Composite based on a lamellar material and a porous material comprising an active substance and/or a microorganism

Patent metadata

Field	Value
Publication number	US-11655156-B2
Application number	US-201916964125-A
Country	US
Kind code	B2
Filing date	Jan 22, 2019
Priority date	Jan 23, 2018
Publication date	May 23, 2023
Grant date	May 23, 2023

Abstract

The present invention concerns a process for preparing a composite of porous material/compound/hybrid organic-inorganic material having a 2:1 lamellar structure, said hybrid material having the following general formula I:

Na x [(Mg 3 )(Al x (RSi) 4−x )O 8+x (OH) 2 ]  (I)

wherein

x is a number such that 0≤x<1.2 and

R represents a C 1 -C 30 alkyl group, an aryl group, a (C 1 -C 30 alkyl)aryl group or an O—(C 1 -C 30 alkyl) group, it being possible for the alkyl group to be substituted with a group chosen from a phenyl, vinyl, aminopropyl or mercaptopropyl group,

and said compound being chosen from the group constituted of at least one active substance and at least one microorganism and mixtures thereof the process comprising:

a) the step of sol-gel synthesis of the hybrid organic-inorganic material having a 2:1 lamellar structure in the presence of the compound and of the porous material saturated with the compound;

b) the recovery of the composite.

It also concerns a composite obtainable by means of this process, a composition comprising it and its use in particular for the fertilization of plants.

First claim

The invention claimed is:

1. A process for preparing a composite of porous material/compound/hybrid organic-inorganic material having a 2:1 lamellar structure, said hybrid material having the following general formula I:
Na x [(Mg 3 )(Al x (RSi) 4−x )O 8+x (OH) 2 ]  (I)

wherein
x is a number such that 0≤x<1.2 and
R represents a C 1 -C 30 alkyl group, an aryl group, a (C 1 -C 30 alkyl)aryl group or an O—(C 1 -C 30 alkyl) group, the alkyl group being optionally substituted with at least one substituent selected from phenyl, vinyl or mercaptopropyl,
and said compound being selected from the group consisting of at least one active substance and at least one microorganism and mixtures thereof,
the process comprising:
a) the step of sol-gel synthesis of the hybrid organic-inorganic material having a 2:1 lamellar structure in the presence of the compound and of the porous material saturated with the compound; and
b) the recovery of the composite,
wherein the silicon source required for the synthesis of the hybrid material of formula I of step a) is an organoalkoxysilane or a mixture of organoalkoxysilanes having the following general formula II: RSi(OR′) 3 (II);
wherein R′ is a methoxy or ethoxy group.

2. The process as claimed in claim 1 , wherein step a) comprises the following steps:
a1) addition of a magnesium source, of the compound, of the porous material saturated with the compound, of the silicon source, in the case where x≠0, of the aluminum source, and of a solvent;
a2) adjustment of the pH to between 8 and 14;
a3) stirring of the mixture so as to obtain a gel;
a4) recovery of the solid phase of the gel obtained in step a3);
a5) drying of the solid phase of the gel obtained in step a4).

3. The process as claimed in claim 2 , wherein the compound comprises a microorganism and the microorganism in step a1) is in the form of a preculture of said microorganism, and the process comprises a prior step, before step a), of preparation of the microorganism preculture.

4. The process as claimed in claim 1 , wherein x=0.

5. The process as claimed in claim 1 , wherein the compound is an amino acid active substance.

6. The process as claimed in claim 1 , wherein the compound is a microorganism selected from the group consisting of a bacterium, a microalga, a fungus and mixtures thereof.

7. The process as claimed in claim 1 , wherein the porous material is activated or non-activated carbon.

8. The process as claimed in claim 1 , wherein the silicon source is selected from the group consisting of phenyltrimethoxysilane of the following formula (a): Phenyl-Si(OCH 3 ) 3 (a), tetraethyl orthosilicate of the following formula (b): Si(OC 2 H 5 ) 4 (b), hexadecyltrimethoxysilane of the following formula (c): CH 3 (CH 2 ) 14 CH 2 —Si(OCH 3 ) 3 (c), methyltriethoxysilane (MTES) of the following formula (d): CH 3 —Si(OCH 3 ) 3 (d) and mixtures thereof.

9. The process as claimed in claim 1 , which comprises a prior step, before step a), of preparation of the porous material saturated with the compound.

10. The process as claimed in claim 1 , wherein the compound is tryptophan.

11. The process as claimed in claim 1 , wherein the porous material is activated carbon.

12. The process as claimed in claim 1 , wherein the silicon source is hexadecyltrimethoxysilane of the following formula (c): CH 3 (CH 2 ) 14 CH 2 —Si(OCH 3 ) 3 (c).

13. The process as claimed in claim 1 , wherein the source of silicon is selected from the group consisting of phenyltrimethoxysilane (a) and hexadecyltrimethoxysilane (c).

14. A composite of porous material/compound/hybrid organic-inorganic material having a 2:1 lamellar structure of formula (I), obtained by means of the process as claimed in claim 1 .

15. A composition comprising the composite as claimed in claim 14 and an excipient.

16. The composition as claimed in claim 15 , which is in solid form, in liquid form or in gel form.

17. The composition as claimed in claim 16 , wherein the solid form is in powder, granule or microgranule form.

18. The composition as claimed in claim 15 which allows the controlled release of the compound in the soil.

19. The composition as claimed in claim 15 , which also comprises nutrients, organic raw materials and/or mineral raw materials.

20. A method for the fertilization, nutrition, growth stimulation and/or prophylaxis of plants and/or the improvement of the physical, chemical and/or biological properties of the soil or of the culture substrate of plants comprising the administration of an effective amount of the composite as claimed in claim 14 , or of a composition comprising the composite as claimed in claim 14 and an excipient, to a plant in need thereof or to the soil or culture substrate of a plant in need thereof.

21. The method as claimed in claim 20 application to the leaves, the roots, in an open field or in soilless culture of the plant in need thereof.

Assignees

• Agro Innovation Int
• Univ Haute Alsace
• Centre Nat Rech Scient

Inventors

• Pluchon Sylvain K
• Yvin Jean-Claude
• Brendle Jocelyne
• Limousy Lionel
• Dutournie Patrick
• Maillard Anne
• Bruneau Marion
• Bennici Simona

Classifications

• A01N63/22

  Bacillus · CPC title

• C05G3/80

  Soil conditioners · CPC title

• A01N65/03

  Algae · CPC title

• C05F11/08

  Organic fertilisers containing added bacterial cultures, mycelia or the like · CPC title

• C05G5/12

  Granules or flakes · CPC title