Coatings for materials

Patent metadata

Field	Value
Publication number	US-11624151-B2
Application number	US-201816494957-A
Country	US
Kind code	B2
Filing date	Mar 21, 2018
Priority date	Mar 28, 2017
Publication date	Apr 11, 2023
Grant date	Apr 11, 2023

Abstract

A textile includes a substrate and a coating applied to a surface of the substrate. The coating includes a plurality of bilayers positioned one on top of the other. Each bilayer includes a first layer including a cationic polymer and a second layer comprising an anionic polymer. The cationic polymer in the first layer includes a polyethyleneimine (PEI), a poly(vinyl amine) (PVAm), a poly(allyl amine) (PAAm), a polydiallyldimethylammonium chloride (PDDA), or a chitosan (CH). The anionic polymer in the second layer includes a poly(acrylic acid) (PAA), a poly(styrene sulfonate) (PSS), a poly(methacrylic acid) (PMAA), a poly(sodium phosphate) (PSP), or a poly(vinyl sulfate) (PVS).

First claim

What is claimed is:

1. A textile, comprising:
a substrate;
a coating applied to a surface of the substrate, wherein the coating is effective to reduce or prevent adhesion of bacteria to the substrate without actively killing the bacteria, wherein the coating comprises:
a plurality of bilayers positioned one on top of the other, wherein each bilayer includes a first layer comprising a cationic polymer and a second layer comprising an anionic polymer;
wherein the cationic polymer in the first layer comprises a poly(vinyl amine) (PVAm), a poly(allyl amine) (PAAm), or a polydiallyldimethylammonium chloride (PDDA), and wherein the anionic polymer in the second layer comprises a poly(acrylic acid) (PAA), a poly(styrene sulfonate) (PSS), a poly(methacrylic acid) (PMAA), a poly(sodium phosphate) (PSP), or a poly(vinyl sulfate) (PVS); or
wherein the cationic polymer in the first layer comprises a polyethyleneimine (PEI), a poly(vinyl amine) (PVAm), a poly(allyl amine) (PAAm), a polydiallyldimethylammonium chloride (PDDA), or a chitosan (CH), and wherein the anionic polymer in the second layer comprises a poly(acrylic acid) (PAA), a poly(methacrylic acid) (PMAA), a poly(sodium phosphate) (PSP), or a poly(vinyl sulfate) (PVS);
wherein the first layer of each bilayer has a concentration of the cationic polymer, and wherein the concentration of the cationic polymer increases in each successive first layer of the plurality of bilayers moving from an inner surface of the coating adjacent the substrate to an outer surface of the coating distal the substrate.

2. The textile of claim 1 , wherein the cationic polymer in the first layer comprises a polydiallyldimethylammonium chloride (PDDA), and wherein the anionic polymer in the second layer comprises a poly(acrylic acid) (PAA).

3. The textile of claim 1 , wherein the cationic polymer in the first layer of each bilayer comprises CH.

4. The textile of claim 1 , wherein the cationic polymer in the first layer of one bilayer is different than the cationic polymer in the first layer of another bilayer.

5. The textile of claim 1 , wherein the plurality of bilayers comprises at least four bilayers or at least ten bilayers.

6. The textile of claim 1 , wherein the substrate has a first surface and the coating is applied to the first surface;
wherein the coating has a thickness Tc measured between an innermost surface of the coating adjacent the first surface of the substrate and an outermost surface of the coating distal the substrate, wherein the thickness Tc is less than 1.0 micron; and
wherein each bilayer has a thickness Tb from 1 nm to 100 nm.

7. The textile of claim 1 , wherein the substrate has a weight Ws and the coating has a weight Wc, wherein the weight Wc divided by the weight Ws is less than 0.05.

8. The textile of claim 1 , wherein the substrate comprises polyester.

9. The textile of claim 1 , wherein the surface of the substrate has an average surface roughness greater than or equal to 1.0 microns.

10. The textile of claim 1 , wherein the coating reduces the adhesion of S. aureus or P. aeruginosa bacteria by at least 95 percent or by at least 99 percent, as characterized by the Bacterial Adhesion Testing.

11. Clothing or linen comprising the textile of claim 1 .

12. The textile of claim 3 , wherein the cationic polymer in the first layer of each bilayer consists essentially of CH.

Assignees

• Texas A & M Univ Sys

Inventors

• Grunlan Jaime Christopher
• Smith Ryan J

Classifications

• A01N33/04

  Nitrogen directly attached to aliphatic or cycloaliphatic carbon atoms · CPC title

• D06M16/00 Primary

  Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic · CPC title

• D06M15/263

  of unsaturated carboxylic acids; Salts or esters thereof · CPC title

• D06M15/03

  Polysaccharides or derivatives thereof · CPC title

• D06M23/005

  Applying monomolecular films on textile products like fibres, threads or fabrics · CPC title