2 tubes in one or more solutions to incorporate additional chemical species;
densifying and purifying the coating of the SiO 2 tubes using thermochemical treatments;
collapsing a bundled or assembled collection of the coated SiO 2 tubes using a thermal operation to form a collapsed, cross-sectionally solid, optical preform with interstitial spaces between the coated SiO 2 tubes having been removed, and having varied compositional domains; and
pulling the collapsed solid optical preform into a cylinder with a diameter less than that of the collapsed solid optical preform.

19. The method of claim 18 , further comprising processing the collapsed solid optical preform by repeated operations involving drawing the collapsed solid optical preform into rods with a reduced diameter to form reduced diameter rods, cutting the reduced diameter rods into individual segments, assembling the individual segments into a stacked array, and collapsing the stacked array to a solid rod of glass; wherein the drawing, cutting, assembling and collapsing operations are repeated one or more times to decrease the lateral dimensions of compositional gradients within the collapsed solid optical preform and to place the collapsed solid preform in its final shape.

20. The method of claim 18 , wherein the plurality of SiO 2 tubes consists of individual pieces which are individually coated and later assembled into a single structure.

21. The method of claim 18 , wherein the plurality of SiO 2 tubes comprises a fused assembly of SiO 2 tubes, and internal surfaces of the SiO 2 tubes are coated during a coating operation.

22. The method of claim 18 , wherein coating the plurality of tubes with SiO 2 particles to form a porous SiO 2 network comprises using a liquid solution coating operation.

23. The method of claim 18 , wherein the operation of submerging the coated SiO 2 tubes in a plurality of solutions to incorporate dopants includes submerging the coated tubes in solutions containing one or more of the following species: Nd, Yb, Er, Ho, P, Tm, Sm, Eu, Pm, U, Ge, Ga, B, Ba, Al, La, Te, or Ce.

24. The method of claim 18 , wherein collapsing the bundled or assembled collection of coated SiO 2 tubes using a thermal operation comprises using a furnace.

25. The method of claim 18 , wherein collapsing the bundled or assembled collection of coated SiO 2 tubes using a thermal operation comprises using a glass lathe/hydrogen-oxygen torch.

Assignees

• L Livermore Nat Security Llc

Inventors

• Lange Andrew
• Dawson Jay W
• Dylla-Spears Rebecca
• Mart Cody Wren
• Messerly Michael J
• Sasan Koroush
• Schenkel Nick
• Suratwala Tayyab I

Classifications

• C03B2201/36

  doped with rare earth metals and aluminium, e.g. Er-Al co-doped · CPC title

• C03B2201/31

  doped with germanium · CPC title

• C03B37/02727

  Annealing or re-heating · CPC title

• C03B37/01262

  Depositing additional preform material as liquids or solutions, e.g. solution doping of preform tubes or rods · CPC title

• C03B2201/28

  doped with phosphorus · CPC title