Methods for wastewater treatment using alcohol ethoxylate surfactants

Patent metadata

Field	Value
Publication number	US-11655168-B2
Application number	US-202016881857-A
Country	US
Kind code	B2
Filing date	May 22, 2020
Priority date	May 22, 2020
Publication date	May 23, 2023
Grant date	May 23, 2023

Abstract

Methods for treating wastewater in conjunction with subterranean operations with a wastewater treatment additive. In some embodiments, the methods include providing wastewater recovered from at least a portion of a subterranean formation, wherein the wastewater includes water and an organic foulant material, and introducing a wastewater treatment additive that includes an alcohol ethoxylate surfactant into the recovered wastewater.

First claim

What is claimed is:

1. A method comprising:
introducing a wastewater treatment additive that comprises an alcohol ethoxylate surfactant and a non-polymeric chelating agent into wastewater recovered from at least a portion of a subterranean formation, wherein the wastewater comprises water and an organic foulant material, wherein the organic foulant material is humic acid, wherein the alcohol ethoxylate surfactant is present in an amount from about 500 parts per million to about 2,000 parts per million by volume of the wastewater treatment additive, wherein the alcohol ethoxylate is isotridecanol ethoxylate, wherein the non-polymeric chelating agent is present in an amount from about 1 part per million to about 500 parts per million by volume of the wastewater treatment additive, and wherein the wastewater treatment additive reduces the formation of humic acid aggregates.

2. The method of claim 1 , wherein the wastewater is recovered from at least a portion of a subterranean formation in conjunction with at least one subterranean operation selected from a group consisting of: a SAGD operation, an enhanced oil recovery operation, a solvent-based oil recovery operation, a polymer flooding operation, a cyclic steam injection operation, a drilling operation, a completion operation, a cleanout operation, a cementing operation, a hydraulic fracturing treatment, an acidizing treatment, and any combination thereof.

3. The method of claim 1 , wherein the wastewater treatment additive further comprises at least one additional alcohol ethoxylate surfactant selected from the group consisting of: an isotridecanol ethoxylate, a primary alcohol ethoxylate, a secondary alcohol ethoxylate, a tertiary alcohol ethoxylate, a linear alcohol ethoxylate, a fatty alcohol ethoxylate, an alkylphenol ethoxylate, a tridecyl ethoxylate, a lauryl alcohol ethoxylate, a stearyl alcohol ethoxylate, a behenyl alcohol ethoxylate, an oleyl alcohol ethoxylate, and any combination thereof.

4. The method of claim 1 , wherein the non-polymeric chelating agent comprises at least one chelating agent selected from the group consisting of: ethylenediaminetetraacetic acid (EDTA), citric acid, sodium citrate, hydroxyethyl ethylenediamine triacetic acid (HEDTA), nitrilotriacetic acid (NTA), diethylene triamine pentaacetic acid (DTPA), glutamic acid diacetic (GLDA), propylene diamine tetraacetic acid (PDTA), ethylenediaminedisuccinic acid (EDDS), diethanolglycine (DEG), ethanoldiglycine (EDG), a glucoheptonate, a phosphate, an amine, a citrate, an aminocarboxylic acid, a 1,3-diketone, a hydroxycarboxylic acid, an aminoalcohol, an aromatic heterocyclic base, a phenol, an aminophenol, an oxime, a Schiff base, a tetrapyrrole, a sulfur compound, a synthetic macrocyclic compound, a phosphonic acid, N-(phosphonomethyl)iminodiacetic acid, a derivative of any of the foregoing, a salt of any of the foregoing, and any combination thereof.

5. The method of claim 1 , wherein the wastewater treatment additive further comprises at least one solvent selected from the group consisting of: water, an alcohol, a glycol, and any combination thereof.

6. The method of claim 1 , further comprising disposing of or reusing at least a portion of the wastewater after introducing the wastewater treatment additive into the recovered wastewater.

7. The method of claim 1 , wherein the non-polymeric chelating agent comprises ethylenediaminetetraacetic acid (EDTA).

8. The method of claim 7 , wherein the wastewater treatment additive further comprises at least one additional non-polymeric chelating agent selected from the group consisting of citric acid, sodium citrate, hydroxyethyl ethylenediamine triacetic acid (HEDTA), nitrilotriacetic acid (NTA), diethylene triamine pentaacetic acid (DTPA), glutamic acid diacetic (GLDA), propylene diamine tetraacetic acid (PDTA), ethylenediaminedisuccinic acid (EDDS), diethanolglycine (DEG), ethanoldiglycine (EDG), a glucoheptonate, a phosphate, an amine, a citrate, an aminocarboxylic acid, a 1,3-diketone, a hydroxycarboxylic acid, an aminoalcohol, an aromatic heterocyclic base, a phenol, an aminophenol, an oxime, a Schiff base, a tetrapyrrole, a sulfur compound, a synthetic macrocyclic compound, a phosphonic acid, N-(phosphonomethyl)iminodiacetic acid, a derivative of any of the foregoing, a salt of any of the foregoing, and any combination thereof.

9. A method comprising:
separating a production stream into a first portion comprising oil and a second portion comprising wastewater; wherein the wastewater comprises water and humic acid; and
introducing a wastewater treatment additive into the second portion, the wastewater treatment additive comprising an ethoxylated isotridecanol, a non-polymeric chelating agent, and a solvent, wherein the ethoxylated isotridecanol is present in the wastewater treatment additive in an amount of about 500 parts per million to about 2,000 parts per million by volume of the wastewater treatment additive, wherein the ethoxylated isotridecanol reduces the formation of humic acid aggregates in the second portion; and wherein the non-polymeric chelating agent is present in an amount from about 1 part per million to about 500 parts per million by volume of the wastewater treatment additive;
filtering the second portion to remove oils and/or contaminants remaining in the second portion; and
introducing the second portion into a disposal well.

10. The method of claim 9 , wherein the wastewater treatment additive comprises at least one additive selected from the group consisting of: a surfactant, a pH adjuster, a biocide, a coagulant, a corrosion inhibitor, an oxygen scavenger, a sulfide scavenger, a scale inhibitor, and any combination thereof.

11. The method of claim 9 , wherein the non-polymeric chelating agent comprises at least one chelating agent selected from the group consisting of ethylenediaminetetraacetic acid (EDTA), citric acid, sodium citrate, hydroxyethyl ethylenediamine triacetic acid (HEDTA), nitrilotriacetic acid (NTA), di ethylene tri amine pentaacetic acid (DTPA), glutamic acid diacetic (GLDA), propylene diamine tetraacetic acid (PDTA), ethylenediaminedisuccinic acid (EDDS), diethanolglycine (DEG), ethanoldiglycine (EDG), a glucoheptonate, a phosphate, an amine, a citrate, an aminocarboxylic acid, a 1,3-diketone, a hydroxycarboxylic acid, an aminoalcohol, an aromatic heterocyclic base, a phenol, an aminophenol, an oxime, a Schiff base, a tetrapyrrole, a sulfur compound, a synthetic macrocyclic compound, a phosphonic acid, N-(phosphonomethyl)iminodiacetic acid, a derivative of any of the foregoing, a salt of any of the foregoing, and any combination thereof.

12. A method comprising:
flowing recovered wastewater through at least a portion of a treatment system, wherein the recovered wastewater comprises water and an organic foulant material comprising humic acid; and
injecting a wastewater treatment additive that comprises an alcohol ethoxylate surfactant and a non-polymeric chelating agent into the portion of the treatment system to contact the recovered wastewater with the wastewater treatment additive to reduce the formation of humic acid aggregates and form treated wastewater, wherein ethoxylated isotridecanol is present in the wastewater treatment additive in an amount of about 500 parts per million to about 2,000 parts per million by volume of the wastewater treatment additive, and wherein the non-polymeric chelating agent is present in an amount from about 1 part per million to about 500 parts per million by volume of the wastewater treatment additive.

13. The method of claim 12 , wherein at least a portion of the treatment system comprises a surface pipe and a pump fo

Assignees

• Halliburton Energy Services Inc

Inventors

• Hurd Jeff Allen
• Li Chunli

Classifications

• C02F2101/34

  containing oxygen · CPC title

• C02F2305/04

  Surfactants, used as part of a formulation or alone · CPC title

• C09K8/524

  organic depositions, e.g. paraffins or asphaltenes · CPC title

• C02F2303/22

  Eliminating or preventing deposits, scale removal, scale prevention (C02F1/042, C02F1/4602, C02F5/00 take precedence) · CPC title

• C02F1/547

  Tensides · CPC title