Functional structural body and method for making functional structural body

Patent metadata

Field	Value
Publication number	US-11655157-B2
Application number	US-201916698636-A
Country	US
Kind code	B2
Filing date	Nov 27, 2019
Priority date	May 31, 2017
Publication date	May 23, 2023
Grant date	May 23, 2023

Abstract

A functional structural body that can realize a prolonged life time by suppressing the decrease in function and that can fulfill resource saving without requiring a complicated replacement operation is provided. A functional structural body includes a skeletal body of a porous structure composed of a zeolite-type compound; and at least one solid acid present in the skeletal body, the skeletal body has channels connecting with each other, and the solid acid is present at least in the channels of the skeletal body.

First claim

What is claimed is:

1. A structural body, comprising:
a skeletal body of a porous structure composed of a zeolite-type compound; and
at least one solid acid present in the skeletal body, wherein
the zeolite-type compound is selected from the group consisting of zeolites, cation exchanged zeolites and silicalites,
a framework of the zeolite-type compound is selected from the group consisting of FAU type (Y type or X type), MTW type, MFI type (ZSM-5), FER type (ferrierite), LTA type (A type), MWW type (MCM-22), MOR type (mordenite), LTL type (L type), and BEA type (beta type),
the skeletal body has channels connecting with each other,
the solid acid is present at least in the channels of the skeletal body,
the solid acid is selected from the group consisting of iron oxide (FeO x ), zinc oxide (ZnO), aluminum oxide (Al 2 O 3 ), zirconium oxide (ZrO 2 ), titanium oxide (TiO 2 ), selenium trioxide (SeO 3 ), selenium dioxide (SeO 2 ), tellurium trioxide (TeO 3 ), tellurium dioxide (TeO 2 ), tin dioxide (SnO 2 ), manganese oxide (Mn 2 O 7 ), technetium oxide (Tc 2 O 7 ), and rhenium oxide (Re 2 O 7 ),
the channels have any one of a one-dimensional pore, a two-dimensional pore, and a three-dimensional pore defined by the framework of the zeolite-type compound and an enlarged pore portion which has a diameter greater than any one of the one-dimensional pore, the two-dimensional pore, and the three-dimensional pore, the enlarged pore portion is not defined by the framework of the zeolite-type compound, and is greater than or equal to a diameter of the solid acid,
the solid acid is at least embedded in the enlarged pore portion,
an average particle size of the solid acid is greater than any one of the one-dimensional pore, the two-dimensional pore, and the three-dimensional pore defined by the framework of the zeolite-type compound, and
the solid acid is nanoparticles.

2. The structural body according to claim 1 , wherein the enlarged pore portion causes a plurality of pores constituting any one of the one-dimensional pore, the two-dimensional pore, and the three-dimensional pore to connect with each other.

3. The structural body according to claim 1 , wherein an average particle size of the nanoparticles is greater than an average inner diameter of the channel and is less than or equal to the inner diameter of the enlarged pore portion.

4. The structural body according to claim 1 , wherein an average particle size of the nanoparticles is from 0.1 nm to 50 nm.

5. The structural body according to claim 4 , wherein the average particle size of the nanoparticles is from 0.45 nm to 14.0 nm.

6. The structural body according to claim 1 , wherein a ratio of an average particle size of the nanoparticles to an average inner diameter of the channels is from 0.06 to 500.

7. The structural body according to claim 6 , Wherein the ratio of the average particle size of the nanoparticles to the average inner diameter of the channels is from 0.1 to 36.

8. The structural body according to claim 7 , wherein the ratio of the average particle size of the nanoparticles to the average inner diameter of the channels is from 1.7 to 4.5.

9. The structural body according to claim 1 , wherein a metal element of solid acid is contained in an amount of 0.5 mass % to 2.5 mass % based on the structural body.

10. The structural body according to claim 1 , wherein an average inner diameter of the channel, is from 0.1 nm to 1.5 nm, and the inner diameter of the enlarged pore portion is from 0.5 nm to 50 nm.

11. The structural body according to claim 1 , further including at least one catalytic substance held on an outer surface of the skeletal body.

12. The structural body according to claim 11 , wherein a content of the at least one solid acid present in the skeletal body is greater than that of the at least one catalytic substance held on the outer surface of the skeletal body.

13. The structural body according to claim 1 , wherein the zeolite-type compound comprises a plurality of pores less than 1 nm in diameter.

Assignees

• Univ Hokkaido Nat Univ Corp
• Furukawa Electric Co Ltd

Inventors

• Masuda Takao
• Nakasaka Yuta
• Yoshikawa Takuya
• Kato Sadahiro
• Fukushima Masayuki
• Inamori Kojiro
• Takahashi Hiroko
• BANBA Yuichiro
• Sekine Kaori

Classifications

• B01J35/45

  Nanoparticles · CPC title

• B01J35/56

  Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths · CPC title

• B01J29/7415

  Zeolite Beta · CPC title

• B01J29/655

  containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead · CPC title

• B01J29/63

  Iron group metals or copper · CPC title