Selective hydrogenation catalyst and methods of making and using same
US-9221727-B2 · Dec 29, 2015 · US
US11628430B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11628430-B2 |
| Application number | US-201816480082-A |
| Country | US |
| Kind code | B2 |
| Filing date | Feb 21, 2018 |
| Priority date | Feb 27, 2017 |
| Publication date | Apr 18, 2023 |
| Grant date | Apr 18, 2023 |
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There is provided a method for producing a catalyst liquid containing a Group 6 to 11 transition metal catalyst in which the transition metal catalyst can be prevented from being blackened during storage, the method including performing addition of an alkenyl compound and addition of a phosphorus ligand, and then performing addition of a Group 6 to 11 transition metal catalyst
Opening claim text (preview).
The invention claimed is: 1. A method for producing a catalyst liquid, comprising performing addition of an alkenyl compound and a phosphorus ligand to a solvent, then performing addition of a Group 6 to 11 transition metal catalyst, and then stirring at room temperature, wherein the alkenyl compound, the phosphorus ligand, and the Group 6 to 11 transition metal catalyst are added in that order; the alkenyl compound is 2,7-octadien-1-ol; the phosphorus ligand is triethylamine 3-(diphenylphosphino)benzenesulfonate; the Group 6 to 11 transition metal catalyst is palladium acetate; and the solvent is at least one selected from sulfolane and water. 2. The production method according to claim 1 , wherein the catalyst liquid is a catalyst liquid for a telomerization reaction. 3. The production method according to claim 2 , wherein the telomerization reaction is a telomerization reaction using butadiene or isoprene as a raw material.
Aromatic phosphines (P-C aromatic linkage) · CPC title
Palladium · CPC title
Olefin oligomerisation or telomerisation · CPC title
Platinum · CPC title
Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring · CPC title
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