Lubricant additive composition

Patent metadata

Field	Value
Publication number	US-11639481-B2
Application number	US-202217812212-A
Country	US
Kind code	B2
Filing date	Jul 13, 2022
Priority date	Jul 16, 2021
Publication date	May 2, 2023
Grant date	May 2, 2023

Abstract

An additive composition contains a viscosity index improver and a pour point depressant. A process can be used for preparing the additive composition. The additive composition can be used as a lubricant additive in a lubricating oil formulation, and lubricating oil formulations can contain the additive composition.

First claim

The invention claimed is:

1. An additive composition (A), comprising:
a viscosity index improver (V), and
a pour point depressant (P),
wherein the viscosity index improver (V) is a polymer having a weight average molecular weight (Mw) of 100,000 to 1,000,000 g/mol and is obtainable by polymerizing a viscosity index improver monomer composition comprising:
a) 10 to 30% by weight of one or more polybutadiene-based macromonomers a) having a number-average molecular weight of 500 to 10,000 g/mol, based on a total weight of the viscosity index improver monomer composition,
b) 50 to 70% by weight of one or more monomers selected from the group consisting of methyl(meth)acrylate, butyl(meth)acrylate, a styrene monomer having from 8 to 17 carbon atoms, a substituted styrene monomer having 8 to 17 carbon atoms and having an alkyl substituent in a side chain, and a mixture thereof, based on the total weight of the viscosity index improver monomer composition,
c) 1 to 15% by weight of one or more monomers selected from a linear C 7 -C 30 alkyl(meth)acrylate, a branched C 7 -C 30 alkyl(meth)acrylate, and a mixture thereof, based on the total weight of the viscosity index improver monomer composition,
wherein the pour point depressant (P) is a polymer having a weight average molecular weight (Mw) of 10,000 to 60,000 g/mol and is obtainable by polymerizing a pour point depressant monomer composition comprising:
e) 20 to 35% by weight of one or more monomers selected from the group consisting of a linear C 1 -C 6 alkyl(meth)acrylate, a branched C 1 -C 6 alkyl(meth)acrylate, and a mixture thereof, based on a total weight of the pour point depressant monomer composition,
f) 20 to 75% by weight of one or more monomers selected from the group consisting of a linear C 7 -C 15 alkyl(meth)acrylate and a branched C 7 -C 15 alkyl(meth)acrylate, based on the total weight of the pour point depressant monomer composition,
g) 5 to 60% by weight of one or more monomers selected from the group consisting of a linear C 16 -C 24 alkyl(meth)acrylate and a branched C 16 -C 24 alkyl(meth)acrylate, based on the total weight of the pour point depressant monomer composition, and
wherein a weight ratio of (V) to (P) is 99:1 to 80:20, based on a total solid polymer content of (V) and (P) in the additive composition.

2. The additive composition (A) according to claim 1 , wherein the viscosity index improver (V) has a weight-average molecular weight from 100,000 to 600,000 g/mol.

3. The additive composition (A) according to claim 1 , wherein the one or more polybutadiene-based macromonomers a) has a number-average molecular weight of 1,000 to 6,000 g/mol.

4. The additive composition (A) according to claim 1 , wherein the one or more monomers e) is selected from the group consisting of methyl (meth)acrylate, butyl (meth)acrylate, and a mixture thereof.

5. The additive composition (A) according to claim 1 , wherein the amount of the one or more monomers f) is 20 to 60% by weight, based on the total weight of the pour point depressant monomer composition.

6. The additive composition (A) according to claim 1 , wherein the amount of the one or more monomers g) is 20 to 50% by weight, based on the total weight of the pour point depressant monomer composition.

7. The additive composition (A) according to claim 1 , wherein the amounts of the one or more monomers e), the one or more monomers f), and the one or more monomers g) in the pour point depressant monomer composition sum up to 95 to 100% by weight, based on the total weight of the pour point depressant monomer composition.

8. The additive composition (A) according to claim 1 , wherein the amount of the one or more monomers b) is 55 to 70% by weight, based on the total weight of the viscosity index improver monomer composition.

9. The additive composition (A) according to claim 1 , wherein the one or more monomers c) is selected from the group consisting of a linear C 12-14 alkyl methacrylate, a linear C 16-18 alkyl methacrylate, and a mixture thereof.

10. The additive composition (A) according to claim 1 , wherein the viscosity index improver monomer composition further comprises 0 to 20% by weight of one or more monomers d) selected from the group consisting of a (meth)acrylate of an ether alcohol, an aminoalkyl (meth)acrylate, an aminoalkyl (meth)acrylamide, and a mixture thereof.

11. The additive composition (A) according to claim 10 , wherein the amounts of the one or more polybutadiene-based macromonomers a), the one or more monomers b), the one or more monomers c), and the one or more monomers d) in the viscosity index improver monomer composition sum up to 95 to 100% by weight, based on the total weight of the viscosity index improver monomer composition.

12. The additive composition (A) according to claim 1 , wherein the viscosity index improver (V) has a weight-average molecular weight (Mw) from 100,000 to 500,000 g/mol.

13. A method for preparing the additive composition (A) as defined in claim 1 , the method comprising:
providing the viscosity index improver monomer composition and initiating radical polymerization in the viscosity index improver monomer composition, to obtain the viscosity index improver (V),
providing the pour point depressant monomer composition and initiating radical polymerization in the pour point depressant monomer composition, to obtain the pour point depressant (P),
mixing the viscosity index improver (V) with the pour point depressant (P) to provide the additive composition (A).

14. A lubricating oil formulation, comprising:
one base oil or a mixture of base oils, and
the additive composition (A) as defined in claim 1 .

15. A method of improving storage stability, viscosity index, and low temperature performance of a lubricating oil formulation, the method comprising:
adding the additive composition (A) as defined in claim 1 to the lubricating oil formulation.

16. The additive composition (A) according to claim 3 , wherein the one or more polybutadiene-based macromonomers a) has a number-average molecular weight of 1,500 to 5,500 g/mol.

17. The additive composition (A) according to claim 4 , wherein the one or more monomers e) is methyl (meth)acrylate.

18. The additive composition (A) according to claim 5 , wherein the amount of the one or more monomers f) is 25 to 55% by weight, based on the total weight of the pour point depressant monomer composition.

19. The additive composition (A) according to claim 6 , wherein the amount of the one or more monomers g) is 25 to 50% by weight, based on the total weight of the pour point depressant monomer composition.

20. The additive composition (A) according to claim 10 , wherein the viscosity index improver monomer composition comprises 0.1 to 10% by weight of the one or more monomers d).

Assignees

• Evonik Operations Gmbh

Inventors

• Yuki Tsuyoshi
• Arai Yasuo
• Matsuda Tomohiro
• Kishida Nobuhiro

Classifications

• C10M157/00 Primary

  Lubricating compositions characterised by the additive being a mixture of two or more macromolecular compounds covered by more than one of the main groups C10M143/00 - C10M155/00, each of these compounds being essential · CPC title

• C10M2209/084

  Acrylate; Methacrylate · CPC title

• C10M145/14 Primary

  Acrylate; Methacrylate · CPC title

• C10N2030/02

  Pour-point; Viscosity index · CPC title

• C10M169/041

  the additives being macromolecular compounds only · CPC title