Hydrogen gas producing apparatus using photocatalyst

Patent metadata

Field	Value
Publication number	US-11654412-B2
Application number	US-202117495625-A
Country	US
Kind code	B2
Filing date	Oct 6, 2021
Priority date	Oct 11, 2020
Publication date	May 23, 2023
Grant date	May 23, 2023

Abstract

In an apparatus producing hydrogen gas by the decomposition reaction of water using photocatalyst, its miniaturization is achieved while suppressing the decrease of production efficiency of hydrogen gas as low as possible or improving the efficiency. The apparatus 1 comprises a container portion 2 receiving water W; a photocatalyst member 3 immersed in the water, having photocatalyst which generates excited electrons and positive holes when irradiated with light, causes a decomposition reaction of the water and generates hydrogen gas; a light source 4 emitting the light irradiated to the photocatalyst member; and a heat exchange device 7 conducting waste heat of the light source to the water in the container portion; wherein the water to be decomposed on the photocatalyst member in the container portion is warmed by the waste heat of the light source by the heat exchange device.

First claim

The invention claimed is:

1. A hydrogen gas producing apparatus, comprising:
a container portion which receives water,
a photocatalyst member placed in the container portion to be immersed in the water therein, which member has photocatalyst which generates excited electrons and positive holes when it is irradiated with light, causes a decomposition reaction of the water which decomposes water into hydrogen and oxygen and generates hydrogen gas;
a light source emitting the light which is irradiated to the photocatalyst member and induces the decomposition reaction of the water; and
a heat exchange device which conducts waste heat of the light source to the water in the container portion;
wherein the water to be decomposed on the photocatalyst member in the container portion is warmed by the waste heat of the light source by the heat exchange device, and
wherein the photocatalyst member comprises plural plate members in which the photocatalyst is fixed in layer in a surface direction of each of the plate members, the plate members being arranged so that their respective surfaces are mutually faced and inclined to become closer to one another as those are farther away from the light source, and an incident angle of the light emitted from the light source to each surface of the plate members is larger than 0°.

2. The apparatus of claim 1 , wherein the light source is operated with electric power obtained by solar power generation and emits the light irradiated to the photocatalyst member while waste heat in the operation of the light source is conducted to the water by the heat exchange device.

3. The apparatus of claim 1 , wherein a density of the light irradiated to the photocatalyst member is adjusted at or lower than a density which gives a photocatalyst efficiency more than a predetermined value, which efficiency is a ratio of an amount of the generated hydrogen gas per photon quantity entering into the photocatalyst.

4. The apparatus of claim 1 , wherein the apparatus is configured to confine the light emitted from the light source in the container portion.

5. The apparatus of claim 4 , wherein the container portion has a light reflecting mechanism for confining the light emitted from the light source in the container portion.

6. The apparatus of claim 4 , wherein the photocatalyst member is a member on which the photocatalyst is formed in layer, and the photocatalyst layer is formed in a thickness that not all the light is absorbed in the photocatalyst when the light enters into the photocatalyst layer for the first time, and the light which penetrated through the photocatalyst member is irradiated again to the photocatalyst member.

7. The apparatus of claim 1 , wherein the container portion has a heat insulation mechanism which suppresses heat dissipation from the water to outside of the container portion.

8. The apparatus of claim 1 , wherein the layer of the photocatalyst of the photocatalyst member is formed in a thickness which increases as it is farther away from the light source.

9. The apparatus of claim 1 , wherein the photocatalyst member is configured to satisfy a condition that the light emitted from the light source reflects on the plate members twice or more.

10. The apparatus of claim 1 , wherein an emission wavelength of the light source is selected to fall in a wavelength band in which a quantum yield of the photocatalyst exceeds beyond a predetermined threshold value.

11. A hydrogen gas producing apparatus, comprising:
a container portion which receives water,
a photocatalyst member placed in the container portion to be immersed in the water therein, which member has photocatalyst which generates excited electrons and positive holes when it is irradiated with light, causes a decomposition reaction of the water which decomposes water into hydrogen and oxygen and generates hydrogen gas;
a light source emitting the light which is irradiated to the photocatalyst member and induces the decomposition reaction of the water; and
a heat exchange device which conducts waste heat of the light source to the water in the container portion;
wherein the water to be decomposed on the photocatalyst member in the container portion is warmed by the waste heat of the light source by the heat exchange device,
wherein the light source is operated with electric power obtained by solar power generation and emits the light irradiated to the photocatalyst member while waste heat in the operation of the light source is conducted to the water by the heat exchange device, and
wherein a rated output of the light source is adjusted so that a light emitting efficiency of the light source will be maximized when a current is supplied to the light source at a rated current value of the solar power generation.

12. The apparatus of claim 11 , wherein a density of the light irradiated to the photocatalyst member is adjusted at or lower than a density which gives a photocatalyst efficiency more than a predetermined value, which efficiency is a ratio of an amount of the generated hydrogen gas per photon quantity entering into the photocatalyst.

13. The apparatus of claim 11 , wherein the apparatus is configured to confine the light emitted from the light source in the container portion.

14. The apparatus of claim 13 , wherein the container portion has a light reflecting mechanism for confining the light emitted from the light source in the container portion.

15. The apparatus of claim 13 , wherein the photocatalyst member is a member on which the photocatalyst is formed in layer, and the photocatalyst layer is formed in a thickness that not all the light is absorbed in the photocatalyst when the light enters into the photocatalyst layer for the first time, and the light which penetrated through the photocatalyst member is irradiated again to the photocatalyst member.

16. The apparatus of claim 11 , wherein the container portion has a heat insulation mechanism which suppresses heat dissipation from the water to outside of the container portion.

17. The apparatus of claim 11 , wherein an emission wavelength of the light source is selected to fall in a wavelength band in which a quantum yield of the photocatalyst exceeds beyond a predetermined threshold value.

18. A hydrogen gas producing apparatus, comprising:
a container portion which receives water,
a photocatalyst member placed in the container portion to be immersed in the water therein, which member has photocatalyst which generates excited electrons and positive holes when it is irradiated with light, causes a decomposition reaction of the water which decomposes water into hydrogen and oxygen and generates hydrogen gas;
a light source emitting the light which is irradiated to the photocatalyst member and induces the decomposition reaction of the water; and
a heat exchange device which conducts waste heat of the light source to the water in the container portion;
wherein the water to be decomposed on the photocatalyst member in the container portion is warmed by the waste heat of the light source by the heat exchange device,
wherein the light source is operated with electric power obtained by solar power generation and emits the light irradiated to the photocatalyst member while waste heat in the operation of the light source is conducted to the water by the heat exchange device, and
wherein the light source includes two or more LEDs, and a number of operated LEDs in the two or more LEDs is changed so that a light emitting efficiency of the light source will be maximized in accordance with an output current of

Assignees

• Toyota Motor Co Ltd
• Toyoda Gosei Kk

Inventors

• Masuda Taizo
• Okumura Kenichi
• Tomizawa Ryota
• Yoshimura Atsuki

Classifications

• C01B3/042 Primary

  Decomposition of water (by electrolysis of water C25B1/04) · CPC title

• B01J2219/0892

  involving catalytically active material · CPC title

• B01J2219/0871

  Heating or cooling of the reactor · CPC title

• B01J2219/1203

  Incoherent waves · CPC title

• B01J16/005

  in the presence of catalytically active bodies, e.g. porous plates · CPC title