Method for producing metal titanium

Patent metadata

Field	Value
Publication number	US-11649554-B2
Application number	US-201917267572-A
Country	US
Kind code	B2
Filing date	Jul 18, 2019
Priority date	Aug 31, 2018
Publication date	May 16, 2023
Grant date	May 16, 2023

Abstract

A method for producing metal titanium by carrying out electrolysis using an anode and a cathode in a molten salt bath, the method using an anode containing metal titanium as the anode, the method comprising a titanium deposition step of depositing metal titanium on the cathode, wherein, in the titanium deposition step, a temperature of the molten salt bath is from 250° C. or more and 600° C. or less, and an average current density of the cathode in a period from the start to 30 minutes later of the titanium deposition step is maintained in a range of 0.01 A/cm 2 to 0.09 A/cm 2 .

First claim

The invention claimed is:

1. A method for producing metal titanium by carrying out electrolysis using an anode and a cathode in a molten salt bath, the method comprising:
a titanium deposition step of depositing metal titanium on the cathode, wherein, in the titanium deposition step, a temperature of the molten salt bath is from 250° C. or more and 600° C. or less, and an average current density of the cathode in a period from the start to 30 minutes later of the titanium deposition step is maintained in a range of from 0.01 A/cm 2 to 0.09 A/cm 2 , and
a titanium separation step of mechanically separating the metal titanium deposited on the cathode from the cathode after the titanium deposition step,
wherein the metal titanium is produced in the form of a sheet having a thickness of from 20 μm to 1000 μm,
wherein at least a surface of the cathode is made from metal titanium, and
wherein the anode contains metal titanium.

2. The method according to claim 1 , wherein in the titanium deposition step, a surface area of a cathode immersed portion that is immersed in the molten salt bath is 3000 mm 2 or more.

3. The method according to claim 1 , wherein a surface of the cathode on which metal titanium is deposited in the titanium deposition step has a curved surface shape.

4. The method according to claim 3 , wherein the cathode has a cylindrical shape.

5. The method according to claim 1 , wherein the molten salt bath contains at least two selected from the group consisting of MgCl 2 , NaCl, KCl, CaCl 2 , LiCl, alkali metal iodides, and alkali metal bromides.

6. The method according to claim 5 , wherein the molten salt bath contains 80 mol % or more of at least two selected from the group consisting of MgCl 2 , NaCl, KCl, CaCl 2 , and LiCl.

7. The method according to claim 1 , wherein the molten salt bath contains from 3 mol % to 12 mol % of TiCl 2 .

8. The method according to claim 1 , wherein the molten salt bath does not contain BaCl 2 .

9. The method according to claim 1 , wherein the cathode contains 70% by mass or more of Ti, Mo, or Fe.

10. The method according to claim 1 , further comprising an anode dissolving step of dissolving the anode by electrolysis in the molten salt bath prior to the titanium deposition step.

11. The method according to claim 1 , wherein in the titanium deposition step, the average current density of the cathode after the period is changed and maintained in a range of 0.01 A/cm 2 to 5.00 A/cm 2 .

12. The method according to claim 1 , wherein the anode comprises titanium sponge, a titanium rod, and/or a titanium plate.

Assignees

• Toho Titanium Co Ltd

Inventors

• Horikawa Matsuhide
• Suzuki Daisuke
• Yamamoto Haruka
• Fujii Hideki

Classifications

• C25C7/025 Primary

  used in cells for the electrolysis of melts · CPC title

• C25C7/06

  Operating or servicing · CPC title

• C25C3/28 Primary

  of titanium · CPC title

• C22B34/12

  Obtaining titanium {or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08} · CPC title

• C25C7/08

  Separating of deposited metals from the cathode · CPC title