Three-dimensional printing

Patent metadata

Field	Value
Publication number	US-11613670-B2
Application number	US-201816605391-A
Country	US
Kind code	B2
Filing date	Jun 18, 2018
Priority date	Jun 18, 2018
Publication date	Mar 28, 2023
Grant date	Mar 28, 2023

Abstract

An example of a three-dimensional (3D) printing kit includes a build material composition and a fusing agent to be applied to at least a portion of the build material composition during 3D printing. The build material composition includes a thermoplastic elastomer having: an avalanche angle ranging from about 49 degrees to about 59 degrees; a break energy ranging from about 55 kJ/kg to about 78 kJ/kg; and an avalanche energy ranging from about 10 kJ/kg to about 27 kJ/kg. The fusing agent includes an energy absorber to absorb electromagnetic radiation to coalesce the thermoplastic elastomer in the at least the portion.

First claim

What is claimed is:

1. A three-dimensional (3D) printing kit, comprising:
a build material composition including a thermoplastic elastomer having:
an avalanche angle ranging from about 49 degrees to about 59 degrees;
a break energy ranging from about 55 kJ/kg to about 78 kJ/kg; and
an avalanche energy ranging from about 10 kJ/kg to about 27 kJ/kg;

a fusing agent to be applied to at least a portion of the build material composition during 3D printing, the fusing agent including an energy absorber to absorb electromagnetic radiation to coalesce the thermoplastic elastomer in the at least the portion; and
a detailing agent including a surfactant, a co-solvent, and water,
wherein the build material composition, the fusing agent, and the detailing agent are maintained separately until used together in three-dimensional printing.

2. The 3D printing kit as defined in claim 1 wherein the thermoplastic elastomer has a dynamic density within about 15% of a bulk density of the thermoplastic elastomer.

3. The 3D printing kit as defined in claim 1 wherein one of:
(i) the thermoplastic elastomer is a polyether block amide, the avalanche angle ranges from about 55 degrees to about 59 degrees, the break energy ranges from about 68 kJ/kg to about 78 kJ/kg, and the avalanche energy ranges from about 17 kJ/kg to about 27 kJ/kg; or
(ii) the thermoplastic elastomer is a thermoplastic polyurethane, the avalanche angle ranges from about 49 degrees to about 53 degrees, the break energy ranges from about 55 kJ/kg to about 65 kJ/kg, and the avalanche energy ranges from about 10 kJ/kg to about 20 kJ/kg.

4. The 3D printing kit as defined in claim 1 wherein the thermoplastic elastomer is a polyether block amide having a dynamic density of about 0.36 g/cc.

5. The 3D printing kit as defined in claim 1 , further comprising a coloring agent selected from the group consisting of a black agent, a cyan agent, a magenta agent, and a yellow agent.

6. The 3D printing kit as defined in claim 1 wherein the detailing agent is to maintain the temperature of the build material composition in contact therewith below a lowest temperature in a melting range of the thermoplastic elastomer of the build material composition.

7. The 3D printing kit as defined in claim 1 wherein the fusing agent is a core fusing agent and the energy absorber has absorption at least at wavelengths ranging from 400 nm to 780 nm.

8. The 3D printing kit as defined in claim 7 , further comprising a primer fusing agent including a plasmonic resonance absorber which is an inorganic pigment selected from the group consisting of lanthanum hexaboride, tungsten bronzes, indium tin oxide, aluminum zinc oxide, ruthenium oxide, silver, gold, platinum, iron pyroxenes, copper iron phosphate, magnesium iron phosphate, zinc iron phosphate, iron copper pyrophosphate, magnesium copper pyrophosphate, zinc copper pyrophosphate, and combinations thereof.

9. The 3D printing kit as defined in claim 1 wherein the fusing agent is a primer fusing agent and the energy absorber is a plasmonic resonance absorber which is an inorganic pigment selected from the group consisting of lanthanum hexaboride, tungsten bronzes, indium tin oxide, aluminum zinc oxide, ruthenium oxide, silver, gold, platinum, iron pyroxenes, copper iron phosphate, magnesium iron phosphate, zinc iron phosphate, iron copper pyrophosphate, magnesium copper pyrophosphate, zinc copper pyrophosphate, and combinations thereof.

10. A three-dimensional (3D) printing composition, comprising:
a build material including a thermoplastic elastomer having:
an avalanche angle ranging from about 49 degrees to about 59 degrees;
a break energy ranging from about 55 kJ/kg to about 78 kJ/kg; and
an avalanche energy ranging from about 10 kJ/kg to about 27 kJ/kg;

a fusing agent to be applied to at least a portion of the build material during 3D printing, the fusing agent including an energy absorber having absorption at least at some wavelengths ranging from 400 nm to 4000 nm to absorb electromagnetic radiation to coalesce the thermoplastic elastomer in the at least the portion; and
a detailing agent including a surfactant, a co-solvent, and water i
wherein the build material, the fusing agent, and the detailing agent are maintained separately until used together in three-dimensional printing.

11. The 3D printing composition as defined in claim 10 wherein the thermoplastic elastomer has a dynamic density within about 15% of a bulk density of the thermoplastic elastomer.

Assignees

• Hewlett Packard Development Co

Inventors

• Fung Erica
• Fleischmann Carolin
• Tandy Jesiska
• Querol Esparch Carmina
• Long Greg S
• Emamjomeh Ali
• Woodruff Shannon Reuben
• Donovan Rachael
• Flack Kenneth

Classifications

• B33Y10/00

  Processes of additive manufacturing · CPC title

• C09D175/04

  Polyurethanes · CPC title

• B29C64/165 Primary

  using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber · CPC title

• C09D177/00 Primary

  Coating compositions based on polyamides obtained by reactions forming a carboxylic amide link in the main chain (based on polyhydrazides C09D179/06; based on polyamide-imides C09D179/08); Coating compositions based on derivatives of such polymers · CPC title

• B33Y70/00

  Materials specially adapted for additive manufacturing · CPC title