Integrated nitrogen liquefier for a nitrogen and argon producing cryogenic air separation unit

Patent metadata

Field	Value
Publication number	US-11629913-B2
Application number	US-202117241218-A
Country	US
Kind code	B2
Filing date	Apr 27, 2021
Priority date	May 15, 2020
Publication date	Apr 18, 2023
Grant date	Apr 18, 2023

Abstract

A nitrogen liquefier configured to be integrated with an argon and nitrogen producing cryogenic air separation unit and method of nitrogen liquefaction are provided. The integrated nitrogen liquefier and associated methods may be operated in at least three distinct modes including: (i) a nil liquid nitrogen mode; (ii) a low liquid nitrogen mode; and (iii) a high liquid nitrogen mode. The present systems and methods are further characterized in an oxygen enriched stream from the lower pressure column of the air separation unit is an oxygen enriched condensing medium used in the argon condenser.

First claim

What is claimed is:

1. An air separation unit comprising:
a main air compression system configured for receiving a stream of incoming feed air and producing a compressed air stream;
an adsorption based pre-purifier unit configured for removing water vapor, carbon dioxide, nitrous oxide, and hydrocarbons from the compressed air stream and producing a compressed and purified air stream;
a main heat exchange system configured to cool the compressed and purified air stream to temperatures suitable for fractional distillation;
a distillation column system having a higher pressure column and a lower pressure column linked in a heat transfer relationship via a condenser-reboiler, the distillation column system further includes an argon column arrangement operatively coupled with the lower pressure column, the argon column arrangement having at least one argon column and an argon condenser, the distillation column system configured for receiving the cooled, compressed and purified air stream and produce at least two or more oxygen enriched streams from the lower pressure column; an argon product stream, and a gaseous nitrogen product stream;
wherein at least one of the oxygen enriched streams from the lower pressure column is an oxygen enriched condensing medium directed to the argon condenser; and
a nitrogen liquefier comprising a nitrogen feed compressor; a nitrogen recycle compressor; a warm booster compressor, a booster loaded warm turbine, a cold booster compressor, and a booster loaded cold turbine, a flow control valve disposed upstream of the nitrogen feed compressor and a bypass valve configured for diverting a gaseous nitrogen feed stream to the nitrogen recycle compressor;
wherein the nitrogen liquefier is integrated with the main heat exchange system and distillation column system and wherein the nitrogen liquefier is arranged or configured to receive a portion of the gaseous nitrogen product stream and produce a liquid nitrogen stream;
wherein the nitrogen liquefier is configured to operate in three modes, including: (i) a first nil liquid nitrogen mode where no portion of the gaseous nitrogen product stream is diverted to the nitrogen liquefier and no liquid nitrogen product stream is produced in the nitrogen liquefier; (ii) a second low liquid nitrogen mode wherein a portion of the gaseous nitrogen product stream is diverted as the gaseous nitrogen feed stream to the nitrogen liquefier, the gaseous nitrogen feed stream bypasses the nitrogen feed compressor and is diverted to the nitrogen recycle compressor; and (iii) a third high liquid nitrogen mode wherein a portion of the gaseous nitrogen product stream is diverted as the gaseous nitrogen feed stream to the nitrogen feed compressor of the nitrogen liquefier.

2. The air separation unit of claim 1 , wherein the nitrogen liquefier further comprises wherein the bypass valve is an expansion valve configured for reducing the pressure of the gaseous nitrogen feed stream diverted to the nitrogen recycle compressor.

3. The air separation unit of claim 1 , wherein in the first nil liquid nitrogen mode, the flow control valve and the bypass valve are both in a closed position such that none of the gaseous nitrogen product stream is diverted to the nitrogen liquefier.

4. The air separation unit of claim 1 , wherein in the second low liquid nitrogen mode, the flow control valve is in a closed position and the bypass valve is in an open position such that a portion of the gaseous nitrogen product stream is diverted to the nitrogen recycle compressor of the nitrogen liquefier.

5. The air separation unit of claim 4 , wherein the portion of the gaseous nitrogen product stream is diverted to the nitrogen recycle compressor portion is between 1% and 5% of the gaseous nitrogen product stream, by volumetric flow.

6. The air separation unit of claim 1 , wherein in the third high liquid nitrogen mode, the flow control valve is in an open position and the bypass valve is in a closed position such than a portion of the gaseous nitrogen product stream is diverted to the nitrogen feed compressor of the nitrogen liquefier.

7. The air separation unit of claim 6 , wherein the portion of the gaseous nitrogen product stream diverted to the nitrogen liquefier is between 5% and 10% of the gaseous nitrogen product stream.

8. The air separation unit of claim 1 , wherein:
the argon column is configured to receive an argon-oxygen enriched stream from the lower pressure column and to produce a third oxygen enriched stream that is returned to or released into the lower pressure column and an argon-enriched overhead that is directed to the argon condenser; and
the argon condenser is configured to condense the argon-enriched overhead against the oxygen enriched condensing medium taken from the lower pressure column to produce a crude argon stream, an argon reflux stream and an oxygen enriched waste stream.

9. The air separation unit of claim 8 , wherein the argon condenser is configured to condense the argon-enriched overhead against a mixture of the oxygen enriched condensing medium taken from the lower pressure column and a source of liquid nitrogen to produce the crude argon stream, the argon reflux stream and the oxygen enriched waste stream.

10. The air separation unit of claim 9 , wherein the source of liquid nitrogen is a portion of the liquid nitrogen product stream taken from a nitrogen subcooler.

11. The air separation unit of claim 8 , wherein the oxygen enriched waste stream is warmed in the main heat exchange system and used to regenerate the adsorption based pre- purification unit.

12. The air separation unit of claim 11 , wherein the oxygen enriched waste stream is further compressed upstream of the adsorption based pre-purification unit.

Assignees

• Kromer Brian R
• Prosser Neil M
• Cabral Jeremy M
• Handley James R
• Praxair Technology Inc

Inventors

• Kromer Brian R
• Prosser Neil M
• Cabral Jeremy M
• Handley James R

Classifications

• F25J3/04496

  for compensating variable air feed or variable product demand by alternating between periods of liquid storage and liquid assist · CPC title

• F25J3/04412 Primary

  in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column · CPC title

• F25J3/0486

  of vaporisers for oxygen enriched liquids, e.g. purging of liquids · CPC title

• F25J3/04357

  and comprising a gas work expansion loop · CPC title

• F25J3/04727

  using an auxiliary pure argon column for nitrogen rejection (F25J3/04739 takes precedence) · CPC title