Preparations of platinum complexes

Patent metadata

Field	Value
Publication number	US-11629410-B2
Application number	US-202017755571-A
Country	US
Kind code	B2
Filing date	Jul 9, 2020
Priority date	Nov 6, 2019
Publication date	Apr 18, 2023
Grant date	Apr 18, 2023

Abstract

Preparation containing:
(A) 30 to 90% by weight of at least one organic solvent; (B) 10 to 70% by weight of at least one platinum complex of the type [L1L2Pt[O(CO)R1]X] n , wherein L1 and L2 represent the same or different monoolefin ligands, or together represent a compound L1L2 acting as a diolefin ligand, wherein X is selected from bromide, chloride, iodide, and —O(CO)R2, wherein —O(CO)R1 and —O(CO)R2 represent the same or different C6-C18 non-aromatic monocarboxylic acid groups, or together represent a C8-C18 non-aromatic dicarboxylic acid group —O(CO)R1 R2(CO)O—, wherein they are mononuclear platinum complexes with n=1, or wherein, if L1L2 and/or —O(CO)R1 R2(CO)O— are present, they may be polynuclear platinum complexes with a whole number n>1, and (C) 0 to 10% by weight of at least one additive.

First claim

The invention claimed is:

1. A preparation consisting of:
(A) 30 to 90% by weight of at least one organic solvent;
(B) 10 to 70% by weight of at least one platinum complex of the type [L1L2Pt[O(CO)R1]X] n ,
wherein L1 and L2 represent the same or different monoolefin ligands, or together represent a compound L1L2 acting as a diolefin ligand,
wherein X is selected from bromide, chloride, iodide, and —O(CO)R2,
wherein —(CO)R1 and —O(CO)R2 represent the same or different C6-C18 or C8-C18 non-aromatic monocarboxylic acid groups, or together represent a C8-C18 non-aromatic dicarboxylic acid group —O(CO)R1R2(CO)O—,
wherein they are mononuclear platinum complexes with n=1, or wherein, if L1L2 and/or —O(CO)R1R2(CO)O— are present, they may be polynuclear platinum complexes with a whole number n>1, and
(C) 0 to 10% by weight of at least one additive.

2. The preparation according to claim 1 , wherein L1L2 represents a compound acting as a diolefin ligand,
wherein X is selected from bromide, chloride, iodide, and —O(CO)R2,
wherein —O(CO)R1 and —O(CO)R2 represent the same or different C6-C18 or C8-C18 non-aromatic monocarboxylic acid groups, and
wherein they are mononuclear platinum complexes with n=1, or polynuclear platinum complexes with a whole number n>1.

3. The preparation according to claim 1 , wherein whole number n>1 is in the range of 2 to 5.

4. The preparation according to claim 1 in the form of a non-colloidal organic solution.

5. The preparation according to claim 1 , having a platinum content originating from the at least one platinum complex in the range of 2.5 to 25% by weight.

6. The preparation according to claim 1 , wherein the at least one platinum complex has the formula [(COD)Pt[O(CO)R1] 2 ] n or [(NBD)Pt[O(CO)R1] 2 ] n , wherein n is 1 or 2, and wherein R1 stands for a C5-C17 or C7-C17 non-aromatic hydrocarbon group.

7. The preparation according to claim 1 , wherein the decomposition temperature of the at least one platinum complex is in the range of 150 to 200 or 150 to 250° C.

8. The preparation according to claim 1 , wherein the at least one additive (C) is selected from the group consisting of wetting additives, rheological additives, defoamers, deaerators, additives for influencing the surface tension and odorants.

9. A method for producing a platinum layer on a substrate, comprising the steps of:
(1) applying a coating layer of a preparation according to claim 1 to a substrate, and
(2) thermally decomposing the coating layer to form a platinum layer.

10. The method according to claim 9 , wherein the substrate comprises one or more materials selected from the group consisting of glass, ceramic, semiconductor substrates, metal, plastic, modified or unmodified polymers of natural origin, carbon substrates, card and paper.

11. The method according to claim 9 , wherein the substrate is provided with the coating layer on inner and/or outer surfaces or on inner and/or outer surface portions.

12. The method according to claim 9 , wherein the application method used to produce the coating layer is selected from the group consisting of dipping, spray application, printing, application by means of paintbrush, application by means of brush, application by means of felt, and application by means of cloth.

13. The method according to claim 9 , wherein the coating layer applied in step (1) is initially dried and in the process partially or completely freed of the organic solvent before it is subjected to thermal decomposition in step (2).

14. The method according to claim 9 , wherein the thermal decomposition according to step (2) takes place by thermal treatment, which comprises heating to an object temperature above the decomposition temperature of the at least one platinum complex.

15. The method according to claim 14 , wherein the heating to the object temperature takes place in a kiln and/or by infrared irradiation.

16. The method according to claim 9 , wherein the platinum layer is 50 nm to 5 μm thick.

Assignees

• Heraeus Deutschland Gmbh & Co Kg

Inventors

• Sievi Robert
• Gock Michael
• Walter Richard
• Ulland Holger

Classifications

• H01B1/02 Primary

  mainly consisting of metals or alloys · CPC title

• C07F15/0086

  Platinum compounds · CPC title

• H01B13/0016

  for heat treatment · CPC title

• C23C18/08 Primary

  characterised by the deposition of metallic material · CPC title

• A61K8/23 Primary

  Sulfur; Selenium; Tellurium; Compounds thereof · CPC title