Method for treating lithium ion battery waste

Patent metadata

Field	Value
Publication number	US-11618959-B2
Application number	US-201816765225-A
Country	US
Kind code	B2
Filing date	Oct 22, 2018
Priority date	Nov 24, 2017
Publication date	Apr 4, 2023
Grant date	Apr 4, 2023

Abstract

Provided is a treatment method whereby it becomes possible to recovery copper, nickel and cobalt, which are valuable metals, contained in a lithium ion battery waste and to separate copper, nickel and cobalt from one another effectively. A method for treating a lithium ion battery waste according to the present invention includes: an alloy production step S1 of introducing the lithium ion battery waste into a furnace and then melting the lithium ion battery waste by heating, thereby producing an alloy containing copper, nickel and cobalt; and an electrolytic purification step S2 of subjecting the alloy to such an electrolytic treatment that the alloy is charged as an anode into a sulfuric acid solution and then electricity is conducted between the anode and a cathode to electrodeposit copper contained in the alloy onto the cathode, thereby separating nickel and cobalt from each other.

First claim

The invention claimed is:

1. A method for treating a lithium ion battery waste, the method comprising:
an alloy production step of introducing the lithium ion battery waste into a furnace and then melting the lithium ion battery waste by heating, thereby producing an alloy containing copper, nickel and cobalt; and
an electrolytic purification step of subjecting the alloy to such an electrolytic treatment that the alloy is charged as an anode into a sulfuric acid solution and then electricity is conducted between the anode and a cathode to electrodeposit copper contained in the alloy onto the cathode, thereby separating copper from nickel and cobalt,
wherein in the electrolytic purification step, the electrolytic treatment is performed while a pH of an electrolyte solution is controlled to be 0 or more and 1.2 or less and a current density (Dk) of the cathode is controlled to be equal to or less than a current density calculated by the following Equation 1:
Dk (A/m 2 )=−2062×pH+3002  (Equation 1).

2. The method for treating a lithium ion battery waste according to claim 1 , wherein in the electrolytic purification step, a current density of the anode is set in a range of 3 A/m 2 or more and 3000 A/m 2 or less.

3. The method for treating a lithium ion battery waste according to claim 2 , wherein in the electrolytic purification step, the electrolytic treatment is performed while a copper concentration in the sulfuric acid solution that is the electrolyte solution is maintained in a range of 5 g/L or more and 50 g/L or less.

4. The method for treating a lithium ion battery waste according to claim 3 , wherein the alloy contains phosphorus in a range of 0.5 wt % or more and 2.0 wt % or less, and
the alloy is used as an anode in the electrolytic purification.

5. The method for treating a lithium ion battery waste according to claim 3 , further comprising an electrowinning step of supplying the electrolyte solution obtained after the electrolytic treatment in the electrolytic purification step to an electrolysis tank and electrodepositing copper remaining in the electrolyte solution by using an insoluble anode.

6. The method for treating a lithium ion battery waste according to claim 2 , wherein the alloy contains phosphorus in a range of 0.5 wt % or more and 2.0 wt % or less, and
the alloy is used as an anode in the electrolytic purification.

7. The method for treating a lithium ion battery waste according to claim 6 , further comprising an electrowinning step of supplying the electrolyte solution obtained after the electrolytic treatment in the electrolytic purification step to an electrolysis tank and electrodepositing copper remaining in the electrolyte solution by using an insoluble anode.

8. The method for treating a lithium ion battery waste according to claim 2 , further comprising an electrowinning step of supplying the electrolyte solution obtained after the electrolytic treatment in the electrolytic purification step to an electrolysis tank and electrodepositing copper remaining in the electrolyte solution by using an insoluble anode.

9. The method for treating a lithium ion battery waste according to claim 8 , wherein the electrolyte solution obtained through the electrowinning step and discharged from the electrolysis tank is repeatedly supplied as the electrolyte solution to be used in the electrolytic purification step.

10. The method for treating a lithium ion battery waste according to claim 1 , wherein in the electrolytic purification step, the electrolytic treatment is performed while a copper concentration in the sulfuric acid solution that is the electrolyte solution is maintained in a range of 5 g/L or more and 50 g/L or less.

11. The method for treating a lithium ion battery waste according to claim 10 , wherein the alloy contains phosphorus in a range of 0.5 wt % or more and 2.0 wt % or less, and
the alloy is used as an anode in the electrolytic purification.

12. The method for treating a lithium ion battery waste according to claim 10 , further comprising an electrowinning step of supplying the electrolyte solution obtained after the electrolytic treatment in the electrolytic purification step to an electrolysis tank and electrodepositing copper remaining in the electrolyte solution by using an insoluble anode.

13. The method for treating a lithium ion battery waste according to claim 12 , wherein the electrolyte solution obtained through the electrowinning step and discharged from the electrolysis tank is repeatedly supplied as the electrolyte solution to be used in the electrolytic purification step.

14. The method for treating a lithium ion battery waste according to claim 1 , wherein the alloy contains phosphorus in a range of 0.5 wt % or more and 2.0 wt % or less, and
the alloy is used as an anode in the electrolytic purification.

15. The method for treating a lithium ion battery waste according to claim 14 , further comprising an electrowinning step of supplying the electrolyte solution obtained after the electrolytic treatment in the electrolytic purification step to an electrolysis tank and electrodepositing copper remaining in the electrolyte solution by using an insoluble anode.

16. The method for treating a lithium ion battery waste according to claim 15 , wherein the electrolyte solution obtained through the electrowinning step and discharged from the electrolysis tank is repeatedly supplied as the electrolyte solution to be used in the electrolytic purification step.

17. The method for treating a lithium ion battery waste according to claim 1 , further comprising an electrowinning step of supplying the electrolyte solution obtained after the electrolytic treatment in the electrolytic purification step to an electrolysis tank and electrodepositing copper remaining in the electrolyte solution by using an insoluble anode.

18. The method for treating a lithium ion battery waste according to claim 17 , wherein the electrolyte solution obtained through the electrowinning step and discharged from the electrolysis tank is repeatedly supplied as the electrolyte solution to be used in the electrolytic purification step.

19. The method for treating a lithium ion battery waste according to claim 1 , further comprising an impurity removing step of removing an impurity component by recovering at least a part of an electrolyte solution obtained after the electrolytic treatment in the electrolytic purification step and adding an oxidizing agent and a neutralizing agent to the electrolyte solution to adjust an oxidation-reduction potential (reference electrode: silver/silver chloride electrode) to 570 mV or more and to adjust a pH in a range of 3 or more and 5 or less,
wherein after the impurity removing step, sulfuric acid is added to a filtrate obtained by solid-liquid separation to adjust the pH to 1.5 or less, and the pH-adjusted filtrate is repeatedly supplied as the electrolyte solution to be used in the electrolytic purification step.

20. The method for treating a lithium ion battery waste according to claim 1 , further comprising an impurity removing step of removing an impurity component by recovering at least a part of an electrolyte solution obtained after the electrolytic treatment in the electrolytic purification step, adding an oxidizing agent to the electrolyte solution at a stage in which a pH of the electrolyte solution is 1.5 or less to adjust an oxidation-reduction potential (reference electrode: silver/silver chloride electrode) to 570 mV or more, and then further adding an ox

Assignees

• Sumitomo Metal Mining Co

Inventors

• Takenouchi Hiroshi
• Asano Satoshi
• Tan Toshirou
• Kobayashi Hiroshi
• Takeda Kenji

Classifications

• Y02W30/84

  Recycling of batteries or fuel cells · CPC title

• Y02P10/20

  Recycling · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• C22B23/00

  Obtaining nickel or cobalt · CPC title

• C22B15/00

  Obtaining copper · CPC title