Foaming composition

Patent metadata

Field	Value
Publication number	US-11643518-B2
Application number	US-202016906340-A
Country	US
Kind code	B2
Filing date	Jun 19, 2020
Priority date	Dec 22, 2017
Publication date	May 9, 2023
Grant date	May 9, 2023

Abstract

This invention relates to a foaming composition, comprising at least one ethylene-vinyl acetate (EVA) copolymer; at least one foaming agent; at least one peroxide compound; at least one polyamine; at least one crosslinking enhancer; at least one primary antioxidant; and at least one secondary antioxidant; the content of the crosslinking enhancer is from 0.1 to 3% by weight based on the total weight of the composition. A foaming article cured from the foaming composition under the temperature range of 80 to 120° C. according to the present invention exhibits high initial volume expansion ratio at the baking window from 130 to 200° C. and shows excellent stability after storage.

First claim

What is claimed is:

1. A foaming composition comprising:
(a) from 45 to 70% by weight of at least one ethylene-vinyl acetate (EVA) copolymer;
(b) at least one foaming agent;
(c) at least one peroxide compound;
(d) at least one amine, wherein the at least one amine is selected from diethyltoluenediamine, chlorodiaminobenzene, diethanolamine, diisopropanolamine, triethanolamine, tripropanolamine, 1,6- hexanediamine and any combination thereof;
(e) at least one crosslinking enhancer, wherein the at least one crosslinking enhancer is selected from trimethylolpropane trimethacrylate, zinc diethyl dithiocarbamate, di(morpholin-4-yl) disulphide, dipentamethylenethiuram tetrasulfide and any combination thereof;
(f) at least one primary antioxidant; and
(g) at least one secondary antioxidant;

wherein the crosslinking enhancer is present in an amount of from 0.1 to 3% by weight based on the total weight of the composition.

2. The foaming composition of claim 1 , wherein the at least one foaming agent is selected from 4,4′-oxybis(benzenesulfonyl hydrazide), azodicarbonamide, diisopropyl azodicarboxylate and any combination thereof.

3. The foaming composition of claim 1 , wherein the at least one peroxide compound is an organic peroxide compound.

4. The foaming composition of claim 3 , wherein the organic peroxide compound is selected from 2,5-dimethyl-2,5-di(tert-butylperoxy) hexane, tert-butyl peroxybenzoate, benzoyl peroxide, di(tert-butylperoxyisopropyl) benzene, dicumyl peroxide, 1,1-di(t-butylperoxy)-3,3,5-trimethylcyclohexane, butyl 4,4-bis(tert-butyldioxy) valerate, and any combination thereof.

5. The foaming composition of claim 1 , wherein the at least one primary antioxidant is a phenolic antioxidant.

6. The foaming composition of claim 5 , wherein the at least one primary antioxidant is a hindered phenolic antioxidant.

7. The foaming composition of claim 1 , wherein the at least one secondary antioxidant is selected from a phosphorus-containing antioxidant, a sulfur-containing antioxidant and any combination thereof.

8. The foaming composition of claim 1 , further comprising one or more additives selected from at least one adhesive promoter, at least one filler, at least one lubricant, at least one wax, at least one dye and any combination thereof.

9. The foaming composition of claim 1 , wherein (a) the at least one ethylene-vinyl acetate (EVA) copolymer has a vinyl acetate (VA) content of 12% by weight or more and a melt index of 2 to 25 grams per 10 minutes at 190° C./2.16 kg measured by ASTM D1238.

10. A foaming composition comprising components:
(a) from 45 to 70% by weight of at least one EVA copolymer;
(b) from 15 to 30% by weight of at least one foaming agent;
(c) from 0.1 to 10% by weight of at least one peroxide compound;
(d) from 0.001 to 2% by weight of at least one amine, wherein the at least one amine is selected from diethyltoluenediamine, chlorodiaminobenzene, diethanolamine, diisopropanolamine, triethanolamine, tripropanolamine, 1,6- hexanediamine and any combination thereof;
(e) from 0.1 to 3% by weight of at least one crosslinking enhancer;
(f) from 0.04 to 10% by weight of at least one primary antioxidant; and
(g) from 0.01 to 2% by weight of at least one secondary antioxidant;
further comprising a component of one or more additives selected from at least one adhesive promoter, at least one filler, at least one lubricant, at least one wax, at least one dye and any combination thereof;
wherein the weight percentages of all components add up to 100% by weight.

11. The foaming composition of claim 10 , wherein the at least one crosslinking enhancer is present in an amount of from 1 to 2% by weight based on the total weight of the composition.

12. A foaming article made by curing the foaming composition of claim 1 at a temperature of 80 to 120° C.

13. The foaming article of claim 12 , having a change of volume expansion ratio (Rc) of at least 5% after the foaming article is stored under a condition of 40° C. and 50% RH for 6 months and heated at 140° C.

14. A foaming article made by the steps of:
a) mixing the components of the foaming composition of claim 1 to form a homogeneous mixture in the temperature of 15 to 55° C.;
b) obtaining foaming granules by graining the homogeneous mixture by extrusion in a temperature range of 90 to 100° C.; and
c) forming the foaming article from the foaming granules by injection molding in a temperature range of 95 to 105° C.

15. The foaming article of claim 14 , having a change of volume expansion ratio (Rc) of at least 5% after the foaming article is stored under a condition of 40° C. and 50% RH for 6 months and heated at 140° C.

16. A foamed article made from the foaming composition of claim 1 .

17. A vehicle comprising a vehicle part filled with the foamed article of claim 16 .

18. A foaming composition consisting essentially of:
(a) at least two ethylene-vinyl acetate (EVA) copolymers;
(b) at least one foaming agent;
(c) at least one peroxide compound;
(d) at least one amine, wherein the at least one amine is selected from diethyltoluenediamine, chlorodiaminobenzene, diethanolamine, diisopropanolamine, triethanolamine, tripropanolamine, 1,6- hexanediamine and any combination thereof;
(e) at least one crosslinking enhancer;
(f) at least one primary antioxidant;
(g) at least one secondary antioxidant;
(h) one or more additives selected from at least one adhesive promoter, at least one filler, at least one lubricant, at least one wax, at least one dye and any combination thereof;

wherein the crosslinking enhancer is present in an amount of from 0.1 to 3% by weight based on the total weight of the composition.

Assignees

• Henkel Ag & Co Kgaa

Inventors

• Zhang Xinyu
• Chen Qi

Classifications

• C08J9/0023 Primary

  containing oxygen · CPC title

• C08J9/0095

  Mixtures of at least two compounding ingredients belonging to different one-dot groups · CPC title

• C08K5/14

  Peroxides · CPC title

• C08J9/16 Primary

  Making expandable particles · CPC title

• C08J2201/026

  Crosslinking before of after foaming · CPC title