Anti-scale deposition hierarchical coatings for wellbore applications

Patent metadata

Field	Value
Publication number	US-11643730-B2
Application number	US-201916456634-A
Country	US
Kind code	B2
Filing date	Jun 28, 2019
Priority date	Jun 28, 2019
Publication date	May 9, 2023
Grant date	May 9, 2023

Abstract

The disclosure provides for anti-scale deposition coatings for use on surface, such as on oilfield parts. The coating includes a first, sublayer of a metal, ceramic, or metal-ceramic composite, which is characterized in having a hardness in excess of 35 HRC. The coating includes a second, top layer over the first layer, that is a polymer. A surface of the first layer may be conditioned to have a roughened or patterned topology for receipt of and adherence with the at least one top layer. The first layer may provide the coating with hardness, and the at least one top layer may provide the coating with low-friction and anti-scale properties.

First claim

What is claimed is:

1. A coated part exposed to wellbore production fluids, the coated part comprising:
a part, the part having a surface; and
a coating disposed on the part, the coating comprising:
at least one sublayer disposed on the surface of the part, the at least one sublayer comprising a metal, a ceramic, or a metal-ceramic composite, wherein the at least one sublayer has a hardness in excess of 35 HRC, and wherein: the at least one sublayer comprises a plating comprising Nickel, Cobalt, or Chromium, and wherein the at least one sublayer includes SiO 2 reinforced electroless-nickel plating; and
at least one top layer disposed on a surface of the at least one sublayer, such that the at least one sublayer is positioned between the surface of the part and the at least one top layer, wherein the at least one top layer comprises a polymer, wherein the surface of the at least one sublayer upon which the at least one top layer is disposed has a topography that defines a patterned or roughened surface texture thereof, wherein the surface of the at least one sublayer upon which the at least one top layer is disposed is an etched surface, and wherein a surface of the at least one top layer, opposite the at least one sublayer, is treated with an organic acid; treated with fluoroalkyl silane molecules; or treated with methyltrichlorosilane.

2. The coated part of claim 1 , wherein the at least one top layer is applied to and coated over an entirety of the at least one sublayer, and wherein the at least one top layer consists essentially of a fluoropolymer.

3. An anti-scale deposition coating applied to a part, the anti-scale deposition coating comprising:
at least one sublayer comprising a metal, a ceramic, or a metal-ceramic composite, wherein the at least one sublayer has a hardness in excess of 35 HRC, and a surface that has a topography that defines a patterned or roughened surface texture thereof, and wherein: the at least one sublayer comprises a plating comprising Nickel, Cobalt, or Chromium, and wherein the at least one sublayer includes SiO2 reinforced electroless-nickel plating; and
at least one top layer disposed on the surface of the at least one sublayer, wherein the at least one top layer comprises a fluoropolymer, wherein the surface of the at least one sublayer upon which the at least one top layer is disposed is an etched surface, and wherein a surface of the at least one top layer, opposite the at least one sublayer, is treated with an organic acid; treated with fluoroalkyl silane molecules; or treated with methyltrichlorosilane.

4. A coated part exposed to wellbore production fluids, the coated part comprising:
a part, the part having a surface; and
a coating disposed on the part, the coating comprising:
at least one sublayer disposed on the surface of the part, the at least one sublayer comprising a metal, a ceramic, or a metal-ceramic composite, wherein the at least one sublayer has a hardness in excess of 35 HRC, and wherein:
the at least one sublayer comprises a plating comprising Nickel, Cobalt, or Chromium deposited by an electrolytic plating process or an electroless plating process; or
the at least one sublayer comprises a thermally-diffused layer comprising M x N y , M x B y , or M x C y , wherein M is a metal, N is nitrogen, B is boron, C is carbon, and x and y are integers; or
the at least one sublayer comprises a composite of tungsten carbide and a metal alloy, where the at least one sublayer comprises at least 40 wt % of carbide based on a total weight of the at least one sublayer, has a thickness of from 10 μm to 125 μm, and has a minimum Rockwell hardness C of 45; or
the at least one sublayer comprises an oxide of aluminum, an oxide of magnesium, or an oxide of titanium, wherein the at least one sublayer has a thickness of from 10 μm to 125 μm and having a minimum Rockwell hardness C of 45; and

at least one top layer disposed on a surface of the at least one sublayer, such that the at least one sublayer is positioned between the surface of the part and the at least one top layer, wherein the at least one top layer comprises a polymer, wherein a surface of the at least one top layer, opposite the at least one sublayer, is treated with an organic acid; treated with fluoroalkyl silane molecules; or treated with methyltrichlorosilane, and wherein the surface of the at least one sublayer upon which the at least one top layer is disposed has a topography that defines a patterned or roughened surface texture thereof, and wherein the at least one top layer comprises a liquid ionic polymer or a pore entrapped fluorinated ionic liquid.

5. The coated part of claim 4 , wherein the at least one top layer is applied to and coated over an entirety of the at least one sublayer, and wherein the at least one top layer consists essentially of a fluoropolymer.

6. The coated part of claim 4 , wherein the at least one top layer is a solid top layer consisting essentially of polytetrafluoroethylene (PTFE), perfluoroalkoxy polymer (PFA), ethylene chlorotrifluoroethylene (ECTFE), or fluorinated ethylene propylene (FEP); or wherein the at least one top layer is a fluidic top layer consisting essentially of perfluoropolyether (PFPE).

7. The coated part of claim 4 , wherein the surface of the at least one top layer, opposite the at least one sublayer, is treated with the organic acid, and wherein the organic acid comprises stearic acid, hexadecanoic acid, or benzoic acid.

8. The coated part of claim 4 , wherein the at least one top layer consists essentially of a fluoropolymer and has a thickness of 5 μm to 25 μm.

9. The coated part of claim 4 , wherein the at least one top layer is applied to and coated over an entirety of the at least one sublayer, and wherein the at least one top layer consists essentially of a fluoropolymer and has a thickness of 5 μm to 25 μm.

10. The coated part of claim 4 , wherein the surface of the at least one top layer, opposite the at least one sublayer, is treated with the organic acid, and wherein the organic acid comprises hexadecanoic acid or benzoic acid.

11. The coated part of claim 4 , wherein the surface of the at least one top layer, opposite the at least one sublayer, is treated with fluoroalkyl silane molecules.

12. The coated part of claim 4 , wherein the surface of the at least one top layer, opposite the at least one sublayer, is treated with methyltrichlorosilane.

13. The coated part of claim 4 , wherein:
the at least one sublayer comprises the plating comprising Nickel, Cobalt, or Chromium,
the at least one sublayer includes SiO 2 reinforced electroless-nickel plating,
the at least one top layer consists essentially of a fluoropolymer and has a thickness of 5 μm to 25 μm, and
the surface of the at least one top layer, opposite the at least one sublayer, is treated with fluoroalkyl silane molecules or methyltrichlorosilane.

Assignees

• Schlumberger Technology Corp

Inventors

• Marya Manuel
• Singh Virendra

Classifications

• C25D3/12

  of nickel or cobalt · CPC title

• C23C28/34

  including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates · CPC title

• C25D9/02

  with organic materials · CPC title

• C25D11/02

  Anodisation · CPC title

• C23C8/32

  of ferrous surfaces · CPC title