Method of producing organic pigment composition, method of producing coating film, and method of evaluating luminance of coating film

Patent metadata

Field	Value
Publication number	US-11613693-B2
Application number	US-201716339966-A
Country	US
Kind code	B2
Filing date	Oct 10, 2017
Priority date	Oct 7, 2016
Publication date	Mar 28, 2023
Grant date	Mar 28, 2023

Abstract

A method of producing an organic pigment composition including at least organic pigment microparticles, wherein a diffuse reflectance of the organic pigment microparticles is controlled for the purpose of improving a luminance of a color filter. The luminance of the color filter is controlled to be high, by controlling a ratio of an area of the diffuse reflectance in a target wavelength range to a total area of the diffuse reflectance in the entire measurement wavelength range in a diffuse reflection spectrum of the organic pigment microparticles in the wavelength range of 380 to 780 nm, to be high. The luminance of the color filter is controlled to be high, by coating at least a part of the surface of the organic pigment microparticles with an oxide.

First claim

The invention claimed is:

1. Organic pigment microparticles for a color filter, comprising: the organic pigment microparticles selected from the group consisting of the following (a), (b), and (c):
(a) the organic pigment microparticles are microparticles of C. I. Pigment Red 254,
a ratio of an area of a diffuse reflectance in a target wavelength range to a total area of a diffuse reflectance in the entire measurement wavelength range is 71% or more, in a diffuse reflection spectrum of the organic pigment microparticles in the wavelength range of 380 to 780 nm, and the target wavelength range is 620 to 750 nm;
(b) the organic pigment microparticles are microparticles of copper phthalocyanine,
a ratio of an area of a diffuse reflectance in a target wavelength range to a total area of a diffuse reflectance in the entire measurement wavelength range is 30% or more, in a diffuse reflection spectrum of the organic pigment microparticles in the wavelength range of 380 to 780 nm, and the target wavelength range is 450 to 495 nm; and
(c) the organic pigment microparticles are microparticles of brominated chlorinated zinc phthalocyanine,
a ratio of an area of a diffuse reflectance in a target wavelength range to a total area of a diffuse reflectance in the entire measurement wavelength range is 51% or more, in a diffuse reflection spectrum of the organic pigment microparticles in the wavelength range of 380 to 780 nm, and the target wavelength range is 495 to 570 nm;
wherein at least a part of the surface of the organic pigment microparticles is coated with silicon oxide,
the particle diameter of the oxide coated organic pigment microparticles is 100.5% or more and 190% or less relative to the primary particle diameter of the organic pigment microparticles,
a primary particle diameter of the organic pigment microparticles is 100 nm or less, and the organic pigment microparticles are in a substantially spherical shape, and
wherein the diffuse reflectance of the organic pigment microparticles is controlled for the purpose of improving a luminance of a color filter.

2. The organic pigment microparticles for a color filter according to claim 1 , wherein the silicon oxide contains an amorphous silicon oxide.

3. A color filter comprising the organic pigment microparticles for a color filter according to claim 1 .

4. A color filter comprising the organic pigment microparticles for a color filter according to claim 1 and organic pigment microparticles having a color different from the color of the organic pigment microparticles.

5. The color filter according to claim 3 , wherein the color filter has both high diffuse reflectance and high luminance, compared with a color filter obtained using bead milled organic pigment microparticles.

6. A method of producing the organic pigment composition according to claim 1 , comprising: coating at least a part of the surface of the organic pigment microparticles with silicon oxide.

7. The method of producing an organic pigment composition according to claim 6 , wherein the luminance of the color filter is controlled to be high, by controlling a ratio of an area of the diffuse reflectance in a target wavelength range to an total area of the diffuse reflectance in the entire measurement wavelength range in a diffuse reflection spectrum of the organic pigment microparticles in the wavelength range of 380 to 780 nm, to be high.

8. The method of producing an organic pigment composition according to claim 7 , wherein the diffuse reflection spectrum is measured using powders of the organic pigment microparticles.

9. The method of producing an organic pigment composition according to claim 7 ,
wherein the organic pigment microparticles are microparticles of C. I. Pigment Red 254,
the target wavelength range is 620 to 750 nm, and
the ratio of an area of the diffuse reflectance in the target wavelength range to a total area of the diffuse reflectance in the entire measurement wavelength range is 71% or more.

10. The method of producing an organic pigment composition according to claim 7 ,
wherein the organic pigment microparticles are microparticles of copper phthalocyanine,
the target wavelength range is 450 to 495 nm, and
the ratio of an area of the diffuse reflectance in the target wavelength range to a total area of the diffuse reflectance in the entire measurement wavelength range is 30% or more.

11. The method of producing an organic pigment composition according to claim 7 ,
wherein the organic pigment microparticles are microparticles of brominated chlorinated zinc phthalocyanine,
the target wavelength range is 495 to 570 nm, and
the ratio of an area of the diffuse reflectance in the target wavelength range to a total area of the diffuse reflectance in the entire measurement wavelength range is 51% or more.

12. The method of producing an organic pigment composition according to claim 6 , wherein the silicon oxide contains an amorphous silicon oxide.

13. The method of producing an organic pigment composition according to claim 6 , wherein the organic pigment composition is an organic pigment microparticle dispersion, and the method comprises the following steps (I) to (III):
Step (I) of obtaining at least one kind of organic pigment microparticles;
Step (II) of measuring a diffuse reflectance of the organic pigment microparticles; and
Step (III) of dispersing the organic pigment microparticles in a solvent to obtain the organic pigment microparticle dispersion.

14. A method of producing a coating film, wherein the coating film is prepared using the organic pigment microparticle dispersion obtained by the method of producing an organic pigment composition according to claim 13 , and a luminance of the coating film is controlled.

15. The method of producing a coating film according to claim 14 , wherein a luminance of the coating film is controlled by controlling a diffuse reflectance of the organic pigment microparticles.

16. The method of producing a coating film according to claim 14 ,
wherein a diffuse reflectance of powders of the organic pigment microparticles is measured, and the luminance of the coating film is evaluated by using the following relation obtained by the following steps (I) to (IV):
Step (I) of obtaining at least one kind of organic pigment microparticles;
Step (II) of measuring the diffuse reflectance of the powders of the organic pigment microparticles in the wavelength range of 380 to 780 nm;
Step (III) of dispersing the organic pigment microparticles in a solvent to obtain the organic pigment microparticle dispersion; and
Step (IV) of measuring a luminance of the coating film prepared using the organic pigment microparticle dispersion, to obtain the relation between the luminance of the coating film and a ratio of an area of the diffuse reflectance in the target wavelength range to a total area of the diffuse reflection in the entire measurement wavelength range.

17. A method of producing a color filter, comprising a step of forming the coating film on a substrate for a color filter, in the method of producing a coating film according to claim 14 , to obtain the color filter whose luminance is controlled by controlling the diffuse reflectance of the organic pigment microparticles.

Assignees

• M Technique Co Ltd

Inventors

• Enomura Masakazu
• Honda Daisuke

Classifications

• G02B5/206 Primary

  comprising particles embedded in a solid matrix · CPC title

• G02B5/223

  containing organic substances, e.g. dyes, inks or pigments · CPC title

• C09B67/007 Primary

  Non aqueous dispersions of phthalocyanines containing only a solvent and a dispersing agent · CPC title

• G01N21/27

  using photo-electric detection (G01N21/31 takes precedence){; circuits for computing concentration (logarithmic circuits G06G7/24; photometric circuits in general G01J)} · CPC title

• C09D5/22

  Luminous paints {(luminescent compositions C09K11/00)} · CPC title