Cubic boron nitride sintered material and method of producing same

Patent metadata

Field	Value
Publication number	US-11629101-B2
Application number	US-202017625749-A
Country	US
Kind code	B2
Filing date	Jul 17, 2020
Priority date	Jul 18, 2019
Publication date	Apr 18, 2023
Grant date	Apr 18, 2023

Abstract

A cubic boron nitride sintered material includes: more than or equal to 20 volume % and less than 80 volume % of cubic boron nitride grains; and more than 20 volume % and less than or equal to 80 volume % of a binder phase, and when a carbon content is measured from a cubic boron nitride grain into the binder phase in a direction perpendicular to an interface between the cubic boron nitride grain and the binder phase using TEM-EDX, a first region having a carbon content larger than an average value of a carbon content of the binder phase exists, the interface exists in the first region, and a length of the first region is more than or equal to 0.1 nm and less than or equal to 10 nm.

First claim

The invention claimed is:

1. A cubic boron nitride sintered material comprising: more than or equal to 20 volume % and less than 80 volume % of cubic boron nitride grains; and more than 20 volume % and less than or equal to 80 volume % of a binder phase, wherein
the binder phase includes at least one selected from a group consisting of a compound composed of at least one element selected from a group consisting of a group 4 element, a group 5 element, a group 6 element in a periodic table, and aluminum, and at least one element selected from a group consisting of nitrogen, carbon, boron, and oxygen, and a solid solution originated from the compound, and
when a carbon content is measured from a cubic boron nitride grain into the binder phase in a direction perpendicular to an interface between the cubic boron nitride grain and the binder phase using TEM-EDX, a first region having a carbon content larger than an average value of a carbon content of the binder phase exists, the interface exists in the first region, and a length of the first region is more than or equal to 0.1 nm and less than or equal to 10 nm.

2. The cubic boron nitride sintered material according to claim 1 , wherein a content ratio of the cubic boron nitride grains is more than or equal to 35 volume % and less than 75 volume %.

3. The cubic boron nitride sintered material according to claim 1 , wherein the length of the first region is more than or equal to 0.1 nm and less than or equal to 5 nm.

4. The cubic boron nitride sintered material according to claim 1 , wherein a difference between a maximum value of the carbon content of the first region and the average value of the carbon content of the binder phase is more than or equal to 0.3 atomic % and less than or equal to 5 atomic %.

5. A method of producing the cubic boron nitride sintered material recited in claim 1 , the method comprising:
forming an organic-substance-attached cubic boron nitride powder by attaching an organic substance to a cubic boron nitride powder;
preparing a powder mixture by mixing the organic-substance-attached cubic boron nitride powder and a binder powder; and
obtaining the cubic boron nitride sintered material by sintering the powder mixture, wherein
the powder mixture includes more than or equal to 20 volume % and less than 80 volume % of the organic-substance-attached cubic boron nitride powder and more than 20 volume % and less than or equal to 80 volume % of the binder powder, and
the binder powder includes at least one element selected from a group consisting of a group 4 element, a group 5 element, a group 6 element in a periodic table, and aluminum, and at least one element selected from a group consisting of nitrogen, carbon, boron and oxygen.

6. The method of producing the cubic boron nitride sintered material according to claim 5 , wherein the forming of the organic-substance-attached cubic boron nitride powder includes introducing the cubic boron nitride powder and the organic substance into supercritical water.

7. The method of producing the cubic boron nitride sintered material according to claim 5 , wherein the forming of the organic-substance-attached cubic boron nitride powder includes attaching the organic substance to the cubic boron nitride powder by plasma treatment.

Assignees

• Sumitomo Electric Industries
• Sumitomo Electric Hardmetal Corp

Inventors

• Hama Hisaya
• Okamura Katsumi
• Ishii Akito
• Kukino Satoru

Classifications

• C04B2235/3856

  Carbonitrides, e.g. titanium carbonitride, zirconium carbonitride · CPC title

• C04B2235/3813

  Refractory metal borides · CPC title

• C04B2235/3886

  Refractory metal nitrides, e.g. vanadium nitride, tungsten nitride · CPC title

• C04B2235/75

  Products with a concentration gradient · CPC title

• C04B2235/48

  Organic compounds becoming part of a ceramic after heat treatment, e.g. carbonising phenol resins · CPC title