Method for coating steel sheets or steel strips and method for producing press-hardened components therefrom

Patent metadata

Field	Value
Publication number	US-11613791-B2
Application number	US-201816487004-A
Country	US
Kind code	B2
Filing date	Feb 14, 2018
Priority date	Feb 21, 2017
Publication date	Mar 28, 2023
Grant date	Mar 28, 2023

Abstract

The invention relates to a method for coating a steel sheet or steel strip to which an aluminium-based coating is applied in a dip-coating process and the surface of the coating is freed of a naturally occurring aluminium oxide layer. In order to provide a low-cost method for coating steel sheets or steel strips that makes the steel sheets or steel strips outstandingly suitable for the production of components by means of press hardening and for the further processing thereof, it is proposed that transition metals or transition metal compounds are subsequently deposited on the freed surface of the coating to form a top layer. The invention also relates to a method for producing press-hardened components from the aforementioned steel sheets or steel strips with an aluminium-based coating.

First claim

The invention claimed is:

1. A method for coating a steel sheet or steel strip, comprising:
applying an aluminium-based coat on the steel sheet or steel strip in a hot-dipping process;
freeing a surface of the aluminium-based coat of a naturally occurring aluminium oxide layer;
depositing transition metals or transition metal compounds, at least one of which includes the chemical element iron, on the freed surface of the coat to thereby form a top layer as a planar deposit with a layer weight, based on said iron, in a range of 7 to 25 mg/m 2 .

2. The method of claim 1 , wherein the layer weight, based on said iron, is 10 to 15 mg/m 2 .

3. The method of claim 1 , wherein the transition metals or transition metal compounds comprise beside the chemical element iron at least one further chemical element selected from the group consisting of titanium, vanadium, chromium, and manganese.

4. The method of claim 1 , wherein the chemical element iron is present in a predominant part of the transition metals or the transition metal compounds.

5. The method of claim 1 , wherein the transition metals or the transition metal compounds are deposited in the presence of at least one further chemical element selected from the group consisting of cobalt, molybdenum, tungsten, and compounds thereof.

6. The method of claim 1 , wherein the transition metals or the transition metal compounds are deposited by chemical deposition.

7. The method of claim 6 , wherein the chemical deposition includes spraying, dipping or rolling application.

8. The method of claim 6 , further comprising removing atmospherically occurring, natural oxide layer and the chemical deposition in a single process step.

9. The method of claim 8 , wherein the removal of the atmospherically occurring, natural oxide layer and the chemical deposition are performed in a continuously operating coating installation which is located downstream of a hot-dip coating installation or is separate from the hot-dip coating installation.

10. The method of claim 1 , wherein the transition metals or the transition metal compounds are deposited electrolytically.

11. The method of claim 10 , wherein the transition metals or transition metal compounds are applied electrolytically in an aqueous medium as an electrolyte at an electrolyte temperature of 25° C. to 85° C., at current densities between 0.05 and 150 A/dm 2 .

12. The method of clairn 22 , wherein an aluminium oxide layer with mixed oxides from the top layer is formed on the coat with the top layer when exposed to an oxygen atmosphere or when exposed to steam.

13. The method of claim 12 , wherein the aluminium oxide layer is formed with the mixed oxides in a furnace at a temperature >750° C. and a furnace dwell time >90 s.

14. The method of claim 12 , wherein self-limitation of a layer growth of the aluminium oxide is avoided by formation of the mixed oxides.

15. The method of claim 12 , wherein corundum, eskdaite, haematite, karelianite, tistarite, ilmenite, perowskite and/or spinets are formed as the mixed oxides.

16. The method of claim 1 , wherein the aluminium-based coat includes aluminium, aluminium-silicon (AS) or aluminium-zinc-silicon (AZ) with optional incorporation of an additional element selected from the group consisting of. magnesium, manganese, titanium, and rare earth.

17. A method for producing a press-hardened component from a steel sheet or steel strip, comprising:
applying an aluminium-based coat on the steel sheet or steel strip in a hot-dipping process, with a surface of the aluminium-based coat being freed of a naturally occurring aluminium oxide layer and transition metals or transition metal compounds, least one of which includes the chemical element iron, being deposited on the freed surface of the coat in order to form a top layer as a planar deposit with a layer weight, based on said iron, in a range of 7 to 25 mg/m 2 ;
heating at least a region of the steel sheet or steel strip to a temperature above Ac3;
forming the steel sheet or steel strip at saki temperature;
cooling the steel sheet or steel strip such as to harden at least a region of the steel sheet or steel strip at a rate which is above a critical cooling rate.

18. The method of claim 17 , wherein the steel sheet or steel strip is made of a steel which is hardenable by heat treatment.

19. The method of claim 18 , wherein the steel is alloyed with manganese and boron.

20. The method of claim 19 , wherein the steel is a 22MnB5 steel.

Assignees

• Salzgitter Flachstahl Gmbh

Inventors

• Beier Frank
• Körner Kerstin
• Debeaux Marc

Classifications

• C21D9/46 Primary

  for sheet metals · CPC title

• C23C2/12 Primary

  Aluminium or alloys based thereon · CPC title

• C23C28/00

  Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D · CPC title

• C22C38/04

  containing manganese · CPC title

• C21D1/06 Primary

  Surface hardening · CPC title