Method for producing ultrapure water

Patent metadata

Field	Value
Publication number	US-11629071-B2
Application number	US-201816481545-A
Country	US
Kind code	B2
Filing date	Feb 13, 2018
Priority date	Feb 13, 2017
Publication date	Apr 18, 2023
Grant date	Apr 18, 2023

Abstract

The present invention relates to a method for producing purified water comprising a step (a) of passing water through a first mixed bed ion exchanger comprising beads having a diameter between 0.5 and 0.7 mm and a step (b) of passing water through a second mixed bed ion exchanger comprising beads having a diameter of less than 0.5 mm. The invention further relates to a module comprising the first and second mixed bed ion exchanger and to a water treatment system for producing ultrapure water comprising the first and second mixed bed ion exchanger.

First claim

The invention claimed is:

1. A method for producing purified water comprising a step (a) of passing water through a first mixed bed ion exchanger comprising beads having a diameter between 0.5 and 0.7 mm and a step (b) of passing water through a second mixed bed ion exchanger comprising beads having a diameter of less than 0.5 mm, wherein the ratio of the volume of the first mixed bed ion exchanger to the volume of the second mixed bed ion exchanger is between 10:1 and 1:1, and wherein the water is not passed through any other ion exchanger to produce said purified water.

2. A method according to claim 1 , wherein the purified water is ultrapure water having a resistivity greater than 18 MΩ-cm.

3. A method according to claim 1 , wherein step (a) is performed before step (b).

4. A method according to claim 1 , wherein the first mixed bed ion exchanger comprises media that consists of a mixture of anion exchange beads and cation exchange beads.

5. A method according to claim 1 , wherein the second mixed bed ion exchanger comprises media that consists of a mixture of anion exchange beads and cation exchange beads.

6. A method according to claim 1 , wherein the first mixed bed ion exchanger is based on styrene divinylbenzene co-polymer.

7. A method according to claim 1 , wherein the second mixed bed ion exchanger is based on styrene divinylbenzene co-polymer.

8. A method according to claim 1 , wherein the method comprises a further step (c) of passing water through an activated carbon bed.

9. A method according to claim 1 , wherein the method comprises a further step (d) of treating water by reverse osmosis performed prior to steps (a) and (b), or a further step (e) of treating water by electrodeionization performed prior to steps (a) and (b); or wherein the method comprises a further step (d) of treating water by reverse osmosis and a further step (e) of treating water by electrodeionization, wherein step (d) and step (e) are performed prior to steps (a) and (b).

10. A module comprising a first mixed bed ion exchanger comprising beads having a diameter between 0.5 and 0.7 mm and a second mixed bed ion exchanger comprising beads having a diameter of less than 0.5 mm, wherein the ratio of the volume of the first mixed bed ion exchanger to the volume of the second mixed bed ion exchanger is between 10:1 and 1:1, and wherein the module is devoid of any additional ion exchanger.

11. A module according to claim 10 , wherein the first mixed bed ion exchanger is based on styrene divinylbenzene co-polymer.

12. A module according to claim 10 , wherein the second mixed bed ion exchanger is based on styrene divinylbenzene copolymer.

13. A module according to claim 10 , wherein it further comprises an activated carbon bed.

14. A water treatment system for producing ultrapure water having a resistivity greater than 18 MΩ-cm, comprising a first mixed bed ion exchanger comprising beads having a diameter between 0.5 and 0.7 mm and a second mixed bed ion exchanger comprising beads having a diameter of less than 0.5 mm, wherein the ratio of the volume of the first mixed bed ion exchanger to the volume of the second mixed bed ion exchanger is between 10:1 and 1:1, and wherein the system is devoid of any additional ion exchanger to produce said ultrapure water.

15. A water treatment system according to claim 14 , wherein the first and the second mixed bed ion exchanger are provided in a single module comprising a first mixed bed ion exchanger comprising beads having a diameter between 0.5 and 0.7 mm and a second mixed bed ion exchanger comprising beads having a diameter of less than 0.5 mm.

16. A water treatment system according to claim 14 , wherein the first and the second mixed bed ion exchanger are provided in at least two modules.

17. A water treatment system according to claim 14 , further comprising an activated carbon bed.

18. The module of claim 13 , wherein said activated carbon bed is mixed with said first mixed bed ion exchanger.

Assignees

• Merck Patent Gmbh

Inventors

• Kano Ichiro
• Dima Gabriela
• Ratieuville Yann

Classifications

• C02F1/441

  by reverse osmosis · CPC title

• C02F2001/427

  using mixed beds · CPC title

• C02F1/42 Primary

  by ion-exchange (ion-exchange in general B01J) · CPC title

• C02F1/283

  using coal, charred products, or inorganic mixtures containing them · CPC title

• C02F9/20

  Portable or detachable small-scale multistage treatment devices, e.g. point of use or laboratory water purification systems · CPC title