Sub-critical gas-assisted processing of a polymer blend

Patent metadata

Field	Value
Publication number	US-11623381-B2
Application number	US-201815960969-A
Country	US
Kind code	B2
Filing date	Apr 24, 2018
Priority date	Apr 24, 2018
Publication date	Apr 11, 2023
Grant date	Apr 11, 2023

Abstract

A method of processing of a polymer blend is provided. The method includes the step of introducing a polymer material and a secondary polymer material into a barrel of an extruder. A user-selected gas having a supercritical point is injected into the barrel. The user-selected gas is below the supercritical point thereof. The polymer material, the secondary polymer material and the user-selected gas are mixed within the barrel to form a polymer blend. The polymer blend is ejected from the barrel into a mold, pelletizer or the like.

First claim

We claim:

1. A method of processing of a polymer blend, comprising the steps of:
introducing a polymer material into a barrel of an extruder;
melting the polymer material in the barrel;
introducing a secondary polymer material into the melted polymer material in the barrel of the extruder;
mixing the secondary polymer material into the melted polymer material to form a stream of polymer blended material within the barrel;
injecting a user-selected gas having a supercritical point into the stream of polymer blended material in the barrel, the user-selected gas being below the supercritical point thereof;
mixing the user-selected gas into the stream of polymer blended material within the barrel to form a polymer blend;
exposing the user-selected gas and the stream of polymer blended material to multiple low pressure zones and multiple high pressure zones within the barrel as the user-selected gas is mixed into the stream of polymer blended material within the barrel, wherein at least one of the multiple low pressure zones is downstream of at least one of the multiple high pressure zones; and
ejecting the polymer blend from the barrel.

2. The method of claim 1 wherein the extruder includes:
a first hopper communicating with the barrel and being adapted for receiving the polymer material therein; and
a second hopper communicating with the barrel downstream of the first hopper and adapted for receiving the secondary polymer material therein.

3. The method of claim 1 wherein the polymer blend is ejected from the barrel into a mold.

4. The method of claim 1 wherein the polymer blend is ejected from the barrel into a pelletizer.

5. A method of processing of a polymer blend, comprising the steps of:
introducing a polymer material into the barrel of an extruder;
melting the polymer material in the barrel;
introducing a secondary polymer material into the melted polymer material in the barrel of the extruder;
mixing the secondary polymer material into the melted polymer material to form a stream of polymer blended material within the barrel;
injecting a user-selected gas having a supercritical point into the stream of polymer blended material within the barrel downstream of the introduction of the polymer material and the secondary polymer material into the barrel, the user-selected gas being below the supercritical point thereof;
mixing the user-selected gas and the stream of polymer blended material within the barrel to form a polymer blend;
exposing the polymer blend to multiple low pressure zones and to multiple high pressure zones as the polymer blend is mixed within the barrel; and
ejecting the polymer blend from the barrel;

wherein at least one of the multiple low pressure zones is downstream of at least one of the multiple high pressure zones.

6. The method of claim 5 wherein the user-selected gas forms bubbles in the polymer blend when the polymer blend is exposed to each of the low pressure zones.

7. The method of claim 6 wherein the bubbles in the polymer blend are compressed when the polymer blend is exposed to each of the high pressure zones.

8. The method of claim 5 wherein the extruder includes:
a first hopper communicating with the barrel and being adapted for receiving the polymer material therein; and
a second hopper communicating with the barrel downstream of the first hopper and being adapted for receiving the secondary polymer material therein.

9. The method of claim 5 wherein the polymer blend is ejected from the barrel into a mold.

10. The method of claim 5 wherein the polymer blend is ejected from the barrel into a pelletizer.

11. A method of processing of a polymer blend, comprising the steps of:
introducing a polymer material into a barrel of an extruder;
melting the polymer material in the barrel;
mixing a secondary polymer material into the melted polymer material to form a stream of polymer blended material within the barrel;
injecting a user-selected gas having a supercritical point into the stream of polymer blended material within the barrel, the user-selected gas being below the supercritical point thereof;
mixing the stream of polymer blended material and the user-selected gas within the barrel to form a polymer blend;
passing the polymer blend through multiple low pressure zones and to multiple high pressure zones within the barrel as the stream of polymer blended material and the user-selected gas are being mixed in the barrel, such that the user-selected gas forms bubbles in the polymer blend when the polymer blend passes through the low pressure zone and the bubbles in the polymer blend are compressed when the polymer blend passes through the high pressure zone; and
ejecting the polymer blend from the barrel;

wherein at least one of the multiple low pressure zones is downstream of at least one of the multiple high pressure zones.

12. The method of claim 11 wherein the extruder includes:
a first hopper communicating with the barrel and being adapted for receiving the polymer material therein; and
a second hopper communicating with the barrel downstream of the first hopper and being adapted for receiving the secondary polymer material therein.

13. The method of claim 11 wherein the polymer blend is ejected from the barrel into a mold.

14. The method of claim 11 wherein the polymer blend is ejected from the barrel into a pelletizer.

Assignees

• Wisconsin Alumni Res Found

Inventors

• Turng Lih-Sheng
• Ellingham Jr Thomas K

Classifications

• C08L23/12

  Polypropene · CPC title

• B29C48/05

  Filamentary, e.g. strands · CPC title

• B29C48/04

  Particle-shaped (making granules B29B9/00) · CPC title

• B29K2105/04

  cellular or porous · CPC title

• C08L67/04

  Polyesters derived from hydroxycarboxylic acids, e.g. lactones (C08L67/06 takes precedence) · CPC title