Method and system for cooling a hydrocarbon stream

Patent metadata

Field	Value
Publication number	US-11624555-B2
Application number	US-202016826907-A
Country	US
Kind code	B2
Filing date	Mar 23, 2020
Priority date	Nov 27, 2017
Publication date	Apr 11, 2023
Grant date	Apr 11, 2023

Abstract

A system and method for increasing the efficiency of natural gas liquefaction processes by using a hybrid cooling system and method. More specifically, a system and method for converting a transcritical precooling refrigeration process to a subcritical process. In one embodiment, the refrigerant is cooled to sub-critical temperature using an economizer. In another embodiment, the refrigerant is cooled to a sub-critical temperature using an auxiliary heat exchanger. Optionally, the economizer or auxiliary heat exchanger can be bypassed when ambient temperatures are sufficiently low to cool the refrigerant to a sub-critical temperature. In another embodiment, the refrigerant is isentropically expanded.

First claim

The invention claimed is:

1. A method for cooling a hydrocarbon feed stream against a first refrigerant to produce a cooled hydrocarbon stream, the first refrigerant having a critical temperature, the method comprising:
(a) compressing the first refrigerant in at least one compression stage to produce a compressed first refrigerant;
(b) cooling the compressed first refrigerant against an ambient fluid in at least one heat exchanger to produce a cooled first refrigerant having a first temperature that is greater than or equal to the critical temperature of the first refrigerant;
(c) further cooling the cooled first refrigerant in at least one auxiliary heat exchanger to produce a further cooled first refrigerant at a second temperature that is less than the critical temperature of the first refrigerant; and
(d) cooling a fluid stream in each of at least one cooling circuit located in downstream fluid flow communication from the auxiliary heat exchanger, each of the at least one cooling circuit having at least one evaporation stage, each of the following steps being performed in each evaporation stage:
(i) reducing the pressure of the first refrigerant;
(ii) cooling the fluid stream against the reduced pressure first refrigerant in an evaporator, resulting in vaporization of at least a portion of the reduced pressure first refrigerant; and
(iii) flowing at least a portion of the vaporized reduced pressure first refrigerant into one of the at least one compression stages;

wherein at least one fluid stream being cooled in the at least one cooling circuit comprises the hydrocarbon feed stream and step (d) produces a cooled hydrocarbon stream; and
wherein refrigeration duty for the at least one auxiliary heat exchanger is provided by at least one auxiliary refrigerant, the at least one auxiliary refrigerant being the hydrocarbon feed stream.

2. The method of claim 1 , further comprising:
(e) further cooling and liquefying the cooled hydrocarbon stream in at least one liquefaction heat exchanger against a second refrigerant stream to produce a liquefied natural gas stream.

3. The method of claim 2 , wherein the at least one fluid stream being cooled in the at least one cooling circuit comprises the second refrigerant.

4. The method of claim 1 , wherein the first refrigerant comprises ethane, carbon-dioxide, or ethylene.

5. The method of claim 1 , wherein step (a) further comprises:
(a) compressing the first refrigerant in a plurality of compression stages to produce the compressed first refrigerant.

6. The method of claim 5 , wherein step (d) further comprises cooling at least one fluid stream in a plurality of evaporation stages located downstream from the economizer, wherein the steps (d)(i) through (d)(iii) are performed in each of the plurality of evaporation stages.

7. The method of claim 1 , further comprising:
(e) combining a vapor phase portion of the warmed first refrigerant with the vaporized reduced pressure first refrigerant in one of the at least one evaporation stage before performing step (d)(iii).

8. The method of claim 7 , further comprising:
(f) separating the warmed first refrigerant into the vapor phase portion and a liquid phase portion and performing step (d) using the liquid phase portion.

Assignees

• Air Prod & Chem

Inventors

• Krishnamurthy Gowri
• Roberts Mark Julian

Classifications

• F25J2210/06

  Splitting of the feed stream, e.g. for treating or cooling in different ways · CPC title

• F25J2270/60

  Closed external refrigeration cycle with single component refrigerant [SCR], e.g. C1-, C2- or C3-hydrocarbons · CPC title

• F25B41/39

  Dispositions with two or more expansion means arranged in series, i.e. multi-stage expansion, on a refrigerant line leading to the same evaporator · CPC title

• F25J1/0095

  Oxides of carbon, e.g. CO2 · CPC title

• F25B1/10

  with multi-stage compression (with cascade operation F25B7/00) · CPC title