Apparatus for, and method of, roll forming sheets of high refractive index glass

Patent metadata

Field	Value
Publication number	US-11629087-B2
Application number	US-202117521364-A
Country	US
Kind code	B2
Filing date	Nov 8, 2021
Priority date	Nov 13, 2020
Publication date	Apr 18, 2023
Grant date	Apr 18, 2023

Abstract

A method of forming a glass sheet comprises: (a) forming a ribbon of glass from molten glass with a pair of forming rollers; (b) reducing horizontal temperature variability of the ribbon of glass to be 10° C. or less across 80 percent of an entire width of the ribbon of glass before the ribbon of glass cools to a glass transition temperature; (c) controlling a cooling rate of the ribbon of glass while the ribbon of glass moves vertically downward within a setting zone such that the ribbon of glass has a first average cooling rate before the ribbon of glass cools to the glass transition temperature and a second average cooling rate after the ribbon of glass cools to the glass transition temperature, the first average cooling rate being less than the second average cooling rate; and (d) separating a glass sheet from the ribbon of glass.

First claim

The invention claimed is:

1. A method of forming a glass sheet comprising:
forming a ribbon of glass from molten glass with a pair of forming rollers;
controlling horizontal temperature variability of the ribbon of glass to be 10° C. or less across 80 percent of an entire width of the ribbon of glass before the ribbon of glass cools to a glass transition temperature;
controlling a cooling rate of the ribbon of glass while the ribbon of glass moves vertically downward within a setting zone such that the ribbon of glass has a first average cooling rate before the ribbon of glass cools to the glass transition temperature and a second average cooling rate after the ribbon of glass cools to the glass transition temperature, the first average cooling rate being less than the second average cooling rate; and
separating a glass sheet from the ribbon of glass.

2. The method of claim 1 , further comprising:
extracting heat from one or both of the pair of forming rollers.

3. The method of claim 2 , wherein
extracting heat from one or both of the pair of forming rollers comprises one or more of: (i) transmitting a heat exchanging fluid into the forming roller, the heat exchanging fluid in thermal communication with an outer surface of the forming roller; (ii) spraying a liquid, having a temperature less than a temperature of the outer surface of the forming roller, onto the outer surface; (iii) contacting the forming roller with a liquid cooled metal brush; and (iv) opposing the forming roller with a liquid cooled riding block.

4. The method of claim 1 , further comprising controlling the horizontal temperature variability of the ribbon of glass to be 5° C. or less across 80 percent of the entire width of the ribbon of glass before the ribbon of glass cools to the glass transition temperature.

5. The method of claim 1 , further comprising controlling the horizontal temperature variability of the ribbon of glass to be 10° C. or less across 90 percent of the entire width of the ribbon of glass before the ribbon of glass cools to the glass transition temperature.

6. The method of claim 1 , further comprising controlling the horizontal temperature variability of the ribbon of glass to be 10° C. or less across the entire width of the ribbon of glass before the ribbon of glass cools to the glass transition temperature.

7. The method of claim 1 , further comprising:
before the pair of forming rollers has formed the ribbon of glass from the molten glass, supplying the molten glass to an internal chamber of a feed device comprising a floor below the internal chamber; and
supplying the molten glass from the internal chamber of the feed device, through the floor and into a gap separating the pair of forming rollers.

8. The method of claim 7 , further comprising:
individually controlling thermal output of each of a plurality of heating elements of the feed device in thermal communication with the molten glass within the internal chamber of the feed device.

9. The method of claim 1 , wherein
controlling the horizontal temperature variability of the ribbon of glass before the ribbon of glass cools to the glass transition temperature comprises increasing heat loss of lateral edges of the ribbon of glass relative to a center portion of the ribbon of glass disposed between the lateral edges.

10. The method of claim 9 , wherein
increasing the heat loss of the lateral edges of the ribbon of glass relative to the center portion of the ribbon of glass disposed between the lateral edges comprises blowing cooling gas onto the lateral edges.

11. The method of claim 9 , wherein
the ribbon of glass has a thickness between two primary surfaces that face in generally opposite directions; and
increasing the heat loss of the lateral edges of the ribbon of glass relative to the center portion of the ribbon of glass disposed between the lateral edges comprises reducing the thickness of the ribbon of glass at the lateral edges of the ribbon of glass.

12. The method of claim 11 , wherein
before the thickness of the ribbon of glass at the lateral edges of the ribbon of glass is reduced, the thickness of the ribbon of glass at the lateral edges is at least 0.5 mm greater than the thickness of the ribbon of glass at the center portion of the ribbon of glass, and
after the thickness of the ribbon of glass at the lateral edges of the ribbon of glass is reduced, the thickness of the ribbon of glass at the lateral edges is less than 0.1 mm greater than the thickness of the ribbon of glass at the center portion of the ribbon of glass.

13. The method of claim 9 , wherein
the ribbon of glass has a thickness between two primary surfaces that face in generally opposite directions, and
increasing the heat loss of the lateral edges of the ribbon of glass relative to the center portion of the ribbon of glass disposed between the lateral edges comprises contacting the lateral edges of the ribbon of glass with opposing pinching rollers that extract heat from the lateral edges of the ribbon of glass.

14. The method of claim 1 , wherein
controlling the horizontal temperature variability of the ribbon of glass before the ribbon of glass cools to the glass transition temperature comprises reducing heat loss of a center portion of the ribbon of glass relative to lateral edges of the ribbon of glass, the center portion of the ribbon of glass being disposed between the lateral edges of the ribbon of glass.

15. The method of claim 14 , wherein
reducing the heat loss of the center portion of the ribbon of glass relative to the lateral edges of the ribbon of glass comprises facing a heat loss reduction element at the center portion of each primary surfaces of the ribbon of glass but not the lateral edges of the ribbon of glass.

16. The method of claim 15 , wherein
the heat loss reduction element comprises an insulative substrate.

17. The method of claim 15 , wherein
the heat loss reduction element comprises a heating element.

18. The method of claim 1 , further comprising:
before the pair of forming rollers has formed the ribbon of glass, supplying a stream of molten glass from a feed device into a gap separating the pair of forming rollers, wherein
each roller of the pair of forming rollers has an axis of rotation and the axes of rotation are parallel to each other,
the gap has a minimum distance at a horizontal plane extending through both axes of rotation,
the stream of molten glass exits the feed device vertically above the horizontal plane and forms a puddle of molten glass within the gap between the pair of forming rollers above the horizontal plane,
the puddle of molten glass has a width parallel to the axes of rotation and a height from the horizontal plane, and
controlling the horizontal temperature variability of the ribbon of glass before the ribbon of glass cools to the glass transition temperature comprises increasing the height of the puddle of molten glass from the horizontal plane.

19. The method of claim 18 , wherein
movable dams disposed above the horizontal plane cooperate with the pair of forming rollers to limit the width of the puddle of molten glass, and
increasing the height of the puddle of molten glass from the horizontal plane comprises moving one or both of the movable dams closer to the other of the movable dams.

20. The method of claim 1 , wherein
the ribbon of glass cools at the first average cooling rate while the ribbon of glass cools from 50° C. above the glass transition temperature to the glass transition

Assignees

• Corning Inc

Inventors

• Bressler Douglas Dale
• Deneka David Alan
• Gerrish Michael Charles
• Jennings Douglas Hull
• Kunitake Miki Eugene
• Lock William Edward
• Mudiraj Shyam Prasad
• Partridge Neil Eugene
• Payne Jeremy Nathan
• Proulx Ii Eugene Roland
• Sutton Ryan Christopher
• Tarcza Steven Howard

Classifications

• C03C3/062

  with less than 40% silica by weight · CPC title

• C03B25/02

  in a discontinuous way · CPC title

• C03B17/067 Primary

  combined with thermal conditioning of the sheets · CPC title

• C03C3/095

  containing rare earths · CPC title

• C03C1/00

  Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels · CPC title