Methods of treating fabrics with organic acids and related treatment compositions

Patent metadata

Field	Value
Publication number	US-11634859-B2
Application number	US-202117173618-A
Country	US
Kind code	B2
Filing date	Feb 11, 2021
Priority date	Feb 13, 2020
Publication date	Apr 25, 2023
Grant date	Apr 25, 2023

Abstract

Processes and uses related to treating fabrics with an organic acid, such as citric acid with certain treatment liquors or consumer product treatment compositions. A process to determine the presence of a metal-based residue on a fabric. Uses of a treatment composition or a treatment liquor to rejuvenate a non-white color of a fabric. Processes to demonstrate and/or display the color-rejuvenation benefits of a treatment composition.

First claim

What is claimed is:

1. A process to determine the presence of a metal-based residue on a fabric, the process comprising the steps of:
providing a vessel with a storage portion and an open mouth;
providing a treatment liquor to the storage portion of the vessel,
the treatment liquor comprising an organic acid,
optionally, forming the treatment liquor by combining a treatment composition and water, the treatment composition comprising the organic acid;

submerging at least a portion of the fabric in the treatment liquor for at least two seconds; and
detecting the presence of released metal-based residue into the treatment liquor, wherein the metal of the metal-based residue is calcium, magnesium, copper, aluminum, or mixtures thereof.

2. The process of claim 1 , wherein the organic acid is selected from the group consisting of citric acid, acetic acid, lactic acid, malic acid, maleic acid, salts thereof, and mixtures thereof.

3. The process of claim 1 , wherein the organic acid is citric acid, a salt thereof, or a mixture thereof.

4. The process of claim 1 , wherein the organic acid is a naturally derived organic acid.

5. The process of claim 1 , wherein the metal of the metal-based residue is calcium.

6. The process of claim 1 , wherein the fabric was prewashed with a powdered laundry detergent.

7. The process of claim 6 , wherein the prewashed fabric has been treated with a laundry detergent in at least two wash cycles.

8. The process of claim 1 , wherein the fabric was prewashed in water having a hardness of from about 0 to about 30 grains per gallon (gpg).

9. The process of claim 1 , wherein the treatment composition comprises from about 5% to about 50%, by weight of the treatment composition, of the organic acid, with the proviso that if the organic acid is acetic acid in the presence of no other organic acid, then the treatment composition comprises from 10% to about 50%, by weight of the treatment composition, of the acetic acid.

10. The process of claim 1 , wherein the fabric comprises cotton fibers, polycotton fibers, or combinations thereof.

11. The process of claim 1 , wherein the fabric comprises a plurality of colors.

12. The process of claim 1 , wherein the metal-based residue is derived from an anionic surfactant, an anionic polymer, a carbonate, a silicate, or a combination thereof.

13. The process of claim 1 , wherein the metal-based residue is derived from a laundry detergent.

14. The process of to claim 1 , wherein the fabric is characterized by:
an original color when new;
a first color when faded; and
a second color following treatment with the treatment liquor;
where the difference in color (ΔE) between of the original color and the second color is less than the difference in color (ΔE) between the original color and the first color.

15. A process to determine the presence of a metal-based residue on a fabric, the process comprising the steps of:
providing a vessel with a storage portion and an open mouth;
providing a treatment liquor to the storage portion of the vessel, the treatment liquor comprising an organic acid, optionally, forming the treatment liquor by combining a treatment composition and water, the treatment composition comprising the organic acid;
submerging at least a portion of the fabric in the treatment liquor for at least two seconds; and
detecting the presence of released metal-based residue into the treatment liquor, wherein the metal-based residue is derived from an anionic surfactant, an anionic polymer, a carbonate, a silicate, or a combination thereof.

16. The process of claim 15 , wherein the metal-based residue is derived from a laundry detergent.

17. The process of to claim 15 , wherein the fabric is characterized by:
an original color when new;
a first color when faded; and
a second color following treatment with the treatment liquor;
where the difference in color (ΔE) between of the original color and the second color is less than the difference in color (ΔE) between the original color and the first color.

Assignees

• Procter & Gamble

Inventors

• Delaney Sarah Ann
• Wenning Genevieve Cagalawan
• Escobar Sol Melissa
• Dickerson Bryan Douglas

Classifications

• C11D7/265

  Carboxylic acids or salts thereof · CPC title

• G01N33/367

  Fabric or woven textiles · CPC title

• C11D3/2075 Primary

  Carboxylic acids-salts thereof · CPC title

• D06M13/192 Primary

  Polycarboxylic acids; Anhydrides, halides or salts thereof {(D06M13/1845 takes precedence)} · CPC title

• C11D3/2086

  Hydroxy carboxylic acids-salts thereof · CPC title