Energy storage for combustion turbine using molten carbonate electrolyzer cell

Patent metadata

Field	Value
Publication number	US-11619167-B2
Application number	US-202217582893-A
Country	US
Kind code	B2
Filing date	Jan 24, 2022
Priority date	Feb 18, 2019
Publication date	Apr 4, 2023
Grant date	Apr 4, 2023

Abstract

An energy storage system includes: a reformer configured to receive natural gas and steam and to output reformed natural gas; a combustion turbine configured to output heated sweep gas; and a molten carbonate electrolyzer cell (“MCEC”) including: an MCEC anode, and an MCEC cathode configured to receive the heated sweep gas from the combustion turbine. The energy storage system is configured such that: when no excess power is available, the combustion turbine receives the reformed natural gas from the reformer, and when excess power is available, the MCEC operates in a hydrogen-generation mode in which the MCEC anode receives the reformed natural gas from the reformer, and outputs MCEC anode exhaust that contains hydrogen.

First claim

What is claimed is:

1. An energy storage system comprising:
a reformer configured to receive natural gas and steam and to output reformed natural gas;
a combustion turbine configured to output heated sweep gas; and
a molten carbonate electrolyzer cell (“MCEC”) comprising:
an MCEC anode, and
an MCEC cathode configured to receive the heated sweep gas from the combustion turbine, wherein:

the energy storage system is configured such that:
when no excess power is available, the combustion turbine receives the reformed natural gas from the reformer, and
when excess power is available, the MCEC operates in a hydrogen-generation mode in which the MCEC anode receives the reformed natural gas from the reformer, and outputs MCEC anode exhaust that contains hydrogen.

2. The energy storage system of claim 1 , further comprising:
an electrochemical hydrogen compressor (“EHC”) comprising:
an EHC anode configured to receive the MCEC anode exhaust, and
an EHC cathode configured to output a purified hydrogen-containing stream.

3. The energy storage system of claim 2 , further comprising:
a storage tank configured to receive the purified hydrogen-containing stream.

4. The energy storage system of claim 2 ,
a proton exchange membrane (PEM) fuel cell configured to receive the purified hydrogen-containing stream from the EHC cathode and to output electricity.

5. The energy storage system of claim 2 , wherein the EHC anode is configured to output an EHC anode exhaust that contains excess fuel.

6. The energy storage system of claim 5 , further comprising:
a burner configured to receive the heated sweep gas from the combustion turbine, and to further heat the heated sweep gas using heat from the EHC anode exhaust before the heated sweep gas is received by the MCEC cathode.

7. The energy storage system of claim 2 , further comprising:
a methanation catalyst configured to receive the MCEC anode exhaust and to convert carbon monoxide in the MCEC anode exhaust into methane.

8. The energy storage system of claim 1 , further comprising:
a proton exchange membrane (PEM) fuel cell configured to receive the MCEC anode exhaust from the MCEC and to output electricity.

9. The energy storage system of claim 1 , wherein the energy storage system is configured such that, when no excess power is available, the MCEC operates in a power-generation mode in which the MCEC operates in reverse relative to the hydrogen-generation mode.

10. The energy storage system of claim 1 , further comprising:
a heat recovery steam generator configured to generate the steam and supply the steam to the reformer.

11. An energy storage method utilizing a molten carbonate electrolyzer cell (“MCEC”) comprising an MCEC anode and an MCEC cathode, the method comprising:
receiving natural gas and steam at a reformer and outputting reformed natural gas from the reformer;
outputting heated sweep gas from a combustion turbine;
receiving the heated sweep gas from the combustion turbine at the MCEC cathode;
when no excess power is available, receiving the reformed natural gas from the reformer at the combustion turbine; and
when excess power is available, operating in a hydrogen-generation mode, receiving the reformed natural gas from the reformer at the MCEC anode, and outputting MCEC anode exhaust that contains hydrogen from the MCEC anode.

12. The energy storage method of claim 11 , further comprising an electrochemical hydrogen compressor (“EHC”), the method comprising:
receiving the MCEC anode exhaust at an EHC anode; and
outputting a purified hydrogen-containing stream from an EHC cathode.

13. The energy storage method of claim 12 , comprising:
receiving the purified hydrogen-containing stream at a storage tank.

14. The energy storage method of claim 12 , comprising:
receiving the purified hydrogen-containing stream from the EHC cathode at a proton exchange membrane (PEM) fuel cell; and
outputting electricity.

15. The energy storage method of claim 12 , comprising:
outputting an EHC anode exhaust that contains excess fuel from the EHC anode.

16. The energy storage method of claim 15 , comprising:
receiving the heated sweep gas from the combustion turbine at a burner; and
further heating the heated sweep gas using heat from the EHC anode exhaust before the heated sweep gas is received by the MCEC cathode.

17. The energy storage method of claim 12 , comprising:
receiving the MCEC anode exhaust at a methanation catalyst; and
converting carbon monoxide in the MCEC anode exhaust into methane.

18. The energy storage method of claim 11 , comprising:
receiving the MCEC anode exhaust from the MCEC at a proton exchange membrane (PEM) fuel cell; and
outputting electricity.

19. The energy storage method of claim 11 , comprising:
when no excess power is available, operating in a power-generation mode in which the MCEC operates in reverse relative to the hydrogen-generation mode.

20. The energy storage method of claim 11 , comprising:
generating the steam at a heat recovery steam generator; and
supplying the steam to the reformer.

Assignees

• Fuelcell Energy Inc

Inventors

• Jahnke Fred C

Classifications

• C01B2203/0205

  containing a reforming step · CPC title

• F02C6/18

  using the waste heat of gas-turbine plants outside the plants themselves, e.g. gas-turbine power heat plants (using waste heat as source of energy for refrigeration plants F25B27/02; using the waste heat of a gasturbine for steam generation or in a steam cycle see F01K23/10) · CPC title

• H01M8/14

  Fuel cells with fused electrolytes · CPC title

• H01M8/0668

  Removal of carbon monoxide or carbon dioxide · CPC title

• H01M8/0612

  from carbon-containing material · CPC title