Cathode active material for lithium secondary battery and lithium secondary battery including the same

Patent metadata

Field	Value
Publication number	US-11637282-B2
Application number	US-202117401091-A
Country	US
Kind code	B2
Filing date	Aug 12, 2021
Priority date	Aug 13, 2020
Publication date	Apr 25, 2023
Grant date	Apr 25, 2023

Abstract

A cathode active material for a lithium secondary battery includes a lithium-transition metal composite oxide particle having a lattice strain (η) of 0.18 or less, which is calculated by applying Williamson-Hall method defined by Equation 1 to XRD peaks measured through XRD analysis, and having an XRD peak intensity ratio of 8.9% or less, which is defined by Equation 2. By controlling the lattice strain and XRD peak intensity ratio of the lithium-transition metal composite oxide particle, a lithium secondary battery with improved life-span characteristics as well as output characteristics is provided.

First claim

What is claimed is:

1. A cathode active material for a lithium secondary battery comprising a lithium-transition metal composite oxide particle,
wherein a lattice strain (η) calculated by applying Williamson-Hall method defined by Equation 1 to XRD peaks measured through X-ray diffraction (XRD) analysis is 0.18 or less;
an XRD peak intensity ratio defined by Equation 2 is 8.9% or less; and
the lattice strain of the lithium-transition metal composite oxide particle is a slope of a straight line, and the straight line is obtained by acquiring full widths at half maximum of all peaks appearing through the XRD analysis, and substituting the acquired full widths at half maximum in Equation 1 when plotting a horizontal axis with sine, and a vertical axis with β cos θ,
β cos θ=η sin θ+λ/ D   [Equation 1]

wherein in Equation 1, β represents full width at half maximum (FWHM) (rad) of the corresponding peak acquired through the XRD analysis, θ represents a diffraction angle (rad), η represents a lattice strain (dimensionless number), λ represents an X-ray wavelength (Å), and D represents a crystallite size (Å),
XRD peak intensity ratio (%)=100 ×I (110)/{ I (110)+ I (003)}  [Equation 2]

wherein in Equation 2, I(110) represents a maximum height of the peak of a (110) plane of the lithium-transition metal composite oxide particle by the XRD analysis, and I(003) represents a maximum height of the peak of a (003) plane of the lithium-transition metal composite oxide particle by the XRD analysis,
wherein the lithium-transition metal composite oxide particle has a composition represented by Chemical Formula 1 below:
Li x Ni 1−y M y O 2+z , and  [Chemical Formula 1]

wherein in Chemical Formula 1, x is in a range of 0.9≤x≤1.2, y is in a range of 0≤y≤0.7, and z is in a range of −0.1≤z≤0.1, and
wherein M includes Mn and Co.

2. The cathode active material for a lithium secondary battery according to claim 1 , wherein the XRD peak intensity ratio of the lithium-transition metal composite oxide particle is in a range from 4 to 8.9%.

3. The cathode active material for a lithium secondary battery according to claim 1 , wherein the lithium-transition metal composite oxide particle has a polycrystalline structure in crystallography.

4. The cathode active material for a lithium secondary battery according to claim 1 , wherein the lithium-transition metal composite oxide particle has at least one of a single particle, a primary particle, and a secondary particle in morphology.

5. The cathode active material for a lithium secondary battery according to claim 1 , wherein in Chemical Formula 1, (1−y) is 0.8 or more.

6. The cathode active material for a lithium secondary battery according to claim 1 , wherein the lithium-transition metal composite oxide particle is manufactured by reacting a transition metal precursor with a lithium precursor.

7. The cathode active material for a lithium secondary battery according to claim 6 , wherein the transition metal precursor is a Ni—Co—Mn precursor.

8. The cathode active material for a lithium secondary battery according to claim 6 , wherein the lithium precursor includes lithium carbonate, lithium nitrate, lithium acetate, lithium oxide or lithium hydroxide.

9. A lithium secondary battery comprising:
a cathode which comprises a cathode active material layer comprising the cathode active material according to claim 1 ; and
an anode facing the cathode.

10. The cathode active material for a lithium secondary battery according to claim 1 , wherein the lithium-transition metal composite oxide particle comprises a coating element or a doping element,
wherein the coating element or the doping element includes at least one element selected from a group consisting of Al, Ti, Ba, Zr, Si, B, Mg and P.

Assignees

• Sk Innovation Co Ltd
• Sk On Co Ltd

Inventors

• Lee Sang Han
• Kang Min Gu
• Yoon Jeong Bae
• Cho Yong Hyun

Classifications

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M2004/028

  Positive electrodes · CPC title

• H01M4/525 Primary

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• H01M10/052

  Li-accumulators · CPC title

• C01P2006/40

  Electric properties · CPC title