Polyethylene blends and films

Patent metadata

Field	Value
Publication number	US-11649331-B2
Application number	US-201917309173-A
Country	US
Kind code	B2
Filing date	Nov 13, 2019
Priority date	Nov 13, 2018
Publication date	May 16, 2023
Grant date	May 16, 2023

Abstract

Provided herein are polyethylene films made of the polyethylene blends having improved properties, particularly in Elmendorf tear and puncture resistance. The polyethylene blends include two primary polyethylene blends.

First claim

What is claimed is:

1. A film comprising a secondary polyethylene blend, the secondary polyethylene blend comprising a first primary polyethylene blend and a second primary polyethylene blend, the first primary polyethylene blend and the second primary polyethylene blend each comprising two polyethylene compositions, each having a density, wherein the density of each of the polyethylene compositions differs from the other in an amount between about 0.050 g/cm 3 and about 0.060 g/cm 3 ; and further wherein the film has (i) an average MD/TD 1% secant modulus greater than or equal to about 3300 psi and (ii) either (ii-a) a heat seal initiation temperature at 5 N of less than or equal to about 95° C. or (ii-b) a heat seal initiation temperature at 1 N of less than or equal to about 95° C.

2. The film of claim 1 , wherein the first polyethylene blend and the second polyethylene blend each has a density between about 0.918 g/cm 3 and about 0.922 g/cm 3 , and an MI (I 2 ) between about 0.90 g/10 min and about 1.10 g/10 min.

3. The film of claim 1 , wherein each polyethylene composition of each primary polyethylene blend has a density between about 0.890 g/cm 3 and about 0.960 g/cm 3 .

4. The film of claim 1 , wherein each of the polyethylene compositions has an MI (I 2 ) between about between about 0.1 g/10 min and about 15.0 g/10 min.

5. The film of claim 1 , wherein film has a thickness of about 1 mil or about 3 mil.

6. The film of claim 1 , wherein the first primary polyethylene blend comprises a first polyethylene composition having a density of about 0.8961 g/cm 3 and a second polyethylene composition having a density of about 0.9510 g/cm 3 .

7. The film of claim 6 , wherein the first primary polyethylene blend comprises the first polyethylene composition in an amount between about 55 wt % and about 57 wt % and has an MI (I 2 ) of about 0.3 g/10 min.

8. The film of claim 6 , wherein the first primary polyethylene blend comprises the second polyethylene composition in an amount between about 43 wt % and about 45 wt % and has an MI (I 2 ) of about 15.0 g/10 min.

9. The film of claim 1 , wherein the second primary polyethylene blend comprises a first polyethylene composition having a density of about 0.8983 g/cm 3 and a second the other polyethylene composition has a density of about 0.9516 g/cm 3 .

10. The film of claim 9 , wherein the second primary polyethylene blend comprises the first polyethylene composition in an amount between about 56 wt % and about 58 wt % and has an MI (I 2 ) of about 7.8 g/10 min.

11. The film of claim 9 , wherein the second primary polyethylene blend comprises the second polyethylene composition in an amount between about 42 wt % and about 44 wt % and has an MI (I 2 ) of about 0.2 g/10 min.

12. The film of claim 1 , wherein each of the polyethylene compositions has an M w /M n between about 2.5 and about 4.0.

13. A film having an average MD/TD 1% secant modulus greater than or equal to about 3300 psi, a heat seal initiation temperature at 5 N of less than or equal to about 95° C., and a hot tack seal initiation temperature at 1 N of less than or equal to about 95° C., the film comprising a secondary polyethylene blend comprising two primary polyethylene blends, each primary polyethylene blend having a density between about 0.918 g/cm 3 and about 0.922 g/cm 3 and an MI (I 2 ) between about 0.90 g/10 min and about 1.10 g/10 min, wherein each primary polyethylene blend comprises two polyethylene compositions, each of the polyethylene compositions having a density between about 0.890 g/cm 3 and about 0.960 g/cm 3 and an MI (I 2 ) between about 0.1 g/10 min and about 15.0 g/10 min, wherein the density of each of the polyethylene compositions differs from the other in an amount of about 0.055 g/cm 3 .

14. A film comprising a secondary polyethylene blend, the secondary polyethylene blend comprising a first polyethylene blend component and a second polyethylene blend component, wherein:
the first polyethylene blend component has a broad orthogonal comonomer distribution, and furthermore comprises either (i) two polyethylene compositions having a density spread of from about 0.050 g/cm 3 and about 0.060 g/cm 3 or (ii) a single polyethylene composition that exhibits at least a first peak and a second peak in a comonomer distribution analysis; and
the second polyethylene blend component has a substantially uniform comonomer distribution and comprises two polyethylene compositions having a density spread of about 0.050 g/cm 3 to about 0.060 g/cm 3 .

15. The film of claim 14 , wherein each of the polyethylene compositions independently has:
a density between about 0.890 g/cm 3 and about 0.960 g/cm 3 ;
an MI (I 2 ) between about 0.90 g/10 min and about 1.10 g/10 min; or
a combination thereof.

16. The film of claim 14 , wherein the first polyethylene blend component and the second polyethylene blend component each independently has:
a density between about 0.918 g/cm 3 and about 0.922 g/cm 3 ;
an MI (I 2 ) between about 0.1 g/10 min and about 15.0 g/10 min; or
a combination thereof.

17. The film of claim 14 , wherein the film has an average MD/TD 1% secant modulus greater than or equal to about 3300 psi, a heat seal initiation temperature at 5 N of less than or equal to about 95° C., and a hot tack seal initiation temperature at 1 N of less than or equal to about 95° C.

18. The film of claim 14 , wherein the first polyethylene blend component exhibits at least a first peak and a second peak in a comonomer distribution analysis, wherein the first peak has a maximum at a log(M w ) value of 4.0 to 5.4 and a TREF elution temperature of 70.0° C. to 100° C., and the second peak has a maximum at a log(M w ) value of 5.0 to 6.0 and a TREF elution temperature of 5° C. to 60°.

19. The film of claim 14 , wherein comonomer contents of polymer fractions across the molecular weight range of the second primary polyethylene blend vary by <10.0 wt %.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Lue Ching-Tai
• Li Dongming
• Rangwalla Hasnain
• Yott Matthew F

Classifications

• B29C48/0018

  combined with shaping by orienting, stretching or shrinking, e.g. film blowing (B29C48/0017 takes precedence) · CPC title

• C08L2203/162

  sealable films · CPC title

• C08L23/0815

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title

• C08J5/18 Primary

  Manufacture of films or sheets · CPC title

• C08J2323/08

  Copolymers of ethene (C08J2323/16 takes precedence) · CPC title