Fibre reinforcement of reactive foams obtained by a moulding foam method

Patent metadata

Field	Value
Publication number	US-11613620-B2
Application number	US-201716303491-A
Country	US
Kind code	B2
Filing date	May 17, 2017
Priority date	May 25, 2016
Publication date	Mar 28, 2023
Grant date	Mar 28, 2023

Abstract

The present invention relates to a molding made of reactive foam, wherein at least one fiber (F) is arranged partially inside the molding, i.e. is surrounded by the reactive foam. The two ends of the respective fiber (F) not surrounded by the reactive foam thus each project from one side of the corresponding molding. The reactive foam is produced by a mold foaming process. The present invention further provides a panel comprising at least one such molding and at least one further layer (S1). The present invention further provides processes for producing the moldings according to the invention from reactive foam/the panels according to the invention and also provides for the use thereof as a rotor blade in wind turbines for example.

First claim

The invention claimed is:

1. A molding made of reactive foam, wherein at least one fiber (F) is with a fiber region (FB2) arranged inside the molding and surrounded by the reactive foam while a fiber region (FB1) of the fiber (F) projects from a first side of the molding and a fiber region (FB3) of the fiber (F) projects from a second side of the molding, wherein the reactive foam has been produced by mold foaming process, wherein the fiber (F) has been introduced into the reactive foam at an angle α of 10° to 70° relative to the thickness direction (d) of the molding and wherein the molding is obtained by a process comprising the steps a) to f):
a) optionally applying at least one layer (S2) onto at least one side of the reactive foam,
b) producing one hole per fiber (F) in the reactive foam and optionally the layer (S2), wherein the hole extends from a first side to a second side of the reactive foam and optionally through the layer (S2),
c) providing at least one fiber (F) on the second side of the reactive foam,
d) passing a needle from the first side of the reactive foam through the hole to the second side of the reactive foam and optionally passing the needle through the layer (S2),
e) securing at least one fiber (F) to the needle on the second side of the reactive foam and
f) returning the needle along with the fiber (F) through the hole, so that the fiber (F) is with the fiber region (FB2) located inside the molding and surrounded by the reactive foam while the fiber region (FB1) of the fiber (F) projects from a first side of the molding or optionally from the layer (S2) and the fiber region (FB3) of the fiber (F) projects from a second side of the molding, wherein over 30% of the total surface area of the molding is closed;
wherein the reactive foam is based on a polyurethane, a polyurea or a polyisocyanate; and
wherein the density increases from the core of the reactive foam to the surface thereof.

2. The molding according to claim 1 , wherein the mold foaming process comprises the following steps I) to IV):
I) providing a reactive mixture which comprises at least one first component (K1) and at least one second component (K2), wherein the first component (K1) and the second component (K2) can react with one another,
II) injecting the reactive mixture provided in step I) into a shaping mold,
III) expanding the reactive mixture in the shaping mold to obtain an expanded foam and
IV) demolding the expanded foam obtained in step III) from the shaping mold to obtain the reactive foam.

3. The molding according to claim 2 , wherein the reactive foam is based on a polyurethane, a polyurea or a polyisocyanurate,
which is in each case produced by a mold foaming process according to claim 2 and where the reactive mixture provided in step I-1) comprises as the first component (K1) at least one polyisocyanate and as the second component (K2) at least one compound having isocyanate-reactive groups and as a further component at least one blowing agent.

4. The molding according to claim 1 , wherein the reactive foam comprises cells, wherein
i) the surface of at least one side of the molding comprises at least one depression, the depression being a slot or a hole, and/or
ii) the total surface area of the molding is closed to an extent of more than 30%, and/or
iii) the reactive foam has a glass transition temperature of at least 80° C.

5. The molding according to claim 1 , wherein
i) the fiber (F) is a single fiber or a fiber bundle, and/or
ii) the fiber (F) is an organic, inorganic, metallic or ceramic fiber or a combination thereof, and/or
iii) the fiber (F) is employed in the form of a fiber bundle having a number of individual fibers per bundle of at least 10 in the case of glass fibers and 1000 to 50 000 in the case of carbon fibers, and/or
iv) the fiber region (FB1) and the fiber region (FB3) each independently of one another account for 1% to 45% and the fiber region (FB2) accounts for 10% to 98% of the total length of a fiber (F), and/or
v) the fiber (F) has been introduced into the reactive foam at an angle α of 30° to 60°, relative to the thickness direction (d) of the molding, and/or
vi) in the molding the first side of the molding from which the fiber region (FB1) of the fiber (F) projects is opposite the second side of the molding from which the fiber region (FB3) of the fiber (F) projects, and/or
vii) the molding comprises a multiplicity of fibers (F) and/or comprises more than 10 fibers (F) or fiber bundles per m 2 .

6. A panel comprising at least one molding according to claim 1 and at least one layer (S1).

7. The panel according to claim 6 , wherein the layer (S1) comprises at least one resin.

8. The panel according to claim 7 , wherein the layer (S1) additionally comprises at least one fibrous material, wherein
i) the fibrous material comprises fibers in the form of one or more plies of chopped fibers, nonwovens, non-crimp fabrics, knits and/or wovens, and/or
ii) the fibrous material comprises organic, inorganic, metallic or ceramic fibers.

9. The panel according to claim 6 , wherein the panel comprises two layers (S1) and the two layers (S1) are each attached at a side of the molding that is opposite the respective other side of the molding.

10. The panel according to claim 6 , wherein
i) the fiber region (FB1) of the fiber (F) is in partial or complete contact with the first layer (S1), and/or
ii) the fiber region (FB3) of the fiber (F) is in partial or complete contact with the second layer (S1), and/or
iii) the panel comprises between at least one side of the molding and at least one layer (S1) at least one layer (S2), the layer (S2) being composed of sheetlike fiber materials or polymeric films.

11. A panel comprising at least one molding according to claim 2 and at least one layer (S1), wherein
i) the molding present in the panel comprises at least one side that has not been subjected to mechanical and/or thermal processing, and/or
ii) the molding present in the panel comprises at least one layer (S2) that has been applied to the reactive foam as a carrier film in the mold foaming process in step II).

12. A process for producing a molding according to claim 1 , wherein at least one fiber (F) is partially introduced into the reactive foam with the result that the fiber (F) is with the fiber region (FB2) arranged inside the molding and surrounded by the reactive foam while the fiber region (FB1) of the fiber (F) projects from a first side of the molding and the fiber region (FB3) of the fiber (F) projects from a second side of the molding.

13. The process according to claim 12 , wherein the partial introduction of at least one fiber (F) into the reactive foam is effected by sewing-in using a needle,
by steps a) to f):
a) optionally applying at least one layer (S2) to at least one side of the reactive foam,
b) producing one hole per fiber (F) in the reactive foam and optionally the layer (S2), wherein the hole extends from a first side to a second side of the reactive foam and optionally through the layer (S2),
c) providing at least one fiber (F) on the second side of the reactive foam,
d) passing a needle from the first side of the reactive foam through the hole to the second side of the reactive foam and optionally passing the needle through the layer (S2),
e) securing at least one fiber (F) to the needle on the second side of the reactive foam and
f) returning the needle including the fiber (F) through the hole, so that the fiber (F) is with the fiber region (FB2) arranged inside the molding and surrounded by the reactive foam while the fiber region (FB1) of the fiber (F) projects from a

Assignees

• Basf Se

Inventors

• Ruckdaeschel Holger
• Terrenoire Alexandre
• Arbter Rene
• Sampath Bangaru Dharmapuri Sriramulu
• Gutmann Peter
• Stoll Ragnar
• Hebette Christophe Leon Marie
• Stein Robert

Classifications

• Y02E10/72

  Wind turbines with rotation axis in wind direction · CPC title

• B32B5/26

  another layer {next to it} also being fibrous or filamentary {(relative arrangement of fibres or filaments of different layers B32B5/12)} · CPC title

• B29K2075/00

  Use of {PU, i.e.} polyureas or polyurethanes {or derivatives thereof}, as moulding material · CPC title

• B32B2605/10

  Trains · CPC title

• C08G18/7671

  containing only one alkylene bisphenyl group · CPC title