Process for preparing organopolysiloane gels

Patent metadata

Field	Value
Publication number	US-11654098-B2
Application number	US-201716622056-A
Country	US
Kind code	B2
Filing date	Jun 12, 2017
Priority date	Jun 12, 2017
Publication date	May 23, 2023
Grant date	May 23, 2023

Abstract

Storage stable organopolysiloxane gels, preparable in commercial quantities are prepared by the hydrosilylation reaction of a silicone resin containing a hydrosilyatable group, a short chain Si—H-functional silicone, and a long chain Si—H-functional silicone.

First claim

The invention claimed is:

1. A process for producing organopolysiloxane gels, comprising:
reacting
(1a) unsaturated organopolysiloxane resins comprising units of the formulae
SiO 2 (Q units) and
R 3 SiO 1/2 and R 2 R 1 SiO 1/2 (M units),

where
R each independently is a monovalent, optionally substituted hydrocarbon radical having 1 to 18 carbon atoms per radical,
R 1 each independently is a monovalent hydrocarbon radical onto which Si-H groups are optionally added in a hydrosilylation reaction,
with the proviso that the organopolysiloxane resins contain at least 2 R 1 radicals, and that the molar ratio of M units to Q units is in the range from 0.5 to 4.0, the organopolysiloxane resins optionally containing, in addition to the M and Q units, small amounts of RSiO 3/2 (T) units and/or R 2 SiO 2/2 (D) units, in amounts of 0.01 to 20 mol %, based on the sum total of all siloxane units, the organopolysiloxane resins optionally containing up to 10% by weight of Si-bonded hydroxyl or alkoxy groups,
and optionally
(1b) compounds having a polar organic group and a hydrosilylatable end group, with
(2) a mixture of two Si-H-containing organopolysiloxanes which have different average chain lengths, of the formula:
(R 2 3-x H x SiO 1/2 ) (R 2 2 SiO 2/2 ) a (R 2 HSiO 2/2 ) b (R 2 3-x H x SiO 1/2 )  (I)

where R 2 each independently is an unsubstituted or optionally heteroatom-substituted, aliphatic, cycloaliphatic or aromatic, optionally polycyclic, C 1 -C 18 hydrocarbon radical,
x is 0 or 1,
a and b are each integers ≥0,
with the provisos that the sum total of a+b ≥30, that the organopolysiloxanes contain an average of at least 2 Si-bonded hydrogen atoms, and that the long-chain organopolysiloxane has at least 3 times the chain length (a+b) of the short-chain organopolysiloxane,
in the presence of
(3) catalysts that promote the addition of Si-bonded hydrogen onto aliphatic multiple bonds,

where (1a), optionally (1b) and (2) is/are dispersed in
(4) diluents

and the reaction is stopped by addition of
(5) stopper compounds used as catalyst poisons.

2. The process of claim 1 , wherein x=0 in formula (I).

3. The process of claim 1 , wherein the sum of a+b >55 in the formula (I).

4. The process of claim 1 , wherein catalysts (3) are metal catalysts in amounts of 1 to 100 ppm by weight (parts per weight per million parts by weight), calculated as elemental metal, based in each case on the total weight of components (1a), optionally (1b) and (2).

5. The process of claim 1 , wherein at least one diluent (4) is a polydimethylsiloxane having 2 to 50 silicon atoms, an aliphatic or alicyclic hydrocarbons having 4 to 30 carbon atoms, or an ester of a carboxylic acid having 2 to 30 carbon atoms.

6. The process of claim 1 , wherein at least one stopper compound (5) is an organic compound having mercapto groups (SH) or an organopolysiloxane having mercaptoalkyl groups.

7. The process of claim 1 , wherein the stopper compounds (5) are used in amounts of at least 1.1 mol of functional group that brings about the stopping per mole of elemental metal.

8. The process of claim 1 , wherein the organopolysiloxane gels obtained after the reaction are homogenized to obtain organopolysiloxane gels which do not separate into two or more phases in the course of storage at room temperature (20° C.) for six months.

9. The process of claim 1 , wherein the organopolysiloxane gels obtained are diluted with further diluents (4) and/or active ingredients for personal care or healthcare and then optionally homogenized.

10. A cosmetic composition comprising an organopolysiloxane gel produced according to claim 1 .

Assignees

• Wacker Chemie Ag

Inventors

• Sandmeyer Frank
• Schosser Christoph

Classifications

• A61K8/895

  containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone · CPC title

• C08L83/04 Primary

  Polysiloxanes · CPC title

• C08G77/70

  Siloxanes defined by use of the MDTQ nomenclature · CPC title

• C08G77/18

  to alkoxy or aryloxy groups · CPC title

• A61K8/891

  saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone · CPC title