Porous ceramics for additive manufacturing, filtration, and membrane applications

Patent metadata

Field	Value
Publication number	US-11638907-B2
Application number	US-201916706526-A
Country	US
Kind code	B2
Filing date	Dec 6, 2019
Priority date	Jun 23, 2017
Publication date	May 2, 2023
Grant date	May 2, 2023

Abstract

In accordance with one aspect of the presently disclosed inventive concepts, a porous ceramic structure includes a three-dimensional printed structure having predefined features, where the three-dimensional structure has a geometric shape. The average length of the features may be at least 10 microns. The three-dimensional structure includes a ceramic material having an open cell structure with a plurality of pores, where the pores form continuous channels through the ceramic material from one side of the ceramic material to an opposite side of the ceramic material.

First claim

What is claimed is:

1. A product, comprising:
a ceramic material having an open cell structure with a plurality of pores, wherein the pores connect through the ceramic material from one side of the ceramic material to an opposite side of the ceramic material; and
an aqueous sorbent solution for absorbing carbon dioxide, the aqueous sorbent solution being positioned in the pores of the ceramic material, wherein a portion of the aqueous sorbent solution is retained in the pores by capillary action.

2. The product as recited in claim 1 , wherein the ceramic material comprises Y 2 O 3 -doped ZrO 2 .

3. The product as recited in claim 1 , wherein an average diameter of the pores is in a range of about 50 nanometers to about 500 nanometers.

4. The product as recited in claim 1 , wherein an average diameter of the pores is in a range of about 50 nanometers to about 200 nanometers.

5. The product as recited in claim 1 , wherein a density of the ceramic material is in a range of about 20% to about 50% of a density of a solid nonporous ceramic form having the same composition as the ceramic material.

6. The product as recited in claim 1 , wherein the ceramic material is in a form of a structure comprising a plurality of crushed ceramic pieces, wherein an average diameter of the crushed ceramic pieces is less than 400 microns.

7. The product as recited in claim 1 , wherein the aqueous sorbent solution is an ionic solution.

8. The product as recited in claim 1 , wherein the ceramic material is nanoporous having nanostructural support for the aqueous sorbent solution.

9. A method of forming the ceramic material as recited in claim 1 , the method comprising:
obtaining an ink, wherein the ink comprises a mixture of metal oxide nanoparticles and a polymer;
forming a body from the ink, wherein forming the body comprises an additive manufacturing process with the ink;
curing the formed body; and
heating the formed body for removing the polymer and for forming the ceramic material from the metal oxide nanoparticles.

10. The method of claim 9 , wherein the additive manufacturing process is direct ink writing, wherein the ink is extruded through a nozzle.

11. The method of claim 10 , wherein features of the formed body have an average diameter of at least a diameter of the nozzle.

12. The method of claim 9 , wherein the ink includes a photoinitiator and an inhibitor, wherein the additive manufacturing is projection micro-stereolithography.

13. The method as recited in claim 12 , wherein features of the formed body have an average length of at least about ten microns.

14. The method as recited in claim 9 , wherein the formed body is a free standing porous structure, wherein the formed body has an average diameter of greater than one centimeter.

15. The method as recited in claim 9 , wherein the ink comprises metal oxide nanoparticles and a polymer resin, wherein a concentration of the metal oxide nanoparticles is at least about 50 wt % of a total mass of the ink.

16. The method as recited in claim 15 , wherein the ink comprises a cross-linking agent.

17. The method as recited in claim 15 , wherein the ink includes metal oxide nanoparticles in a range of about 50 wt % to about 80 wt % of the total mass of the ink.

18. The method as recited in claim 15 , wherein a concentration of the metal oxide nanoparticles is about 60 wt % of the total mass of the ink.

19. The method as recited in claim 15 , wherein a concentration of the metal oxide nanoparticles is about 70 wt % of the total mass of the ink.

20. The method as recited in claim 15 , wherein the metal oxide nanoparticles comprise Y 2 O 3 -doped ZrO 2 .

21. The method as recited in claim 20 , wherein the metal oxide nanoparticles comprising Y 2 O 3 -doped ZrO 2 have an average diameter in a range of at least about 20 nanometers to about 600 nanometers.

22. A product comprising:
a ceramic material having an open cell structure with a plurality of pores, wherein the pores connect through the ceramic material from one side of the ceramic material to an opposite side of the ceramic material; and
an aqueous sorbent solution in the pores of the ceramic material, wherein a portion of the aqueous sorbent solution is retained in the pores by capillary action,
wherein the aqueous sorbent solution is sodium carbonate having a concentration of about 20 wt % solution at room temperature.

23. The product as recited in claim 22 , wherein the ceramic material comprises Y 2 O 3 -doped ZrO 2 .

24. The product as recited in claim 22 , wherein an average diameter of the pores is in a range of about 50 nanometers to about 500 nanometers.

25. The product as recited in claim 22 , wherein an average diameter of the pores is in a range of about 50 nanometers to about 200 nanometers.

26. The product as recited in claim 22 , wherein a density of the ceramic material is in a range of about 20% to about 50% of a density of a solid nonporous ceramic form having the same composition as the ceramic material.

27. The product as recited in claim 22 , wherein the ceramic material is in a form of a structure comprising a plurality of crushed ceramic pieces, wherein an average diameter of the crushed ceramic pieces is less than 400 microns.

28. The product as recited in claim 22 , wherein the aqueous sorbent solution is an ionic solution.

29. The product as recited in claim 22 , wherein the ceramic material is nanoporous having nanostructural support for the aqueous sorbent solution.

30. A porous ceramic structure comprising:
a three-dimensional printed structure having predefined features,
wherein the three-dimensional printed structure has a geometric shape,
wherein an average length of the features is at least 10 microns,
wherein the predefined features comprise a ceramic material having a plurality of pores,
wherein an aqueous sorbent solution for absorbing carbon dioxide is positioned in the pores of the ceramic material, wherein a portion of the aqueous sorbent solution is retained in the pores by capillary action.

31. A filtration medium comprising the porous ceramic structure as recited in claim 30 .

32. The porous ceramic structure as recited in claim 30 , wherein the porous ceramic material comprises Y 2 O 3 -doped ZrO 2 .

33. The porous ceramic structure as recited in claim 30 , wherein an average diameter of the pores is in a range of about 50 nanometers to about 500 nanometers.

34. The porous ceramic structure as recited in claim 30 , wherein the ceramic structure has an open cell structure.

35. The porous ceramic structure as recited in claim 30 , wherein the pores form continuous channels through the ceramic material from one side of the ceramic material to an opposite side of the ceramic material.

Assignees

• L Livermore Nat Security Llc

Inventors

• Campbell Patrick
• Baker Sarah
• Hernandez Maira Ceron
• Knipe Jennifer Marie
• Stolaroff Joshuah K

Classifications

• B01D71/024

  Oxides · CPC title

• B01D69/14111

  with nanoscale dispersed material, e.g. nanoparticles · CPC title

• B01D67/00793

  Dispersing a component, e.g. as particles or powder, in another component · CPC title

• B01J20/28085

  being more than 50 nm, i.e. macropores · CPC title

• B01D53/229

  Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption) · CPC title