Low-emission, stabilized polyurethane
US-2016137814-A1 · May 19, 2016 · US
US11629457B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11629457-B2 |
| Application number | US-201716312856-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 22, 2017 |
| Priority date | Jun 29, 2016 |
| Publication date | Apr 18, 2023 |
| Grant date | Apr 18, 2023 |
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An automobile instrument panel surface material includes a microfiber having an average single fiber diameter of 0.3 to 7 μm; and polyurethane, the automobile instrument panel surface material having nap formed of the microfiber, the automobile instrument panel surface material having, of light fastnesses measured according to a light fastness measurement method of JIS L 0843:2006 under conditions of a xenon arc intensity of 110 MJ/m2, a fading by gray scale evaluation of grade 3.5 or higher, the automobile instrument panel surface material having a glass haze of 10.0% or less as measured according to a glass haze evaluation method of ISO 6452:2007 under conditions of a heating temperature of 100° C. and a heating time of 20 hours.
Opening claim text (preview).
The invention claimed is: 1. An automobile instrument panel surface material, comprising: a microfiber having an average single fiber diameter of 0.3 to 7 μm; and polyurethane containing a UV absorber having a vapor pressure of 5.0×10 E-6 Pa or less at 20° C.; and 0.01 to 0.1% by mass of a silicone oil in mass percentage relative to a total mass of the microfiber and the polyurethane, wherein the polyurethane containing the UV absorber is coated with the silicone oil and does not contain the silicone oil, and wherein the automobile instrument panel surface material has 1) a content of the UV absorber of 0.01 to 5% by mass in mass percentage relative to the polyurethane, 2) nap formed of the microfiber, 3) light fastnesses measured according to a light fastness measurement method of JIS L 0843:2006 under conditions of a xenon arc intensity of 110 MJ/m 2 , a fading by gray scale evaluation of grade 3.5 or higher, and 4) a glass haze of 10.0% or less as measured according to a glass haze evaluation method of ISO 6452:2007 under conditions of a heating temperature of 100° C. and a heating time of 20 hours. 2. The automobile instrument panel surface material according to claim 1 , wherein the polyurethane is polycarbonate polyurethane. 3. The automobile instrument panel surface material according to claim 1 , wherein the UV absorber has a vapor pressure of 1.0×10 E-7 Pa or less at 20° C. 4. A method of manufacturing the automobile instrument panel surface material according to claim 1 , the method comprising: adding a UV absorber having a vapor pressure of 1.0×10 E-7 Pa or less at 20° C. to the polyurethane; a polyurethane impregnating and adding step of impregnating and adding, to a fibrous base material containing a microfiber, the polyurethane containing the UV absorber added thereto; and after the polyurethane impregnating and adding step, and adding to the fibrous base material to which the polyurethane is impregnated and added a silicone oil in an amount of 0.01 to 0.1% by mass in mass percentage relative to a total mass of the microfiber and the polyurethane, wherein the automobile instrument panel surface material has a content of the UV absorber of 0.01 to 5% by mass in mass percentage relative to the polyurethane. 5. A method of manufacturing the automobile instrument panel surface material according to claim 2 , the method comprising: adding a UV absorber having a vapor pressure of 1.0×10 E-7 Pa or less at 20° C. to the polyurethane; a polyurethane impregnating and adding step of impregnating and adding, to a fibrous base material containing a microfiber, the polyurethane containing the UV absorber added thereto; and after the polyurethane impregnating and adding step, and adding to the fibrous base material to which the polyurethane is impregnated and added a silicone oil in an amount of 0.01 to 0.1% by mass in mass percentage relative to a total mass of the microfiber and the polyurethane, wherein the automobile instrument panel surface material has a content of the UV absorber of 0.01 to 5% by mass in mass percentage relative to the polyurethane. 6. A method of manufacturing the automobile instrument panel surface material according to claim 4 , the method comprising: adding a UV absorber having a vapor pressure of 1.0×10 E-7 Pa or less at 20° C. to the polyurethane; a polyurethane impregnating and adding step of impregnating and adding, to a fibrous base material containing a microfiber, the polyurethane containing the UV absorber added thereto; and after the polyurethane impregnating and adding step, and adding to the fibrous base material to which the polyurethane is impregnated and added a silicone oil in an amount of 0.01 to 0.1% by mass in mass percentage relative to a total mass of the microfiber and the polyurethane, wherein the automobile instrument panel surface material has a content of the UV absorber of 0.01 to 5% by mass in mass percentage relative to the polyurethane.
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Resistive to light or to UV · CPC title
with two layers of different macromolecular materials (D06N3/08 takes precedence); {(with two layers of the same kind of macromolecular material D06N2213/03)} · CPC title
with polyurethanes · CPC title
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