Curable concrete composition containing palm ash

Patent metadata

Field	Value
Publication number	US-11613499-B2
Application number	US-202117402682-A
Country	US
Kind code	B2
Filing date	Aug 16, 2021
Priority date	Aug 6, 2019
Publication date	Mar 28, 2023
Grant date	Mar 28, 2023

Abstract

A concrete composition that includes (i) a treated palm oil fuel ash, wherein the treated palm oil fuel ash is the only binder present, (ii) a fine aggregate, (iii) a coarse aggregate, and (iv) an alkali activator containing an aqueous solution of sodium hydroxide and sodium silicate. A cured concrete made from the concrete composition is also disclosed with advantageous compressive strength properties.

First claim

The invention claimed is:

1. A palm ash concrete composition, comprising:
a treated palm oil fuel ash, wherein the treated palm oil fuel ash is the only binder present;
a fine aggregate in an amount of from 10 to 25 wt. % based on a total weight of the concrete composition;
a coarse aggregate having a saturated surface dry (SSD) specific gravity of 2.5 to 2.6; and
an alkali activator comprising an aqueous solution of sodium hydroxide and sodium silicate,
wherein the coarse aggregate has a bimodal particle size distribution with a first mode particle size of 4 to 6 mm and a second mode particle size of 2 to 3 mm, and wherein a weight ratio of coarse aggregate having the first mode particle size to coarse aggregate having the second mode particle size is 1:1 to 3:1.

2. The concrete composition of claim 1 , wherein the treated palm oil fuel ash has a median particle size (d 50 ) of 0.5 to 2.0 μm.

3. The concrete composition of claim 1 , wherein the treated palm oil fuel ash comprises, as constituent oxides, 66 to 68 wt. % SiO 2 , 6 to 7 wt. % Al 2 O 3 , 5 to 6.5 wt. % Fe 2 O 3 , 5 to 6 wt. % CaO, 2.5 to 3.5 wt. % MgO, 4.5 to 6 wt. % K 2 O, 0.3 to 0.35 wt. % SO 3 , 0.18 to 0.2 wt. % Na 2 O, and 3 to 4 wt. % of P 2 O 3 , each based on a total weight of the treated palm oil fuel ash.

4. The concrete composition of claim 1 , wherein the treated palm oil fuel ash has a loss on ignition (LOI) of less 3 wt. %, based on a total weight of the treated palm oil fuel ash, and a specific surface area of 1.4 to 1.6 m 2 /g.

5. The concrete composition of claim 1 , wherein a weight ratio of a combined weight of the coarse aggregate and the fine aggregate to the treated palm oil fuel ash is 1:1 to 2:1.

6. The concrete composition of claim 1 , wherein a weight ratio of the alkali activator to the treated palm oil fuel ash is 0.3:1 to 0.7:1.

7. The concrete composition of claim 1 , wherein a weight ratio of sodium silicate to sodium hydroxide is 1:1 to 3:1.

8. The concrete composition of claim 1 , which has weight ratio of water to the treated palm oil fuel ash of 0.06 to 0.98.

9. The concrete composition of claim 1 , which consists of the treated palm oil fuel ash, the coarse aggregate, the fine aggregate, sodium hydroxide, sodium silicate, and water.

Assignees

• Univ King Fahd Pet & Minerals

Inventors

• Salami Babatunde Abiodun
• Johari Megat Azmi Megat
• Maslehuddin Mohammed
• Ahmad Zainal Arifin

Classifications

• Y02P40/18

  Carbon capture and storage [CCS] · CPC title

• C04B2201/50

  for the mechanical strength · CPC title

• C04B28/021

  Ash cements, e.g. fly ash cements (fly ash as filler C04B18/08); Cements based on incineration residues, e.g. alkali-activated slags from waste incineration (alkali-activated combustion residues as such C04B7/243; mixtures of the lime-pozzuolane type C04B28/18); Kiln dust cements · CPC title

• C04B28/26 Primary

  Silicates of the alkali metals · CPC title

• C04B14/06

  Quartz; Sand · CPC title