Waterborne composition

Patent metadata

Field	Value
Publication number	US-11629266-B2
Application number	US-201917274160-A
Country	US
Kind code	B2
Filing date	Oct 1, 2019
Priority date	Oct 10, 2018
Publication date	Apr 18, 2023
Grant date	Apr 18, 2023

Abstract

A composition including: (a) at least one anionically stabilized acrylic polymer dispersion where the acrylic polymer contains acid monomer units; and (b) at least on polyamino siloxane relative to the weight of the total polymers in the composition, wherein the polyaminosiloxane copolymer containing steric stabilizing groups having a pendant group with a secondary or a primary amine functionality; and (ii) at least a portion of the silicon atoms in the polyaminosiloxane copolymer containing steric stabilizing groups having a pendant alkyl-poly(ethylene oxide) chain with 5 ethylene oxide units to 20 ethylene oxide units.

First claim

What is claimed is:

1. A stable waterborne composition comprising:
(a) at least one anionically stabilized acrylic polymer dispersion, wherein the acrylic polymer contains at least a portion of polymerized acid monomer units; and
(b) at least one polyaminosiloxane copolymer-containing steric stabilizing groups, wherein (i) at least a portion of the silicon atoms in the polyaminosiloxane copolymer contain a pendant group with a secondary or a primary amine functionality; and (ii) at least a portion of the silicon atoms in the polyaminosiloxane copolymer-containing steric stabilizing groups have a pendant alkyl-poly(alkylene oxide) chain,
wherein the portion of the polymerized acid monomer units in the acrylic polymer is from 0.1 weight-percent of more to 5.0 weight-percent of less based on the total weight of all monomers in the polymer; wherein the portion of the silicon atoms in the polyaminosiloxane copolymer containing a pendant group with a secondary or a primary amine functionality is from 60 mol % or more to 97 mol % or less based on the total of the polyaminosiloxane copolymer; and wherein the portion of the silicon atoms in the polyaminosiloxane copolymer-containing steric stabilizing groups having a pendant alkyl-poly(alkylene oxide) chain is from 3 mol % or more to 17 mol % or less based on the total of the polyaminosiloxane copolymer.

2. The composition of claim 1 , wherein the alkyl-poly(alkylene oxide) chain is a poly(ethylene oxide) chain.

3. The composition of claim 1 , wherein the concentration of the polyaminosiloxane copolymer-containing steric stabilizing groups is from 0.01 weight percent to 5.0 weight percent based on the total weight of the polymers in the composition.

4. The composition of claim 1 , wherein (i) at least 70 mole-percent of the silicon atoms in the polyaminosiloxane copolymer-containing steric stabilizing groups have a pendant group with a secondary or a primary amine functionality; and (ii) from 5 mole-percent to 20 mole-percent of the silicon atoms in the polyaminosiloxane copolymer-containing steric stabilizing groups have a pendant alkyl-poly(ethoxide) chain with from 5 ethylene oxide units to 20 ethylene oxide units.

5. The composition of claim 1 , wherein the composition has a pH in a range of from 7 to 10.5, as determined by the procedure of ASTM E70.

6. The composition of claim 1 , wherein the composition is a stable mixture, wherein the fineness of said stable mixture does not increase by greater than 5 micrometers, as determined by the procedure of ASTM Test D-1316, relative to the composition without polyaminosiloxane.

7. The composition of claim 1 , wherein the composition contains less than 0.25 weight percent of ammonia based on the total weight of polymer in the composition as determined by headspace gas chromatography.

8. The composition of claim 1 , wherein the acrylic polymer is selected from a group consisting of (meth)acrylic polymers and styrene-acrylic copolymers.

9. The composition of claim 1 , wherein the acrylic polymer comprises a monomer selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, and phosphoric acid 2-hydroxyethyl methacrylate ester.

10. The composition of claim 9 , wherein the monomer is present in the composition at a concentration of from 0.1 weight-percent to 5.0 weight-percent based on total weight of monomer units in the polymer.

11. The composition of claim 1 , wherein the acrylic polymer has a glass transition temperature in a range of from −55 degrees Celsius to 35 degrees Celsius, as determined according to the procedure of ASTM E-1356-08.

12. The composition of claim 1 , wherein the polyaminosiloxane copolymer-containing steric stabilizing groups is the product resulting from a condensation reaction of a mixture comprising the following compounds:
(a) from 0 mole-percent to 97 mole-percent of a compound having the following structure (I):
Si(R 1 )(R 2 ) 2 (CH 2 ) X NH(CH 2 ) Y NH 2   (I);

(b) from 0 mole-percent to 97 mole-percent of a compound having the following structure (II):
Si(R 2 ) 3 (CH 2 ) X NH(CH 2 ) Y NH 2   (II);

(c) from 0 mole-percent to 97 mole-percent of a compound having the following structure (III):
Si(R 1 )(R 2 ) 2 (CH 2 ) X NH 2   (III);

(d) from 0 mole-percent to 97 mole-percent of a compound having the following structure (IV):
Si(R 2 ) 3 (CH 2 ) X NH 2   (IV);

(e) from 3 mole-percent to 17 mole-percent of a compound having the following structure (V):
Si(R 1 ) x (R 2 ) 3-x (CH 2 ) a —O—(CH 2 CH 2 O) b R 3   (V); and

(f) from 0 mole-percent to 20 mole-percent of a compound having the following structure (VI):
Si(R 4 ) y (R 2 ) 4-y   (VI);

wherein in the above structures (I) to (VI), R 1 in each occurrence is independently selected from a group consisting of methyl and phenyl; R 2 in each occurrence is independently selected from a group consisting of hydroxy, methoxy and ethoxy; values for x, y and a are independently selected in each occurrence from a number in a range of from 0 to 2; and b is independently selected from a number in a range of from 5 to 20; and wherein mole-percent values are relative to the total moles of compounds (a)-(f) and the sum of the mole-percent values for compounds (a)-(f) add up to 100 mole-percent; R 3 is hydrogen, methyl, or acetoxy; y is 0 to 3; R 4 is a C1 to C8 alkyl group or phenyl group.

13. The composition of claim 12 , wherein the polyaminosiloxane is the product resulting from a condensation reaction of a mixture comprising the following compounds:
(a) from 0 mole-percent to 95 mole-percent of 3-(2-aminoethylamino)propyldimethoxy-methylsilane;
(b) from 0 mole-percent to 95 mole-percent of 3-(2-aminoethylamino)propyltrimethoxysilane;
(c) from 0 mol percent to 95 mol percent aminopropyldimethoxymethylsilane;
(d) from 0 mole-percent to 95 mole-percent of aminopropyltrimethoxysilane;
(e) from 3 mole-percent to 17 mole-percent of 2-[methoxy(polyethyleneoxy)9-12propyl]tri-methoxysilane; and
(f) from 0 mole-percent to 20 mole-percent of dimethoxydimethylsilane, diethoxydimethylsilane, trimethoxymethylsilane, triethoxymethylsilane;

wherein the mole-percent values are relative to the total moles of compounds (a)-(f) and the sum of the mole-percent values for compounds (a)-(f) add up to 100 mole-percent.

14. A coating, sealant, or masonry finish comprising the composition of claim 1 .

Assignees

• Dow Global Technologies Llc
• Rohm & Haas

Inventors

• Conner David M
• Westmeyer Mark D
• Baumann Robert

Classifications

• C08G77/26

  nitrogen-containing groups · CPC title

• C08F212/08

  Styrene · CPC title

• C09D183/12

  containing polyether sequences · CPC title

• C08J3/03

  in aqueous media · CPC title

• C09D183/08

  containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen · CPC title